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-
- Description:
- This dissertation seeks to explore how physical forces, notably through the use of magnetic nanoparticles and applied fields, can influence the structural outcomes of colloidal crystals engineered with DNA. Chapter 1 describes how both DNA and magnetic fields can direct the assembly of nanoparticles into periodic and sometimes crystalline materials....
- Keyword:
- colloidal crystal engineering with DNA, iron oxide nanoparticles, and magnetic field assembly
- Subject:
- Chemistry
- Creator:
- Urbach, Zachary James
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/15/2021
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_790857 and http://dissertations.umi.com/northwestern:15441
-
- Description:
- Proteins are known to have diverse biomedical functions and excellent catalytic performance; however, they are also fragile outside living cells, challenging their use in industrial applications. Metal-organic frameworks (MOFs) are highly porous crystalline materials that consist of metal cluster nodes and organic linkers. With their rigid structures, MOFs can effectively...
- Keyword:
- Drug Delivery, Protein Stabilization, and Biocatalysis
- Subject:
- Chemistry
- Creator:
- Chen, Yijing
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_835507 and http://dissertations.umi.com/northwestern:15658
-
- Description:
- Noble metal nanoparticles (NPs) have shown promise as imaging agents, drug delivery platforms, and plasmonic sensors. Anisotropic gold NPs, such as gold nanostars, have particularly received attention due to their shape-dependent optical and spectral properties. With their 3D anisotropic structure with branches protruding into different directions and high surface areas,...
- Keyword:
- Nanoparticle, Nanostar, Electron Tomography, and DIC Microscopy
- Subject:
- Chemistry
- Creator:
- Choo, Priscilla
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_837616 and http://dissertations.umi.com/northwestern:15668
-
- Description:
- Recent progress in the field of nanomaterials has enabled significant advances in optoelectronic devices such as solar cells, light-emitting diodes, photocatalysts, and sensors. Nanoparticles feature superior optical and electronic properties that arise from quantum confinement and therefore cannot be attained used bulk materials. However, further developments in the field of...
- Keyword:
- ultrafast spectroscopy, transient absorption, nanoparticles, two-dimensional, nanoplatelets, and electronic processes
- Subject:
- Chemistry
- Creator:
- Brumberg, Alexandra
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_845490 and http://dissertations.umi.com/northwestern:15773
-
- Description:
- Metallic conductivity and broken inversion symmetry were long thought to be contraindicated properties, under the assumption that long-range Coulombic interactions (screened by free charge carriers) were necessary for coordinated polar displacements. Within the past decade, the discovery of polar metals has prompted a rethinking of the relationship between metallicity and...
- Keyword:
- first principles, contraindicated, polar, phase, ferroelectric, and metal
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Hickox-Young, Daniel Timothy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15762 and etdadmin_upload_845260
-
- Description:
- Two-dimensional (2D) covalent organic frameworks (COFs) are a class of crystalline polymer networks that polymerize and crystallize into layered structures, characterized by their atomically precise structure, permanent porosity and high modularity. Imine-linked COFs are one of the most important and promising classes of macromolecular sheets, which form by the condensation...
- Keyword:
- Covalent organic frameworks
- Subject:
- Polymer chemistry and Chemistry
- Creator:
- Ji, Woojung
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/28/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15494 and etdadmin_upload_799668
-
- Description:
- This thesis describes the synthesis and photophysical characterization of low-dimensionalmaterials—including thin-film semiconductors, colloidal quantum dots, and molecules—with the broader motivation of integrating them into mixed-dimensional heterostructures with novel responses to external stimuli. Due to their high surface area to volume ratio and incomplete dielectric screening, mixed-dimensional heterostructures have high sensitivity...
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Olding, Jack Nicklaus
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15691 and etdadmin_upload_840718
-
- Description:
- Label-free assays, and particularly those based on the combination of mass spectroscopy with surface chemistries, enable high-throughput experiments of a broad range of reactions. However, these methods can still require the incorporation of functional groups that allow immobilization of reactants and products to surfaces prior to analysis. In this thesis,...
- Keyword:
- Nanotechnology, SAMDI, Surface chemistry, Microarray, Mass Spectrometry, and Reactions
- Subject:
- Chemistry, Biomedical engineering, and Chemical engineering
- Creator:
- Helal, Kazi Yasin
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/28/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15011 and etdadmin_upload_719318
-
- Description:
- While Li-ion batteries are currently the preferred energy storage technology, multivalent alternatives such as Mg should be considered. Magnesium metal has a high volumetric capacity and has been shown to cycle with no dendrite formation. However, the highly charged Mg2+ ion cannot easily diffuse into the oxide cathodes favored in...
- Keyword:
- Solid State Chemistry, Multivalent Batteries, Magnesium Cathodes, and Hydrothermal Synthesis
- Subject:
- Inorganic chemistry and Chemistry
- Creator:
- Wustrow, Allison
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_662066 and http://dissertations.umi.com/northwestern:14625
-
- Description:
- Nanoparticles (NPs) are emerging as attractive drug carriers in therapeutic and diagnostic applications. The physiochemical properties of NPs, such as particle size, shape, and surface chemistry, play important roles in the functions of engineered nanoconstructs−NP cores with surface ligands. Recent work has screened these properties by monitoring cellular uptake and/or...
- Subject:
- Chemistry
- Creator:
- Liu, Tingting
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_844987 and http://dissertations.umi.com/northwestern:15753
-
- Description:
- The building blocks of life are proteins. These incredible nanostructures are responsible for forming the diverse infrastructure of living systems and for performing countless biological functions. In Nature, these materials and systems achieve structural complexity and function through highly regulated and controlled assembly of protein building blocks, driven by specific...
- Keyword:
- Hierarchical, Supramolecular , Proteins, and Self-assembly
- Subject:
- Nanotechnology and Chemistry
- Creator:
- Hayes, Oliver George
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_835884 and http://dissertations.umi.com/northwestern:15660
-
- Description:
- Recent progress in semiconductor synthesis and photophysics has revealed a host of new materials with exciting properties for applications in optoelectronic devices such as sensors, photovoltaics, solid state lighting, and more. One of the most significant recent additions to the field is the class of hybrid and inorganic materials that...
- Subject:
- Physical chemistry, Chemistry, and Materials Science
- Creator:
- Cuthriell, Shelby A
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16650 and etdadmin_upload_1000360
-
- Description:
- Realizing electromagnetic metamaterials which operate in the optical regime requires creating precise arrangements of sub-100 nm building blocks. As such, fabricating these materials using conventional lithographic methods is extremely costly. On the other hand, bottom-up assembly of nanoparticles into crystalline superlattices offers opportunities to explore the scalable fabrication of 2-...
- Subject:
- Chemistry
- Creator:
- Zheng, Cindy Yizhe
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15883 and etdadmin_upload_864457
-
- Description:
- Amyloid beta oligomers (AβOs) are a key instigator of neurodegeneration in Alzheimer’s disease (AD). The work presented in this thesis includes three disease-modifying approaches to disrupt pathological AβO-related mechanisms in AD: (1) inhibiting AβO buildup, (2) blocking AβO-induced tau phosphorylation, and (3) neutralizing AβOs. These three approaches were tested in...
