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- Description:
- Contained in the following dissertation are detailed investigations regarding the thermodynamics of small molecule activation by metalloporphyrin complexes isolated within metal-organic frameworks (MOFs). Chapter 1 provides a description of the role metalloporphyrin complexes play in biological systems and the challenges associated with studying small molecule activation by metalloporphryin sites in...
- Keyword:
- Inorganic Chemistry
- Subject:
- Chemistry
- Creator:
- Audrey Theresa Gallagher
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/10/2019
- Date Modified:
- 01/10/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Small hydrocarbons and their oxygenated derivatives are critical to atmospheric organic aerosol formation and growth. Secondary organic aerosols (SOAs) constitute a significant portion of total atmospheric organic aerosols, and are often generated through the oxidation of biogenic volatile organic compounds (VOCs) such as isoprene, -pinene, and -caryophyllene. Interfaces of SOA...
- Keyword:
- aerosol, hydrocarbons, orientations, nonlinear optics, and computation
- Subject:
- Chemistry
- Creator:
- Hilary Marie Chase
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/11/2019
- Date Modified:
- 01/11/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- The electronic spin state (S) of metal ions is fundamental to the performance of magnets, protein cofactors, and magnetic resonance imaging (MRI) contrast agents. The ability to manipulate the spin state of transition metals allows for the development of advanced materials with emergent properties. This following chapters will introduce two...
- Keyword:
- Spin Crossover, spin state, Magnetism, MRI, Double Exchange, and Iron
- Subject:
- Chemistry
- Creator:
- Alexandra I. Gaudette
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/11/2019
- Date Modified:
- 01/11/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Starting materials for natural products, ideally synthesized using low-cost, highly active and selective catalysts, are of great interest to the pharmaceutical industry. Relevant reactions include the synthesis of 1,2-dihydropyridines, reduction of ketones/aldehydes, cleavage of esters, and reduction of amides to amines. Hydroelementation is an important catalytic process that involves H-E...
- Keyword:
- Carbonyl reduction, Catalysis, Pyridine dearomatization, Hydroboration, and Organolanthanide
- Subject:
- Chemistry
- Creator:
- Victoria Lynn Weidner
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/11/2019
- Date Modified:
- 01/30/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- My research interests, which span organic, inorganic, physical and biochemistry, have focused broadly on photo-, magneto- and redox-active molecules, especially those with potential applications in organic photovoltaics, spintronics and electronics. My research under the joint supervision of Professor Wasielewski and Professor Fraser Stoddart has concentrated upon understanding electronic and magnetic...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Yilei Wu
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/16/2019
- Date Modified:
- 01/16/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- Photovoltaic technology can help meet the exploding world energy demand in a sustainable and environmentally friendly way. Organic photovoltaics (OPVs) are especially attractive because they can be constructed with low-cost organic content and are amenable to high-throughput large-scale fabrication techniques. Synthetic modification of organic semiconductors has paved way for the...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Amod Timalsina
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/18/2019
- Date Modified:
- 01/30/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- The expanding use of nanomaterials in consumer products challenges scientists to understand the impact of these materials before their inevitable release into the environment. In the same way that the widespread use of DDT and asbestos has caused unforeseen negative impacts on both the environment and on human health, the...
- Keyword:
- Nanomaterials, Sum Frequency Scattering, Sum Frequency Generation, Nano-Biointerface, and Nonlinear Optics
- Subject:
- Chemistry
- Creator:
- Laura Olenick
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 01/23/2019
- Date Modified:
- 01/23/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- The discovery and tailoring of new useful organic molecules for applications such as medicine and materials science is highly driven by meaningful developments in chemical methodology, and some of the most impactful advances have invoked catalysis to increase efficiency and specificity. N-heterocyclic carbenes (NHCs) have continuously occupied a prominent space...
