This introductory chemistry textbook was compiled by Shelby Hatch at Northwestern University and is adapted from the following sources:
"Introductory Chemistry" by David W. Ball, The Saylor Foundation, Cleveland State University, is licensed
under CC BY-NC-SA 4.0 and is available at https://open.umn.edu/opentextbooks/textbooks/introductory-chemistry ; "Chemistry of Cooking" by Sorangel Rodriguez-Velazquez, American...
Electrochemical cell devices are increasingly being sought for energy conversion and storage applications due to their high efficiencies and their potential for operating free of greenhouse gas (GHG) emissions. Solid Acid Electrochemical Cells (SAECs), which most commonly employ CsH2PO4 (CDP) as the electrolyte component, are uniquely suited to meet the...
The work of this dissertation seeks to enhance the understanding of DNA-driven nanoparticle assembly and introduce kinetic routes to control mesoscale crystal habit and size. Chapter 1 describes the state of the art in the field of nanoparticle assembly and, specifically, DNA- mediated nanoparticle assembly, where the concept of a...
Techniques in atomic physics have delivered some of the most precise measurements ever made, with frequency measurements reaching fractional precisions of 10^18 . High precision measurements can be used to test fundamental physics, such as pursuing a variation in fundamental constants. A finite drift in measurable constants such as the...
Synthetic organic chemistry continues to be a driver in the discovery and development of new molecules for applications in biology, medicine, crop science, polymer science, and materials science. Central to the continued development of this field is the pursuit of new strategies and methods for the efficient construction of molecules...
Small molecules such as indanes, chromanes, tetralins and their derivatives play a significant role in drug discovery due to their potent biological activity. This research herein presents a facile Brønsted acid-catalyzed allylsilane annulation methodology to generate fused ring systems such as indanes. The reaction goes through a homoallylic intermediate which...
In this dissertation, efforts are detailed to utilize semiquinoid bridging ligands to impart strong magnetic coupling between metal centers. Chapter 1 introduces the synthetic challenge of realizing molecule-based magnets with high operating temperatures due to weak magnetic coupling between spin centers through large, diamagnetic ligands. An alternative strategy is described...
This dissertation develops computational models to study the optical coupling between plasmonic nanoparticles and quantum emitters. A large number of nanophotonic applications function by using either plasmon enhanced fields to enhance optical processes within quantum emitters or the sensitivity of plasmon resonances to their environment. Developing computational methods to fully...
Nonlinear optical (NLO) effects are used universally in modern day telecommunication and form the foundation of emergent photonic technologies. Twisted intramolecular charge transfer (TICT) chromophores, composed of a donor and acceptor fragment connected by a twisted bi-aryl bridge, combine large molecular NLO response with properties such as transparency in the...
Bimetallic polymerization catalysis represents a small, though active, area of research due largely to the interesting properties observed in the resulting product polymers, including higher molecular weight, increased comonomer incorporation, and enhanced tacticity. Current work is focused on furthering an understanding of the active catalytic species that give rise to...