- Keyword:
- Amyloid beta oligomer
- Subject:
- Chemistry
- Creator:
- Johnson, Elizabeth Anne
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16421 and etdadmin_upload_962600
-
- Description:
- Gold nanoparticles (AuNPs) display unique characteristics compared to their macro-counterparts that are dependent on shape, size, and attached surface molecules. Methods have been developed to precisely control both size and shape of AuNPs for specific applications. The biocompatibility, plasmonic properties, and ease of functionalization with thiolated molecules, make gold nanoparticles...
- Keyword:
- gold nanopaticles, therapeutics, DNA, cancer vaccine, and plasmonics
- Subject:
- Nanotechnology, Chemistry, and Biology
- Creator:
- Coughlin, Emma
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/28/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15532 and etdadmin_upload_815702
-
- Description:
- Functional electronic materials have transformed modern society toward a highly digitized and interconnected global community. The ever-growing demand for electronic devices with superior functionality poses a great challenge to the state-of-the-art field-effect transistors owing to the limited charge density afforded by silicon. Materials scientists and chemists have been working closely...
- Keyword:
- Bayesian optimization, Gaussian processes, deep neural network, computational materials science, and metal-insulator transition
- Subject:
- Chemistry
- Creator:
- Wang, Yiqun
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/28/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_815597 and http://dissertations.umi.com/northwestern:15531
-
- Description:
- Biomedical imaging is an essential part of medicine that enables the non-invasive observation of biological phenomena. This, in turn, allows for more accurate and earlier diagnoses, monitoring of therapies, and even fundamental research into biological processes. Molecular imaging, a fast-growing subdiscipline of biomedical imaging, seeks to image biochemical processes at...
- Keyword:
- Theranostic, Gadolinium, Bioresponsive, Chemotherapy, MRI, and Platinum
- Subject:
- Inorganic chemistry and Chemistry
- Creator:
- Adams, Casey
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_864932 and http://dissertations.umi.com/northwestern:15884
-
- Description:
- Amyloid beta oligomers (AβOs) are a key instigator of neurodegeneration in Alzheimer’s disease (AD). The work presented in this thesis includes three disease-modifying approaches to disrupt pathological AβO-related mechanisms in AD: (1) inhibiting AβO buildup, (2) blocking AβO-induced tau phosphorylation, and (3) neutralizing AβOs. These three approaches were tested in...
- Keyword:
- Amyloid beta oligomer
- Subject:
- Chemistry
- Creator:
- Johnson, Elizabeth Anne
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 03/24/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16421 and etdadmin_upload_962600
-
- Description:
- The construction of new C–C bonds remains a central facet of organic chemistry due to its critical role in the synthesis of pharmaceutical compounds and organic materials. Mild and selective methodologies are often required for efficient formation of these bonds in natural product total synthesis, medicinal chemistry campaigns, and more....
- Keyword:
- carbene, photochemistry, catalysis, ketone, photoredox, and NHC
- Subject:
- Organic chemistry and Chemistry
- Creator:
- Bay, Anna Victoria
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_929370 and http://dissertations.umi.com/northwestern:16269
-
- Description:
- Understanding the mechanisms associated with chemical catalysis is vital for not only the rational improvement of their capabilities, but also for the advancement of the fundamental knowledge affiliated with the systems in question. These new insights can help predict new reactivities towards more challenging substrates which will allow for easier...
- Keyword:
- Catalysis, Lanthanides, Borylation, and Chemodivergent
- Subject:
- Chemistry
- Creator:
- Rothbaum , Jacob Olasov
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16303 and etdadmin_upload_936040
-
- Description:
- Semiconductor nanocrystals possess unique photophysical properties that make them desirable for many optoelectronic applications such as photovoltaics, LEDs, and quantum computing. When the size of a semiconductor is reduced to below the excitonic Bohr radius of the material, its carriers becomes quantum confined resulting in drastic changes to optical, electronic,...
- Keyword:
- Nanocrystals, Spin, Semiconductors, Spectroscopy, Thermal properties, and Carrier Dynamics
- Subject:
- Physical chemistry, Chemistry, and Materials Science
- Creator:
- Harvey, Samantha
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_857543 and http://dissertations.umi.com/northwestern:15830
-
- Description:
- Early transition metal organometallics chemisorbed on extremely Brønsted acidic sulfated metal oxides such as sulfated alumina (AlS) and sulfated zirconia (ZrS) produce highly active single-site catalysts for olefin polymerization, alkene and arene hydrogenation, and alkane hydrogenolysis, typically with a large percentage of catalytically significant sites. The low support conjugate basicity...
- Subject:
- Chemistry
- Creator:
- Mason, Alexander Heath
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16529 and etdadmin_upload_984243
-
- Description:
- The physical boundary layer, or interface, between two different phases of matter is the site of chemical and physical processes that are critical to many research fields. Many of these interfaces contain electric charge, which influences the structure and composition of the interfacial region and the interactions between the interface...
- Keyword:
- Second harmonic generation, Mineral, Sum frequency generation, Spectroscopy, Interface, and Water
- Subject:
- Physical chemistry and Chemistry
- Creator:
- Ohno, Paul Erich
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14749 and etdadmin_upload_675952
-
- Description:
- Commercial agriculture and industrial manufacturing have contaminated freshwater sources with persistent organic pollutants, heavy metals, and radioactive species. Effective mitigation of this pollution is paramount to safeguarding human health, animal and aquatic life, and the environment. Conventional adsorbents such as activated carbon, metal oxides, resins, and polymers attain moderate to...
- Subject:
- Chemistry
- Creator:
- Drout, Riki Joyce
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/28/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15522 and etdadmin_upload_814397
-
- Description:
- Oligonucleotides can be used to modulate the regulation of pathological genes that are associated with various diseases. However, due to biological barriers, efficient delivery of oligonucleotides, especially to extrahepatic tissues, remains a challenge. To overcome these barriers, multiple delivery strategies have been developed, ranging from medicinal chemistry to nanotechnology. Nanoparticle-based...
- Keyword:
- surface modification, biodistribution, and spherical nucleic acids
- Subject:
- Chemistry
- Creator:
- Zhang, Wuliang
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_830130 and http://dissertations.umi.com/northwestern:15627
-
- Description:
- Soft materials are inherently fluxional, with morphologies and behaviors that are dictated by their solvation state. Thus, many organic systems cannot be reliably imaged by static dry state or cryogenic-transmission electron microscopy (TEM). This motivated us to pursue liquid cell (LC) TEM method development to study our own materials and...
- Subject:
- Chemistry
- Creator:
- Korpanty, Joanna
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16391 and etdadmin_upload_954956
-
- Description:
- The lanthanides, with their limited orbital effects and high oxophilicity, represent a class of catalytic metals highly distinguished from more commonly-utilized transition metals. Homogeneous lanthanide catalysts often afford high catalytic rates and impressive selectivity. However, challenges regarding the synthesis and utilization of highly air- and water-sensitive organo-lanthanide complexes have limited...