- Keyword:
- N-Heterocyclic Carbene, borylation, NHC, boration, aminoboronic acids, and enantioselective catalysis
- Subject:
- Chemistry
- Creator:
- Charles Benjamin Schwamb
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 02/15/2019
- Date Modified:
- 02/15/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- The diverse reactivity patterns, unique structural features imparted by the cumulated double bonds, and possibility of axial chirality have garnered allenes considerable attention in organic synthesis. Numerous methods have been described in the literature to afford optically active allenes starting from chiral starting materials, yet catalytic and asymmetric methods to...
- Keyword:
- Allene, Asymmetric Organocatalysis, High-Throughput Screening, Hydrazone, and Petasis
- Subject:
- Chemistry
- Creator:
- Abdallah Bachir Diagne
- Owner:
- digitalpublishing@northwestern.edu
- Date Uploaded:
- 02/18/2019
- Date Modified:
- 02/18/2019
- Date Created:
- 2017-01-01
- Resource Type:
- Dissertation
-
- Description:
- High-pressure and -temperature synthesis is a powerful tool for synthesizing new intermetallic compounds that cannot be formed using traditional solid-state syntheses. Such metastable compounds can exhibit unrivaled structural complexity, unique bonding, and unusual properties. In the simplest case, there are many binary systems in which no intermetallic compounds are known....
- Keyword:
- intermetallic, properties, structure, synthesis, and high pressure
- Subject:
- Chemistry
- Creator:
- Samantha Marie Clark
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/03/2019
- Date Modified:
- 04/03/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Noncentrosymmetry (NCS) is a requirement for many properties such as piezoelectricity, pyroelectricity, and nonlinear optical activity like second harmonic generation which are desirable for a variety of commercial applications. One method which has been employed to successfully synthesize NCS compounds utilizes acentric anionic groups, such as oxyfluoride metal complexes, as...
- Keyword:
- noncentrosymmetry, crystallography, hydrogen bonding, and oxyfluorides
- Subject:
- Chemistry
- Creator:
- Jacqueline Renee Cantwell
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/03/2019
- Date Modified:
- 04/03/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- The projected increase in the use of nanomaterials raises concerns about adverse impacts new technologies utilizing these materials may have on the environment. These concerns can be addressed from a chemical perspective by studying how emerging nanomaterials interact with biological systems. Fundamentally, the key interactions for nanomaterial uptake into a...
- Keyword:
- Nanotechnology, Sustainable, Nano/Bio, Polymers, and Biomimetic
- Subject:
- Chemistry
- Creator:
- Alicia McGeachy
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/09/2019
- Date Modified:
- 04/09/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Organic Photovoltaic (OPV) materials are of great interest as a low-cost material the purposes of achieving wide spread, solar energy adoption. However, a limiting factor in materials development is the ability to proactively determine the active layer thin film morphology that largely informs device performance. Thus, understanding how materials design...
- Keyword:
- x-ray scattering, spin coating, in situ, GIWAXS, organic photovoltaics, and morphology
- Subject:
- Chemistry
- Creator:
- Eric Fridstein Manley
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/29/2019
- Date Modified:
- 04/29/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Organic Photovoltaic (OPV) materials are of great interest as a low-cost material the purposes of achieving wide spread, solar energy adoption. However, a limiting factor in materials development is the ability to proactively determine the active layer thin film morphology that largely informs device performance. Thus, understanding how materials design...
- Keyword:
- x-ray scattering, spin coating, in situ, GIWAXS, organic photovoltaics, and morphology
- Subject:
- Chemistry
- Creator:
- Eric Fridstein Manley
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 04/29/2019
- Date Modified:
- 04/29/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Fused polycyclic scaffolds with three-dimensional complexity from an array of stereocenters compose the core structures of countless natural product families with a variety of desirable biological activity. The development of synthetic methods and strategies to afford rapid access to these structures is essential to expose a wealth of untapped biological...
