The utilization of hydrofluoric acid for the preparation of silver vanadium oxide fluorides has been advanced for the synthesis of Ag<sub>4</sub>V<sub>2</sub>O<sub>6</sub>F<sub>2</sub> and Ag<sub>3</sub>VO<sub>2</sub>F<sub>4</sub>. Silver-rich metal oxide fluorides are important battery cathode materials due to the high reduction potential of silver vs. Li, which is made even higher by the incorporation...
My research interests, which span organic, inorganic, physical and biochemistry, have focused broadly on photo-, magneto- and redox-active molecules, especially those with potential applications in organic photovoltaics, spintronics and electronics. My research under the joint supervision of Professor Wasielewski and Professor Fraser Stoddart has concentrated upon understanding electronic and magnetic...
Photovoltaic technology can help meet the exploding world energy demand in a sustainable and environmentally friendly way. Organic photovoltaics (OPVs) are especially attractive because they can be constructed with low-cost organic content and are amenable to high-throughput large-scale fabrication techniques. Synthetic modification of organic semiconductors has paved way for the...
Self-assembled monolayers as tunable chemical platforms broadly enable the study of the interaction between biological species and synthetic surfaces. Unlike small molecule chemistry where the freely diffusible product can interact with biological targets as an inhibitor or probe, interfacial chemistry allows for the controlled and multi-valent presentation of ligands to...
Small molecules such as indanes, chromanes, tetralins and their derivatives play a significant role in drug discovery due to their potent biological activity. This research herein presents a facile Brønsted acid-catalyzed allylsilane annulation methodology to generate fused ring systems such as indanes. The reaction goes through a homoallylic intermediate which...