- Keyword:
- Catalysis, Homogeneous, Lanthanide, and Hydroboration
- Subject:
- Chemistry
- Creator:
- Barger, Christopher
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/15/2021
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15464 and etdadmin_upload_795345
-
- Description:
- Polyolefins are the most versatile and widely used polymers worldwide. Depending on the polymer microstructure, polyolefins can exhibit a wide range of useful and tailored properties and applications. Metal-catalyzed coordinative olefin polymerization plays a center role in advancing polyolefin synthesis. This dissertation explores two strategies to modulate the polymer microstructures...
- Keyword:
- scandium, olefin polymerization, zirconium, bimetallic effect, and polar monomer
- Subject:
- Inorganic chemistry and Chemistry
- Creator:
- Chen, Jiazhen
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14719 and etdadmin_upload_669232
-
- Description:
- Spherical Nucleic Acids (SNAs) are unique class of nanomaterial characterized by a dense nucleic acid shell conjugated to a nanoparticle core. This radial orientation of oligonucleotides and architecture distinguishes SNAs from the components from which they are comprised. Specifically, unique chemical and biological properties emerge that are not observed with...
- Keyword:
- Spherical Nucleic Acid, Nanoparticle, Immune system, Toll-like receptors, and Biodistribution
- Subject:
- Nanotechnology, Chemistry, and Immunology
- Creator:
- Ferrer, Jennifer R
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14715 and etdadmin_upload_668701
-
- Description:
- Uranium is a unique, multifaceted element that possesses rich chemistry and promise for challenging reactions. Pressing demands within nuclear stockpile stewardship and the nuclear energy sector call for development of this relatively understudied element. Uranium metal–organic frameworks (U-MOFs), a class of nanoscale hybrid materials, harness the exceptional attributes of uranium...
- Keyword:
- metal-organic frameworks, uranium, and nanotechnology
- Subject:
- Inorganic chemistry, Nanoscience, and Chemistry
- Creator:
- Hanna, Sylvia Lorraine
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16404 and etdadmin_upload_961471
-
- Description:
- In this thesis, I present the development and benchmarking of several theoretical methods designed to enable the rigorous modeling of magnetic properties of molecules containing one or a few heavy atoms, particularly single-molecule magnets. The new methods use a full four-component treatment of relativity, allowing spin–orbit effects to be taken...
- Keyword:
- Single-Molecule Magnets, Electronic Structure, Relativity, Theoretical Chemistry, Zero-Field Splitting, and Magnetizability
- Subject:
- Physical chemistry, Chemistry, and Computational chemistry
- Creator:
- Reynolds, Ryan Dave
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_623099 and http://dissertations.umi.com/northwestern:14425
-
- Description:
- Self-assembled monolayers for matrix-assisted laser desorption/ionization mass spectrometry (SAMDI-MS) is a platform that combines self-assembled monolayers of alkanethiolates on gold and MALDI mass spectrometry analysis to report mass changes resulting from surface reactions. The synthetic flexibility of the monolayer and the use of mass spectrometry as a generalizable readout method...
- Subject:
- Chemistry
- Creator:
- Anderson , Sarah Elizabeth
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/28/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_812568 and http://dissertations.umi.com/northwestern:15516
-
- Description:
- Nanoparticle synthesis is capable of producing particles with any combination of structure, chemistry, size, shape, and surface. All of the different combinations of these physical properties can produce nanoparticles with almost countless materials properties suited for many applications. Given this interest in using nanoparticles in so many different fields, including...
- Keyword:
- nanoparticle growth, thermodynamics, nanoparticles, kinetics, hydrothermal synthesis, and crystal growth
- Subject:
- Inorganic chemistry, Chemistry, and Materials Science
- Creator:
- Ly, Tiffany
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15645 and etdadmin_upload_832870
-
- Description:
- This dissertation investigates the use of organic and semiconductor nanomaterials as chromophores in solar fuels production and energy transfer-mediated [2+2] cycloadditions. A series of novel N-annulated perylene chromophore amphiphiles was synthesized via a modular synthesis. These perylene amphiphiles were found to self-assemble in aqueous solution, forming extended ribbon-like nanostructures that...
- Keyword:
- cycloaddition, Nanomaterials, self-assembly, Quantum dots, Solar fuels, and photocatalysis
- Subject:
- Chemistry
- Creator:
- Nagasing, Benjamin
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/15/2021
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_787179 and http://dissertations.umi.com/northwestern:15434
-
- Description:
- One of the central challenges in solid-state chemistry is synthetic control over structure. Owing to limited reactivity of Pb with transition metals at ambient pressure and high temperature as well as the variety of properties that emerge from the few known binary transition-metal–Pb compounds, this research focuses on accessing and...
- Subject:
- Chemistry and Materials Science
- Creator:
- Tamerius, Alexandra
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_845128 and http://dissertations.umi.com/northwestern:15755
-
- Description:
- Heterogenous catalysis is the pillar of chemical production and a crucial aspect for optimization toward a sustainable future. To improve the current design of heterogeneous catalysts of maximal activity and product selectivity, gaining fundamental understanding of the catalytic active sites is crucial. The nature of active sites has been the...
- Keyword:
- Heterogeneous Catalysis, Metal-Organic Frameworks, Sustainability, and Material Chemistry
- Subject:
- Chemistry
- Creator:
- Wang, Qining
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16664 and etdadmin_upload_1002207
-
- Description:
- Discrete molecules, linear and branched polymers, and disordered cross-linked networks are well studied objects of chemical synthesis. However, two-dimensional polymers (2DPs) have been long missing from this continuum of molecular architectures, both in chemical synthesis and in Nature. Recently, new polymerization strategies and characterization methods have enabled the unambiguous realization...
- Keyword:
- Covalent Organic Frameworks, Controlled Polymerization, Organic Electronics, and Two-dimensional Polymers
- Subject:
- Polymer chemistry, Chemistry, and Materials Science
- Creator:
- Evans, Austin Michael
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/15/2021
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_793170 and http://dissertations.umi.com/northwestern:15454
-
- Description:
- Neurons are sensitive to the mechanical properties of their environment and show better growth, survival and differentiation when they are cultured in soft environments with mechanical properties similar to those of the brain compared to other tissues. Within the central nervous system (CNS), there is also a range of mechanical...
- Keyword:
- Hydrogels, Peptide amphiphiles, Mechanical properties, aza-glycine, Neurons, and Supramolecular
- Subject:
- Chemistry, Biomedical engineering, and Neurosciences
- Creator:
- Godbe, Jacqueline M
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/28/2020
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15006 and etdadmin_upload_719165
-
- Description:
- Single-use plastic waste pollution will cause significant harm to the environment if left unaddressed. One possible mitigation strategy is to develop processes, e.g. catalytic hydrogenolysis, that can convert (i.e. upcycle) waste plastics into value-added products capable of participating in a circular economy. Platinum (Pt) catalysts on strontium titanate nanocuboid supports...