- Keyword:
- Organic Chemistry
- Subject:
- Chemistry
- Creator:
- Emily Elizabeth Robinson
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 05/06/2019
- Date Modified:
- 05/06/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Self-assembled monolayers as tunable chemical platforms broadly enable the study of the interaction between biological species and synthetic surfaces. Unlike small molecule chemistry where the freely diffusible product can interact with biological targets as an inhibitor or probe, interfacial chemistry allows for the controlled and multi-valent presentation of ligands to...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Pradeep Bugga
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 09/30/2019
- Date Modified:
- 09/30/2019
- Date Created:
- 1/1/2018
- Resource Type:
- Dissertation
-
- Description:
- Spherical nucleic acids (SNAs) are a class of structures composed of spherical nanoparticle cores that are densely functionalized with radially oriented, linear DNA. SNAs exhibit properties that are distinct from those of their linear counterparts. These constructs can readily enter cells, evade nuclease degradation, and bind complementary DNA targets with...
- Keyword:
- Nanoparticles, DNA, Hybridization, Thermodynamics, and Synthesis
- Subject:
- Chemistry
- Creator:
- Lam-Kiu Fong
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 09/30/2019
- Date Modified:
- 09/30/2019
- Date Created:
- 1/1/2018
- Resource Type:
- Dissertation
-
- Description:
- The objective of this work has been the design of new lubricant additives to target friction in the boundary lubrication regime and the hydrodynamic lubrication regime. Modern automotive engines operate at higher temperatures and speeds than ever before, and therefore require new and more effective lubricant additives to meet higher...
- Keyword:
- Viscosity Index Improver, Lubricant Additivex, Tribology, Friction Modifier, Antiwear Additive, and Fuel Efficiency
- Subject:
- Chemistry
- Creator:
- Michael Desanker
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 09/30/2019
- Date Modified:
- 09/30/2019
- Date Created:
- 1/1/2018
- Resource Type:
- Dissertation
-
- Description:
- Ultrafast, multi-dimensional coherent spectroscopy (MD-CS) has enabled scientists to probe fundamental aspects of chemical and photo-physical reactions on the nanosecond to femtosecond timescales. Using MD-CS, scientific contributions ranging from increased understanding of energy transfer in photosynthetic biological proteins to correlating the motion of electrons in semiconductors have been achieved. Concurrent...
- Keyword:
- Six-Wave Mixing, Nonlinear Optics, Photon-Echo Spectroscopy, Electronic-Vibrational Coupling, Chemical Physics, and Raman Spectroscopy
- Subject:
- Chemistry
- Creator:
- William Orin Hutson
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 09/30/2019
- Date Modified:
- 09/30/2019
- Date Created:
- 1/1/2018
- Resource Type:
- Dissertation
-
- Description:
- The thermodynamics and kinetics of electron transfer reactions in catalysis, energy conversion and storage, and plasmon-driven chemistry depend strongly on nanoscale electrode surface structure. To elucidate the structure-function relationships that determine nanoscale electrochemical reactivity, it is necessary to observe electron transfer reactions one molecule at a time. Over the past...
- Keyword:
- Nanoscale Electrochemistry and Tip-Enhanced Raman Spectroscopy
- Subject:
- Chemistry
- Creator:
- Michael Mattei
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/08/2019
- Date Modified:
- 10/08/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Bimetallic polymerization catalysis represents a small, though active, area of research due largely to the interesting properties observed in the resulting product polymers, including higher molecular weight, increased comonomer incorporation, and enhanced tacticity. Current work is focused on furthering an understanding of the active catalytic species that give rise to...
- Keyword:
- Polymerization, Olefin, Catalysis, Polyolefin, Organotitanium, and Binuclear
- Subject:
- Chemistry
- Creator:
- Anna Invergo
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/08/2019
- Date Modified:
- 10/08/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Nonlinear optical (NLO) effects are used universally in modern day telecommunication and form the foundation of emergent photonic technologies. Twisted intramolecular charge transfer (TICT) chromophores, composed of a donor and acceptor fragment connected by a twisted bi-aryl bridge, combine large molecular NLO response with properties such as transparency in the...
- Keyword:
- hyperpolarizability, electro optics, Nonlinear optics, charge transfer, and aggregation
- Subject:
- Chemistry
- Creator:
- Alexander Lou
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/08/2019
- Date Modified:
- 10/08/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Synthetic organic chemistry continues to be a driver in the discovery and development of new molecules for applications in biology, medicine, crop science, polymer science, and materials science. Central to the continued development of this field is the pursuit of new strategies and methods for the efficient construction of molecules...
- Keyword:
- Radical Coupling, Umpolung, Brook Rearrangement, Silymarin, Photoredox, and Photocatalysis
- Subject:
- Chemistry
- Creator:
- Benjamin McDonald
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/08/2019
- Date Modified:
- 11/19/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- This dissertation develops computational models to study the optical coupling between plasmonic nanoparticles and quantum emitters. A large number of nanophotonic applications function by using either plasmon enhanced fields to enhance optical processes within quantum emitters or the sensitivity of plasmon resonances to their environment. Developing computational methods to fully...
- Keyword:
- Quantum Dots, Plexcitons, Metal Nanoparticles, Plasmonics, Chiral Imprinting, and FDTD
- Subject:
- Chemistry
- Creator:
- Thomas Alexander Reichmanis Purcell
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/08/2019
- Date Modified:
- 10/08/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- In this dissertation, efforts are detailed to utilize semiquinoid bridging ligands to impart strong magnetic coupling between metal centers. Chapter 1 introduces the synthetic challenge of realizing molecule-based magnets with high operating temperatures due to weak magnetic coupling between spin centers through large, diamagnetic ligands. An alternative strategy is described...
- Keyword:
- Inorganic chemistry
- Subject:
- Chemistry
- Creator:
- Jordan DeGayner
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/14/2019
- Date Modified:
- 10/14/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Small molecules such as indanes, chromanes, tetralins and their derivatives play a significant role in drug discovery due to their potent biological activity. This research herein presents a facile Brønsted acid-catalyzed allylsilane annulation methodology to generate fused ring systems such as indanes. The reaction goes through a homoallylic intermediate which...
- Keyword:
- Chemistry
- Subject:
- Chemistry
- Creator:
- Weiwei Wang
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 10/14/2019
- Date Modified:
- 10/14/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Techniques in atomic physics have delivered some of the most precise measurements ever made, with frequency measurements reaching fractional precisions of 10^18 . High precision measurements can be used to test fundamental physics, such as pursuing a variation in fundamental constants. A finite drift in measurable constants such as the...
- Keyword:
- Physics
- Subject:
- Chemistry
- Creator:
- Mark Gabriel Kokish
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 11/19/2019
- Date Modified:
- 11/20/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- The work of this dissertation seeks to enhance the understanding of DNA-driven nanoparticle assembly and introduce kinetic routes to control mesoscale crystal habit and size. Chapter 1 describes the state of the art in the field of nanoparticle assembly and, specifically, DNA- mediated nanoparticle assembly, where the concept of a...
- Keyword:
- Single Crystal, Nanoparticle, Nucleation and Growth, Crystallization, , DNA, and Self-Assembly
- Subject:
- Chemistry
- Creator:
- So Young Eileen Seo
- Owner:
- Scholarly Digital Publishing
- Date Uploaded:
- 11/25/2019
- Date Modified:
- 11/25/2019
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
-
- Description:
- Extensive study of nanomaterial chemical and optical properties has enabled their integration into a variety of applications. However, less thoroughly investigated are the heat generation and dissipation processes of nanomaterials following optical excitation. These phenomena are of immense importance as thermal energy can distort a material’s structure, which has profound...