- Subject:
- Chemistry and Materials Science
- Creator:
- Peczak, Ian Lukasz
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16513 and etdadmin_upload_983506
-
- Description:
- Oxide/aqueous and metal/metal oxide interfaces are essential for environmental remediation, catalysis, and corrosion inhibition, in addition to their potential implementation as energy transducers, consumer electronics, and coating products. While these interfaces are critically important, they are difficult to access experimentally under aqueous flow conditions. This thesis describes results obtained with...
- Keyword:
- Zero-Valent Iron, Second Harmonic Generation Spectroscopy, Nanolayers, Passivation, Interface, and Atom Probe Tomography
- Subject:
- Chemistry
- Creator:
- Boamah, Mavis Dufie
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14724 and etdadmin_upload_670561
-
- Description:
- Organic solar cells (OSC) are a next generation solar energy technology that offers the advantages of scalable fabrication, light weight, flexibility, and earth-abundant starting materials. Despite tremendous advances in OSC power conversion efficiency (PCE) over the last decade, active layer material selection and optimization is still largely empirical. In order...
- Keyword:
- Small molecule, Non Fullerene, Crystal Structure, Photovoltaic, and Organic solar Cells
- Subject:
- Chemistry, Materials Science, and Energy
- Creator:
- Swick, Steven Mitomu
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 04/28/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14961 and etdadmin_upload_712474
-
- Description:
- When attached to another species (e.g. a nanoparticle), the sequence specificity of DNA can be repurposed to program interactions between such entities and to direct their formation into ordered structures. The research presented in this thesis aims to push the boundaries of structures that can be made via this approach....
- Keyword:
- image analysis, nanoparticle, DNA, symmetry breaking, high-throughput, and crystal engineering
- Subject:
- Nanotechnology, Chemistry, and Chemical engineering
- Creator:
- Laramy, Christine
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_617692 and http://dissertations.umi.com/northwestern:14404
-
- Description:
- Harnessing the metabolic potential of methanotrophic bacteria is a compelling strategy for the bioremediation of environmentally harmful methane gas. Methanotrophs can activate a 105 kcal/mol C-H bond in methane at ambient conditions using metalloenzymes called methane monooxygenases (MMOs). Particulate methane monooxygenase (pMMO) is a copper-dependent, membrane-bound enzyme that is the...
- Keyword:
- copper, methane, methanotroph, metalloenzyme, particulate methane monooxygenase, and membrane protein
- Subject:
- Microbiology, Chemistry, and Biochemistry
- Creator:
- Ro, Soo Yeon
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14705 and etdadmin_upload_667719
-
- Description:
- The properties of crystalline materials are controlled by their composition and by their structure, however, the structure of a crystal is only partly controlled by its composition. Development of specifically directed inorganic syntheses will require an understanding of the dynamics of crystal phase forming processes, especially those processes involved in...
- Keyword:
- noncentrosymmetry, oxyflouride, crystal, and reconstructive transition
- Subject:
- Chemistry
- Creator:
- Michael John Holland
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/13/2018
- Date Modified:
- 02/13/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- The FDA approvals of afatinib and ibrutinib in 2013 led to a heightened interest in cysteine-reactive covalent inhibitors. However, there are few methods to discover new cysteine-reactive inhibitors for enzymes for which reversible binding scaffolds are not known. To this end, we rationally designed a chemical system to attach a...
- Keyword:
- Electrophile, Covalent, Fragment, Ubiquitin, and Nedd4-1
- Subject:
- Chemistry
- Creator:
- Stefan Kathman
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/19/2018
- Date Modified:
- 02/19/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- Metalloporphyrins fulfill incredibly diverse chemical roles in biology and photocatalysis, where they act as photosensitizers, redox sites, substrate binding sites, and facilitators of long range electron transfer. Metalloporphyrin chemistry is uniquely tuneable through conformation and functionalization of the porphyrin ring, choice of metal, and interaction with the environment as these...
- Keyword:
- Pump-probe spectroscopy, Structural dynamics, Hemoprotein, Metalloporphyrin, X-ray Absorption Spectroscopy, and X-ray free electron laser
- Subject:
- Chemistry
- Creator:
- Megan Lynn Shelby
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/19/2018
- Date Modified:
- 02/19/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- Surface-enhanced Raman spectroscopy (SERS) is a powerful technique for characterizing molecular systems. It combines the chemical selectivity of vibrational spectroscopy with plasmonic signal enhancement to achieve the ultimate limit of detection--a single molecule. By overcoming the effects of ensemble averaging, single molecule SERS (SMSERS) probes distributions in molecular interactions and...
- Keyword:
- hot spots, SMSERS, SERS, and Single Molecule
- Subject:
- Chemistry
- Creator:
- Alyssa Zrimsek
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/19/2018
- Date Modified:
- 02/19/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- Interprotein electron transfer (ET) occupies a central role in both chemistry and biology, as it is important in a variety of functions including cellular respiration, metabolism, and energy transduction during photosynthesis. Consequently, understanding the protein-protein recognition and docking that controls interprotein ET is an important field of scientific research. One...
- Keyword:
- myoglobin, electron transfer, and protein binding
- Subject:
- Chemistry
- Creator:
- Jon Vander Woude
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/21/2018
- Date Modified:
- 02/21/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- Raman spectroscopy is an established and versatile molecular sensing technique, but it is limited by its modest chemical sensitivity. Surface-enhanced Raman spectroscopy (SERS) can amplify otherwise weak normal Raman signals up to nine to ten orders of magnitude, giving rise to its application in many molecular sensing problems, including those...
- Keyword:
- electrochemistry, Raman spectroscopy, SERS, and spectroelectrochemistry
- Subject:
- Chemistry
- Creator:
- Stephanie Zaleski
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/26/2018
- Date Modified:
- 02/26/2018
- Date Created:
- 2016-01-01
- Resource Type:
- Dissertation
-
- Description:
- Organic photovoltaics (OPVs) are an attractive solar energy technology for low-current applications. Herein is described the supramolecular design and methodology to manipulate intermolecular interactions in order to create an active layer in OPVs devices composed of crystalline and amorphous donor-acceptor domains, which has been proposed as the ideal morphology for...
- Keyword:
- Organic Solar Cella, Hydrogen-bonding, and Supramolecular
- Subject:
- Chemistry
- Creator:
- Leonel Barreda
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/27/2018
- Date Modified:
- 02/27/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- With the dual challenges of meeting global energy demand and mitigating anthropogenic climate change, significant effort is being applied to generating power from renewable sources. The dye-sensitized solar cell (DSC) is a photovoltaic technology capable of generating electricity from sunlight, but suffers losses in efficiency due to deleterious electron transfer...