- Keyword:
- spectroscopy, quantum dots, nanoparticles, and plasmonics
- Subject:
- Chemistry
- Creator:
- Kirschner, Matthew S
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14600 and etdadmin_upload_661149
-
Quantum Teleportation of an Electron Spin State Mediated by a Photodriven Electron Transfer Reaction
- Description:
- This thesis describes a novel demonstration of quantum teleportation, a protocol within the broader field of quantum information science, carried out by an electron transfer reaction within a molecular system. As described in Chapter 1, quantum information science has potential impacts in computation, communication, and cryptography. This field relies on...
- Keyword:
- molecular spintronics, physical organic chemistry, photochemistry, and quantum information
- Subject:
- Chemistry
- Creator:
- Rugg, Brandon Kenneth
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14549 and etdadmin_upload_647075
-
- Description:
- Theoretical investigation of photochemical processes in molecules is a nontrivial task. Ab initio calculations that completely describe such processes are often intractable to perform given today’s hardware. Thus, to gain insight into common areas of interest, such as in transition metal photochemistry and organic photovoltaics, less accurate but more feasible...
- Subject:
- Chemistry
- Creator:
- Kelley, Matthew
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_631424 and http://dissertations.umi.com/northwestern:14486
-
- Description:
- The Controlled, Site-Isolated Synthesis of Polyelemental Nanostructures in Polymer Nanoreactors Pengcheng Chen Polyelemental nanoparticles are an attractive class of materials due to their potential applications, which span the fields of catalysis, plasmonics, electronics, magnetics, targeted drug delivery, and bio-imaging. However, conventional synthetic methods for such structures are limited, especially when...
- Keyword:
- Nanostructures, Catalysis, Nanoparticles, Polyelemental, Nanoreactors, and Polymer
- Subject:
- Inorganic chemistry, Chemistry, and Materials Science
- Creator:
- Chen, Pengcheng
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14466 and etdadmin_upload_627177
-
- Description:
- Organic semiconductors have shown great promise for optoelectronic applications, particularly solar photovoltaics. Critical to their success is the ability to understand and manipulate the relationship between molecular structure and bulk properties. Substantial progress on understanding structural influences on electronic properties has been made for the conjugated polymers and small molecules...
- Keyword:
- Aggregation, Ultrafast Spectroscopy, PTB7, Spectroscopy, Organic Semiconductor, and Organic Photovoltaic
- Subject:
- Physical chemistry, Chemistry, and Condensed matter physics
- Creator:
- Fauvell, Thomas James
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14521 and etdadmin_upload_639550
-
- Description:
- This thesis describes fundamental photophysical studies of quantum dot (QD)-molecule complexes, aimed at discovering strategies for enhancing the efficiency of QD-photocatalyzed and QD-sensitized multi-electron catalytic reactions, for the purpose of solar fuels production. Photosensitization of molecular catalysts that are active for reactions such as the reduction of carbon dioxide or...
- Keyword:
- Quantum Dots and Transient Absorption Spectroscopy
- Subject:
- Chemistry
- Creator:
- Lian, Shichen
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14490 and etdadmin_upload_633706
-
- Description:
- Organic semiconductors are an active area of research with great promise for delivering next generation electronics and clean energy technologies. As the field matures, understanding the connection between molecular structure, materials’ properties, and device performance will be critical in finding the right material for an intended application. An effective strategy...
- Keyword:
- solar cells, diketopyrrolopyrrole, transistors, organic semiconductors, polymers, and fluorination
- Subject:
- Chemistry and Materials Science
- Creator:
- Leonardi, Matthew John
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_660666 and http://dissertations.umi.com/northwestern:14589
-
- Description:
- Increasing industrialization and the resulting negative environmental impacts highlight the need to develop alternative renewable energy sources. The Sun is a massive source and organic solar cells are a growing field of study. As new materials are synthesized, the efficiencies of organic solar cells continue to grow, but without an...
- Keyword:
- x-ray scattering, transient absorption, and organic solar cell
- Subject:
- Physical chemistry, Chemistry, and Materials Science
- Creator:
- Lou, Sylvia Jen-Ming
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_626768 and http://dissertations.umi.com/northwestern:14458
-
- Description:
- This work combines the use of high-throughput mass spectrometry with peptide arrays for to monitor reactions on peptides. The Mrksich lab introduced a high-throughput, label-free, biochemical assay that relies on self-assembled monolayers on gold and matrix-assisted laser desorption/ionization mass spectrometry, termed SAMDI-MS. This dissertation introduces new applications of SAMDI-MS and...
- Keyword:
- High-throughput, SAMDI, Phosphatase, Mass spectrometry, and Peptide Arrays
- Subject:
- Chemistry and Biochemistry
- Creator:
- Szymczak, Lindsey Catherine
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14701 and etdadmin_upload_667038
-
- Description:
- One of the grand challenges in materials chemistry and nanochemistry is the development of functional materials through ordered, hierarchical structures using synthetic building blocks. Nature has done this through evolution of molecular components such as nucleic acids, saccharides, lipids, amino acids, and inorganic crystals. The precise spatial positioning of these...
- Keyword:
- Hierarchical Order, Responsive Materials, Peptide Amphiphiles, Self-Assembly, Materials chemistry, and Nanochemistry
- Subject:
- Chemistry and Materials Science
- Creator:
- Chin, Stacey Megan
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_639807 and http://dissertations.umi.com/northwestern:14525
-
- Description:
- The mammalian oocyte undergoes large fluctuations in zinc content as it matures from a prophase I arrested oocyte to a metaphase II egg and finally is fertilized to become a zygote. These changes in total zinc content are necessary for proper progression, as disruption to egg’s ability to acquire and...
- Subject:
- Chemistry
- Creator:
- Garwin, Seth
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_663081 and http://dissertations.umi.com/northwestern:14679
-
- Description:
- Surface-enhanced Raman scattering (SERS) spectroscopy has been demonstrated to be a powerful analytical tool. Its chemical specificity, rapidity, and portability make it an attractive technique for biosensing, but its application to this field has been limited by the fundamental distance dependence of the surface-enhancement effect. Many biological molecules of interest...
- Keyword:
- SERS and Biosensing
- Subject:
- Chemistry
- Creator:
- Vander Ende, Emma
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14691 and etdadmin_upload_665998
-
- Description:
- Hybrid Organic-inorganic halide perovskites are emerging semiconducting materials that have shown over 23% in power conversion efficiency (PCE) for solar cells. The most prominent materials, three-dimensional (3D) perovskites, have limited scope for structural engineering and exhibit instability when encounter with moisture and heat. Here, we focus on studying the structure-property...
- Keyword:
- Inorganic, Optoelectronics, and Hybrid Perovskite
- Subject:
- Chemistry
- Creator:
- Mao, Lingling
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_625542 and http://dissertations.umi.com/northwestern:14439
-
- Description:
- Many transcription factors (TFs) regulate oncogenic processes and are therefore desirable targets for drug intervention. However, few TF inhibitors have been developed to date due to a lack of specificity and few TF binding pockets. The Meade Lab has overcome these challenges by using cobalt-based complexes that disrupt Cys2His2 zinc...
- Keyword:
- cellular delivery, zinc finger, hedgehog pathway, coordination complex, cobalt complex, and transcription factor
- Subject:
- Nanoscience, Molecular biology, and Chemistry
- Creator:
- Bajema, Elizabeth Amber
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14453 and etdadmin_upload_626420
-
- Description:
- Oxidation is an important process in synthesizing a broad range of useful products such as polymers, pharmaceuticals, and fine chemicals. While H2O2 is a highly attractive oxidant for oxidative chemistry due to its high percentage of oxygen and environmentally friendly water byproduct, it is often used in excess due to...