- Keyword:
- Alternative Energy, Material Science, and Physical Chemistry
- Subject:
- Chemistry
- Creator:
- William L. Hoffeditz
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 03/13/2018
- Date Modified:
- 03/13/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Halide perovskites, AMX3 (A = monocation, B = Ge, Sn, or Pb, and X = halogen), present a versatile class of solution-processable semiconductors made from earth abundant materials with outstanding electrical and optical properties. Their solar cell efficiencies have dramatically increased from ~9% to ~22% in less than five years...
- Keyword:
- solar cells, semiconductors, halide perovskites, and two-dimensional
- Subject:
- Chemistry
- Creator:
- Duyen Hanh Cao
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/02/2018
- Date Modified:
- 04/02/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Ultrafast spectroscopy offers an unprecedented view on the dynamic nature of chemical reactions. From charge transfer in semiconductors to folding and isomerization of proteins, these all important processes can now be monitored and in some instances even controlled on real, physical timescales. One of the biggest challenges of ultrafast science...
- Keyword:
- Microscopy, Perovskite, Spectroscopy, Compressed Sensing, and Interferometry
- Subject:
- Chemistry
- Creator:
- Boris Spokoyny
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/18/2018
- Date Modified:
- 04/18/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Climate change may be one of the most important puzzles the world has attempted to solve and one of the greatest challenges in this area is to improve our understanding of how atmospheric aerosol particles impact climate processes. We seek to overcome this challenge by focusing on the chemistry and...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Mary Alice Upshur
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/26/2018
- Date Modified:
- 04/26/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- This dissertation describes the relationship between the surface chemistry of colloidal semiconductor nanocrystals (quantum dots, QDs) and their optoelectronic properties, such as photoluminescence and degree of quantum confinement. We primarily focus our efforts on one particular subset of ligands known to couple strongly to the inorganic core of the QD...
- Keyword:
- exciton delocalization, nuclear magnetic resonance, quantum dot, ligand-ligand coupling, and dithiocabamate
- Subject:
- Chemistry
- Creator:
- Rachel Dory Harris
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/26/2018
- Date Modified:
- 04/26/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Understanding the nature of quantum effects in dense biological systems is of great interestto many scientists today. It seems that the question is not does quantum mechanics dictatebiological processes, but rather by how much and to what extent. A big challenge though in thisfield is how to properly test and...
- Keyword:
- Photosystem I, Stochastic Surrogate Hamiltonian, Redfield, Biology, and Quantum Mechanics
- Subject:
- Chemistry
- Creator:
- Daniel Douglas Powell
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/26/2018
- Date Modified:
- 04/26/2018
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- In Chapter 1, a series of "constrained geometry" organoactinide complexes, (CGC)An(NMe)2 (CGC = Me2Si(h5-Me4C5)(tBuN); An = Th, 1; U, 2), prepared via efficient in situ, two-step protodeamination routes in good yields and high purity, is presented. Both 1 and 2 are quantitatively converted to the neutrally charged, solvent-free dihalides (1-Cl2,...
- Keyword:
- Chemistry and Inorganic (0488)
- Subject:
- Chemistry
- Creator:
- Bryan D Stubbert
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/07/2018
- Date Modified:
- 05/07/2018
- Date Created:
- 2006-12-05
- Resource Type:
- Dissertation
-
- Description:
- Four series of doped CdO thin films have been grown on both amorphous glass and single-crystal MgO(100) substrates by metal-organic chemical vapor deposition (MOCVD), and their phase structure, microstructure, electrical, and optical properties investigated. Epitaxial films grown on single-crystal MgO(100) exhibit biaxial, highly textured microstructures. These as-deposited doped CdO thin...
- Keyword:
- epitaxial, doping, CdO, TCO, MOCVD, and Thin films
- Subject:
- Chemistry
- Creator:
- Shu Jin
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/07/2018
- Date Modified:
- 05/07/2018
- Date Created:
- 2006-06-20
- Resource Type:
- Dissertation
-
- Description:
- Counteranion effects on the rate and stereochemistry of propylene polymerization mediated by ion-pair complexes derived from dimethylzirconocene precatalysts activated with strongly Lewis-acidic perfluoroarylmetalloid cocatalyst/activators are shown to arise from the strength of the cation-anion interaction. This is quantified using CS-symmetric Me2C(Cp)(Flu)ZrMe2 (Cp = C5H4, η5 cyclopentadienyl; Flu = C13H8, η5...
- Keyword:
- cocatalyst, polyolefin, microstructure, ion pair, metallocene, and polymerization
- Subject:
- Chemistry
- Creator:
- John Andrew Stevens Roberts
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/09/2018
- Date Modified:
- 05/09/2018
- Date Created:
- 2006-11-28
- Resource Type:
- Dissertation
-
- Description:
- Local structure determination in amorphous and disordered systems, which are crystallographically intractable, is critical for gaining an understanding of their properties. X-ray absorption spectroscopy (XAS) is an excellent tool for local structure determination in amorphous and disordered environmental materials. Amorphous manganese oxides produced by the freshwater bacterium Leptothrix discophora SP6...
- Keyword:
- Biogenic manganese oxides
- Subject:
- Chemistry
- Creator:
- Ian Saratovsky
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/10/2018
- Date Modified:
- 05/10/2018
- Date Created:
- 2006-12-22
- Resource Type:
- Dissertation
-
- Description:
- Two new strategies have been developed to accomplish direct nucleophilic acylation reactions. In the first approach, acylsilanes are added to various electrophiles using N-heterocyclic carbenes as catalysts. The second method utilizes O-silyl thiazolium carbinols as stoichiometric acyl anion precursors to afford acylated products under mild reaction conditions. N-heterocyclic carbenes generated...
- Keyword:
- Nucleophilic Acylation, Acyl anion, N-Heterocyclic carbene, and Thiazolium
- Subject:
- Chemistry
- Creator:
- Anita Mattson
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/14/2018
- Date Modified:
- 05/14/2018
- Date Created:
- 2007-04-05
- Resource Type:
- Dissertation
-
- Description:
- High relaxivity contrast agents are of great importance in the advancement of magnetic resonance imaging diagnostics for use in biomaterials. Biomaterials that are implanted into the body, with the goal of repairing or regenerating lost or damaged tissue, need to be tracked noninvasively, over time. I have completed work using...
- Keyword:
- self-assembly, dumbbell, peptide amphiphile, templation, and MRI
- Subject:
- Chemistry
- Creator:
- Steve Bull
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/30/2018
- Date Modified:
- 05/30/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- A catalytic, multi-component coupling reaction for the synthesis of nitrogen-containing heterocycles has been developed, via the reaction of an imine, α-diazoester and unsaturated coupling partner in the presence of a copper(I) or rhodium(II) transition metal catalyst with excellent diastereo-selectivities and high yields. The transition metal-catalyzed decomposition of a diazo compound...
- Keyword:
- Chemistry and Organic
- Subject:
- Chemistry
- Creator:
- Chris Galliford
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/01/2018
- Date Modified:
- 06/01/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- The [(salen)CrCl + LB] catalyst system was found to be a highly active catalyst system for the [aziridine + CO<sub>2</sub>] coupling reaction, and exhibited a marked preference for the formation of 5-substituted oxazolidinone product, especially in the absence of cocatalyst. The activity of this catalyst system is optimized by modifying...
- Keyword:
- Chemistry and Organic
- Subject:
- Chemistry
- Creator:
- Aaron W Miller
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/05/2018
- Date Modified:
- 06/05/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- The work described here includes both fundamental and application based studies centered around the use of plasmonic sensors. Fundamental studies focus on probing the optical properties of nanosphere lithography (NSL) fabricated Ag nanoparticles, while surface-enhanced Raman spectroscopy (SERS) sensors are applied to identify and characterize artists' red dye and red...
- Keyword:
- Chemistry and Physical Chemistry
- Subject:
- Chemistry
- Creator:
- Alyson Victoria Whitney
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/05/2018
- Date Modified:
- 06/05/2018
- Date Created:
- 2007-05-08
- Resource Type:
- Dissertation
-
- Description:
- UV Raman spectroscopy is a powerful tool to investigate hydrocarbons-zeolite systems, including the coke formation mechanism during MTH reactions, the sorbet-framework interactions and the quantitative analysis of catalytic reactions. First, methanol, dimethyl ether and ethylene reactions were carried out on H-MFI with different Si/Al atomic ratios to study the coke...
- Keyword:
- Quantitative Raman Analysis, UV Raman, Coke, Benzene in MFI, and MTH
- Subject:
- Chemistry
- Creator:
- Chao Zhang
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/05/2018
- Date Modified:
- 06/05/2018
- Date Created:
- 2007-05-10
- Resource Type:
- Dissertation
-
- Description:
- This dissertation describes the development and use of novel chemical affinity templates to direct the assembly and preserve the activity of biological molecules in surface- and solution-based biomolecular assays. The majority of work described herein focuses on advancing biological nanoarray technology to enable the study of fundamentally important biological processes...
- Keyword:
- biorecognition, metal ions, surface, nanoarrays, microscopy, scanning, probe, and viruses
- Subject:
- Chemistry
- Creator:
- Rafael Angel Vega
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/05/2018
- Date Modified:
- 06/05/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- The porphyrazines (pzs), a class of porphyrin derivatives, have shown potential as therapeutic and imaging agents due to a combination of their near-IR absorbance/fluorescence and their enhanced chemical flexibility. Cell viability/proliferation assays and fluorescence microscopy were carried out in both tumor and normal cells to characterize the biological activity of...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Hong Zong
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/25/2018
- Date Modified:
- 06/25/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- Part 1. The complex folded structures associated with RNA allow for specific protein-RNA interactions and also create binding sites for small molecules. Developing organic molecules that can bind RNA with high affinity and specificity is a challenge that must be overcome for RNA to be considered a viable drug target....
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Graham R Lawton
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/26/2018
- Date Modified:
- 06/26/2018
- Date Created:
- 2007-05-03
- Resource Type:
- Dissertation
-
- Description:
- This thesis consists of the synthesis and photophysical characterization of chlorophyll- and porphyrin- based multichromophore arrays designed for the purpose of studying energy and charge transfer therein. The first series of arrays consists of donor-acceptor dyads in which various arylene diimide electron acceptors are attached through a phenyl group to...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Richard Forrest Kelley
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/26/2018
- Date Modified:
- 06/26/2018
- Date Created:
- 2007-05-11
- Resource Type:
- Dissertation
-
- Description:
- Theoretical studies on electronic structure governing charge transport properties are investigated to understand and improve the prediction of electron charge carrier organic semiconductors used in field-effect transistors. Perfluorinated oligothiophene semiconductors have shown experimental n-type behavior, but placement of fluorinated aryl groups changes charge polarities. Models were developed to investigate how...
- Keyword:
- Physical and Chemistry
- Subject:
- Chemistry
- Creator:
- Sharon E Koh
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 06/27/2018
- Date Modified:
- 06/27/2018
- Date Created:
- 2007-05-14
- Resource Type:
- Dissertation
-
- Description:
- The work presented in this dissertation is centered on experimental efforts to maximize the sensitivity of surface-enhanced Raman spectroscopy (SERS) and tip-enhanced Raman spectroscopy (TERS) toward their application in ultrasensitive nanoscale chemical analysis. The work focuses on fundamental studies of the plasmonic properties of silver nanostructures, and how those properties...
- Keyword:
- tip-enhanced raman, nanoparticles, surface-enhanced raman, nanotechnology, and plasmonics
- Subject:
- Chemistry
- Creator:
- Matthew A. Young
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 07/30/2018
- Date Modified:
- 07/30/2018
- Date Created:
- 05-14-2007
- Resource Type:
- Dissertation
-
- Description:
- The work presented here describes investigations into the optical properties of single silver nanoparticles. The contents of this thesis are divided into two parts: (1) single nanoparticle localized surface plasmon resonance (LSPR) spectroscopy and sensing and (2) approaches to combining LSPR spectroscopy with atomic force and transmission electron microscopies. Part...
- Keyword:
- Physical and Chemistry
- Subject:
- Chemistry
- Creator:
- Leif Jorstad Sherry
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 07/30/2018
- Date Modified:
- 07/30/2018
- Date Created:
- 05-21-2007
- Resource Type:
- Dissertation
-
- Description:
- Nanoplasmonics is an emerging branch of photonics that studies the optical properties of noble metals. Nanostructured noble metal materials, which can strongly interact with light and support various plasmon modes, are exceptional candidates for nanophotonic devices. This work describes the latest advances in the fabrication of ordered silver nanoparticles or...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Erin McLellan
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/01/2018
- Date Modified:
- 08/01/2018
- Date Created:
- 06-21-2007
- Resource Type:
- Dissertation
-
- Description:
- Alkenylsilanes of varying chain lengths are investigated as simultaneous chain transfer agents + comonomers in organotitanium-mediated olefin polymerization processes. Ethylene + alkenylsilane polymerizations were carried out with activated Me2Si(Me4C5)(NtBu)TiMe2 and (-CH2CH2-3,3'){(5-indenyl )[1-Me2Si(tBuN)]}2Ti2Me4 precatalysts. Alkenylsilane incorporation levels follow the trend C8H15SiH3 < C6H11SiH3 ≈ C4H7SiH3 < C3H5SiH3. Long-chain branching levels versus...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Smruti Amin
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/01/2018
- Date Modified:
- 08/01/2018
- Date Created:
- 2007-08-29
- Resource Type:
- Dissertation
-
- Description:
- This dissertation covers the synthesis and study of peptide nucleic acids (PNAs), specifically, derivatives of PNA containing amine-bearing sidechains or cyclopentane portions. PNAs are non-natural nucleic acids that have far reaching potential in therapeutics and nucleic acid detection. Despite immense potential and widespread application, improving on the design and applications...