- Keyword:
- Catalysis, hydrogen peroxide generation, oxidation, MOFs, and tandem reaction
- Subject:
- Chemistry
- Creator:
- Limvorapitux, Rungmai
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14696 and etdadmin_upload_666644
-
- Description:
- Atomic layer deposition (ALD) is a gas-phase synthesis technique employed to manufacture thin films and metallic nanoparticles of various compositions and sizes, as well as individual, isolated species on various supports. An understanding of the dynamic surface chemistry that takes place during various ALD processes is vitally important for achieving...
- Subject:
- Chemistry
- Creator:
- Hackler, Ryan Aaron
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14517 and etdadmin_upload_639131
-
- Description:
- Metal-organic frameworks (MOFs) are a class of highly modular materials with welldefined three-dimensional architectures, permanent porosity, and diverse chemical functionalities, which show promise for a wide range of applications, including gas storage and separation, drug delivery, chemical sensing, and catalysis. Nanoparticle forms of MOFs have similar properties but are dispersible...
- Keyword:
- DNA, Nanoparticle, Colloidal crystal engineering, Surface functionalization, and Metal-organic framework
- Subject:
- Chemistry
- Creator:
- Wang, Shunzhi
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14463 and etdadmin_upload_626973
-
- Description:
- Photovoltaic devices containing organic semiconducting chromophores are a promising technology for the conversion of solar energy into electricity. Research into the molecular design and processing of these materials has propelled the power conversion efficiency of laboratory-fabricated organic polymer solar cells (PSCs) to over 17%, which exceeds the 10% threshold deemed...
- Keyword:
- Green Chemistry, Conjugated Copolymers, Organic Semiconductors, Organic Solar Cells, Electron Acceptors, and Photovoltaics
- Subject:
- Chemistry
- Creator:
- Aldrich, Thomas Jordan
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14528 and etdadmin_upload_639853
-
- Description:
- Molecular self-assembly is a process in which molecules spontaneously form ordered aggregates, the process of which is important in the natural world, considering those ordered systems and complex architectures contained in a living cell. The goal of chemists is to design simple molecules or chemical systems that can undergo molecular...
- Keyword:
- self-assembly, host-guest chemistry, and homophilic recognition
- Subject:
- Chemistry
- Creator:
- gong, xirui
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14747 and etdadmin_upload_675818
-
- Description:
- The invention of GdIII-based magnetic resonance imaging (MRI) probes substantially expanded the capability of MRI in visualizing details in tissue. Building upon the achievement of GdIII-based complexes, more ideal probes should feature contrast that is responsive to biomarkers, such as redox status and ion concentrations. The abnormality of these biomarkers...
- Keyword:
- Responsive probes, PARACEST, Paramagnetic NMR, MRI contrast agents, Inorganic Chemistry, and Bioinorganic Chemistry
- Subject:
- Chemistry
- Creator:
- Du, Kang
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2018-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14394 and etdadmin_upload_615839
-
- Description:
- In the design of efficient adsorbents for the sequestration of toxic molecules and the separation of volatile organic compounds, two important criteria are: high porosity and high density of sorptive sites. The work in this thesis showcases how metal-organic frameworks (MOFs) can be used as porous adsorbent templates where many...
- Subject:
- Chemistry
- Creator:
- Audu, Cornelius Okatahi
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14503 and etdadmin_upload_636835
-
- Description:
- Proteins are a class of nanoscale building block with remarkable chemical complexity and sophistication: their diverse functions, shapes and symmetry, and atomically monodisperse structures far surpass the range of nanoparticles that can be accessed synthetically. The chemical topology of proteins that drive their assembly into higher order materials are central...
- Subject:
- Chemistry
- Creator:
- McMillan, Janet
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/12/2020
- Date Created:
- 2019-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:14624 and etdadmin_upload_662062