- Keyword:
- Chemistry and Organic
- Subject:
- Chemistry
- Creator:
- Ethan Andrew Englund
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/06/2018
- Date Modified:
- 08/06/2018
- Date Created:
- 2007-10-08
- Resource Type:
- Dissertation
-
- Description:
- Direct dynamics quasiclassical trajectory (QCT) calculations are performed to study the dynamics of model atom + polyatom reactions. In the first part of this thesis, we examine adiabatic dynamics of H/O reaction with simple alkanes, CD4 and C2H6. Overall good agreement with state-of-the-art experiments shows that the molecular motion is...
- Keyword:
- Physical and Chemistry
- Subject:
- Chemistry
- Creator:
- Wenfang Hu
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/06/2018
- Date Modified:
- 08/06/2018
- Date Created:
- 2007-09-26
- Resource Type:
- Dissertation
-
- Description:
- Small molecule organic materials based on perylene- and naphthalene- diimide are synthesized and characterized for use as semiconductor thin films in organic field-effect transistors. The orbital energetics of the materials are investigated via electrochemical, spectroscopic, and computational techniques. The thin film solids are characterized by x-ray diffraction techniques and surface...
- Keyword:
- Air-stable, Perylene Diimide, n-Type, Semiconductor, and Organic Electronics
- Subject:
- Chemistry
- Creator:
- Brooks A Jones
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/07/2018
- Date Modified:
- 08/07/2018
- Date Created:
- 2007-09-21
- Resource Type:
- Dissertation
-
- Description:
- Metal oxide surfaces are generally recognized as active substrates for many catalytic reactions. Density Functional Theory (DFT) has been found as a useful computational tool to investigate the geometry, energy, electronic structure of reactive oxide surfaces and their interaction with small molecules and fragments. In this thesis, primary efforts have...
- Keyword:
- DFT
- Subject:
- Chemistry
- Creator:
- Xiaoyan Ma
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/13/2018
- Date Modified:
- 08/13/2018
- Date Created:
- 2007-07-06
- Resource Type:
- Dissertation
-
- Description:
- Okilactomycin and chrolactomycin are antitumor antibiotics isolated in 1987 and 2001, respectively. These tetracyclic natural products possess a unique 6-5 fused tetrahydropyrone-butyrolactone. The spirocenter is part of a highly functionalized cyclohexene ring, which together with the aforementioned 6-5 system compose the core of these molecules. A six carbon, 1,3-dialkyl-substituted carbon...
- Keyword:
- natural products and total synthesis
- Subject:
- Chemistry
- Creator:
- William Joseph Morris
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/13/2018
- Date Modified:
- 08/13/2018
- Date Created:
- 2007-06-26
- Resource Type:
- Dissertation
-
- Description:
- Surfaces and interfaces, which are ubiquitous in the environment, control the mobility,speciation, and ultimate fate of groundwater species. The presented work provides insight into the interfacial behavior of three environmental pollutants: hexavalent chromium, oxytetracycline, and morantel. Model surfaces are employed for these studies, including (1-102) α-Al<sub>2</sub>O<sub>3</sub> and a carboxylic acid-terminated...
- Keyword:
- Physical and Chemistry
- Subject:
- Chemistry
- Creator:
- Michael Joseph Musorrafiti
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/13/2018
- Date Modified:
- 08/13/2018
- Date Created:
- 2007-08-22
- Resource Type:
- Dissertation
-
- Description:
- This dissertation describes the invention and development of a new nanolithographic method: On-Wire Lithography (OWL). OWL is a simple, reproducible, and high-throughput procedure for the synthesis and lithographic processing of metal nanowires (i.e. Au, Ag, Pt, Ni, and Cu) that allows researchers to control the morphology and feature size of...
- Keyword:
- Inorganic and Chemistry
- Subject:
- Chemistry
- Creator:
- Lidong Qin
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/13/2018
- Date Modified:
- 08/13/2018
- Date Created:
- 2007-10-01
- Resource Type:
- Dissertation
-
- Description:
- The overarching theme of this thesis is the development of non-natural oligomers for use in biological applications. Chapter I details the synthesis and studies of modified peptide nucleic acid (PNA) oligomers. PNA is a synthetic oligonucleotide mimic that binds to natural nucleic acids with extremely high affinity and specificity, making...
- Keyword:
- Chemistry and Organic
- Subject:
- Chemistry
- Creator:
- Jonathan K Pokorski
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/13/2018
- Date Modified:
- 08/13/2018
- Date Created:
- 2007-07-30
- Resource Type:
- Dissertation
-
- Description:
- Preventing the build-up of indoor pollutants represents an emerging goal in environmental chemistry. Heterogeneous catalysis provides an attractive method of remediating indoor air pollution, but optimization through rational catalyst design requires a detailed understanding of the catalytic surface and surface-pollutant interactions. In this work, a chemical ionization mass spectrometry (CIMS)...
- Keyword:
- Indoor air pollution, TiO2, chemical ionization mass spectrometry, environmental remediation, and acetone
- Subject:
- Chemistry
- Creator:
- Catherine Margaret Schmidt
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/14/2018
- Date Modified:
- 08/14/2018
- Date Created:
- 2007-09-04
- Resource Type:
- Dissertation
-
- Description:
- Interfaces and surfaces are ubiquitous in the environment. Heterogeneous binding events and reactions control the transport and speciation of dissolved pollutants in groundwater. Many heterogeneous processes occur at mineral oxide/water interfaces, and can be controlled either by the mineral oxide, or organic molecules bound to the surface. The prevalent natural...
- Keyword:
- morantel, second harmonic generation, manganese, surfaces, SiO2, and carboxylic acid
- Subject:
- Chemistry
- Creator:
- Christopher Thomas Konek
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/16/2018
- Date Modified:
- 08/16/2018
- Date Created:
- 2007-08-09
- Resource Type:
- Dissertation
-
- Description:
- The first section of this thesis focuses on applications of DNA-modified gold nanoparticles (AuNPs) while the second part addresses the fundamental properties that arise from conjugating DNA to inorganic AuNPs. Two types of applications are discussed. The first application utilizes the colorimetric properties of AuNPs to screen duplex and triplex...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Abigail K. R. Lytton-Jean
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/27/2018
- Date Modified:
- 08/27/2018
- Date Created:
- 2007-11-07
- Resource Type:
- Dissertation
-
- Description:
- This dissertation focuses on the utilization of two coordination chemistry-based synthetic approaches, which provide the ability to rapidly and quantitatively assemble sophisticated supramolecular cofacial porphyrin complexes. Significantly, by adopting a coordination chemistry-based approach, the porphyrin-porphyrin interactions can be regulated in situ via the addition or removal of chemical effector molecules....
- Keyword:
- Allosteric, Coordination Chemistry, and Allosterism
- Subject:
- Chemistry
- Creator:
- Christopher Gordon Oliveri
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/27/2018
- Date Modified:
- 08/27/2018
- Date Created:
- 2007-11-14
- Resource Type:
- Dissertation
-
- Description:
- Two new methods have been developed employing silicon-containing molecules in novel organic transformations. The first strategy utilizes Lewis base-activation of triethoxysilylalkynes to deliver mild acetylide nucleophile equivalents. The second approach involves the use of enolate additions to acylsilanes to generate β-silyloxy homoenolate intermediates. Lewis base-catalyzed activation of triethoxysilylalkynes promotes the...
- Keyword:
- Organic Chemistry
- Subject:
- Chemistry
- Creator:
- Robert B. Lettan ii
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/27/2018
- Date Modified:
- 08/27/2018
- Date Created:
- 2007-07-17
- Resource Type:
- Dissertation
-
- Description:
- The work presented in this thesis describes investigations into linear and nonlinear optical properties of two-dimensional silver nanoparticle arrays. The linear optical measurements - extinction measurements were performed on two-dimensional square arrays of L-shaped silver nanoparticles fabricated by electron beam lithography in order to study the effect of dipole coupling...
- Keyword:
- Physical and Chemistry
- Subject:
- Chemistry
- Creator:
- Jiha Sung
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/27/2018
- Date Modified:
- 08/27/2018
- Date Created:
- 2007-09-27
- Resource Type:
- Dissertation
-
- Description:
- This dissertation describes the use of alkanethiols and polymers for the development of lithographic affinity and resist array templates that can be utilized for directing the assembly of biological molecules, for building up multilayered polyelectrolyte thin films, and for fabricating metal solid-state nanostructures. The first two chapters of the work...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Raymond Jose de Guia Sanedrin
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/27/2018
- Date Modified:
- 08/27/2018
- Date Created:
- 2007-12-05
- Resource Type:
- Dissertation
-
- Description:
- Theoretical analysis of DNA bridge-mediated electron transfer (ET) led to the proposal that photoinduced ET might occur via either superexchange or hopping mechanisms. Electron transfer has been proposed to occur via a superexchange mechanism at short distances and via a hopping mechanism at longer distances. However, a crossover in mechanism...
- Keyword:
- Chemistry and Organic
- Subject:
- Chemistry
- Creator:
- Hui he Zhu
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/28/2018
- Date Modified:
- 08/28/2018
- Date Created:
- 2007-11-29
- Resource Type:
- Dissertation
-
- Description:
- The contents of this dissertation are divided into two sections: (1) the preparation and characterization of quaternary rare-earth chalcogenides and oxychalcogenides and (2) the localized surface plasmon resonance (LSPR) spectroscopy of metallic nanoparticles fabricated by nanosphere lithography (NSL). Single crystals of CsTmCoS3, CsYbCoS3, CsHoCoSe3, CsYbCoSe3, and CsYbZnSe3 have been prepared...
- Keyword:
- Rare-earths, Nanosphere Lithography, Crystal Structure, Magnetic Properties, Localized Surface Plasmon Resonance, and Optical Properties
- Subject:
- Chemistry
- Creator:
- George Hanki Chan
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/28/2018
- Date Modified:
- 08/28/2018
- Date Created:
- 2007-12-05
- Resource Type:
- Dissertation
-
- Description:
- The work described in this dissertation focuses on the optical characterization of micron-sized structures with mesoscale (100-1000 nm) features to investigate of the optical analog to the quantum corral. Lithographically patterned arrays of metallic rings and ellipses were used to study how light can be manipulated and confined within these...
- Keyword:
- Physical Chemistry
- Subject:
- Chemistry
- Creator:
- Yelizaveta Babayan
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/28/2018
- Date Modified:
- 08/28/2018
- Date Created:
- 2007-12-10
- Resource Type:
- Dissertation
-
- Description:
- This thesis attempts a combined theoretical/experimental investigation of two fundamental scaling laws in charge transfer reactions: how the rate of those reactions varies as a function of distance between an electron donor and an electron acceptor and how the rate varies as a function of the number of distinct pathways...
- Keyword:
- molecular electronics, donor bridge acceptor, dephasing, multiple pathways, charge transfer, and bicyclooctane
- Subject:
- Chemistry
- Creator:
- Randall Howard Goldsmith
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-07
- Resource Type:
- Dissertation
-
- Description:
- This thesis investigates singlet exciton fission, a physical process that converts one singlet exciton to a pair of triplet excitons. Singlet fission was discovered nearly forty years ago, but the mechanism for this process is still not well understood. Recent work has suggested that singlet fission may be capable of...
- Keyword:
- Solar Cell, Singlet Exciton Fission, and Theory
- Subject:
- Chemistry
- Creator:
- Eric Greyson
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-11
- Resource Type:
- Dissertation
-
- Description:
- Metallic nanostructures are able to confine and manipulate electromagnetic fields because light can couple to free electron oscillations called surface plasmons (SPs). These plasmons exist on metal surfaces as localized (short-range) or as propagating (long-range) modes depending upon the size and geometry of the nanostructure. This dichotomy is primarily an...
- Keyword:
- plasmon, nanoscience, nanoparticle, Metamaterials, subwavelength holes, and nanopatterning
- Subject:
- Chemistry
- Creator:
- Joel Henzie
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-10
- Resource Type:
- Dissertation
-
- Description:
- This thesis summarizes our research efforts on the application of the nano-structured anodic aluminum oxide (AAO) membrane in heterogeneous catalysis. Procedures for growing the AAO membrane in the center of an aluminum disc have been developed by appropriately masking the disk's perimeter during the anodization and etching steps. The remaining...
- Keyword:
- Physical Chemistry
- Subject:
- Chemistry
- Creator:
- Hao Feng
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-10
- Resource Type:
- Dissertation
-
- Description:
- Chemical vapor deposition (CVD) is a well-developed technique for growing thin films of a wide variety of materials, which relies on the development of new and better performing metal-organic precursors. To this end, three studies have been conducted into the compatibility of sulfur and phosphine containing ligands with low- and...
- Keyword:
- Inorganic Chemistry
- Subject:
- Chemistry
- Creator:
- Matthew McCain
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-13
- Resource Type:
- Dissertation
-
- Description:
- Conjugated organic molecules and polymers hold significant promise for use as active materials in electronic devices. Employing such "soft" materials can decrease cost of device fabrication, while enabling unique properties such as mechanical flexibility, large-area coverage, and highly tunable materials properties. A primary roadblock to the realization of this dream...
- Keyword:
- n-channel FET, multiple trapping and release, computationally-aided, and organic semiconductor
- Subject:
- Chemistry
- Creator:
- Joseph Adam Letizia
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/29/2018
- Date Modified:
- 08/29/2018
- Date Created:
- 2007-12-11
- Resource Type:
- Dissertation
-
- Description:
- Metal nanoprisms are a novel class of anisotropic nanomaterials with unique optical properties dependent on their size, shape, and composition. Silver nanoprisms are of particular interest because their surface plasmon resonance bands are readily tunable in the visible and near-IR region. The objectives of this thesis research focus on photochemical...
- Keyword:
- Inorganic Chemistry
- Subject:
- Chemistry
- Creator:
- Can Xue
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 08/30/2018
- Date Modified:
- 08/30/2018
- Date Created:
- 2007-12-10
- Resource Type:
- Dissertation
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