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Filtering by: Creator Bryan D Stubbert Subject Chemistry

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Constrained Geometry Organoactinide Complexes: Scope and Mechanism of Intramolecular Hydroamination/Cyclization of Primary and Secondary Amines

Description:

In Chapter 1, a series of "constrained geometry" organoactinide complexes, (CGC)An(NMe)2 (CGC = Me2Si(h5-Me4C5)(tBuN); An = Th, 1; U, 2), prepared via efficient in situ, two-step protodeamination routes in good yields and high purity, is presented. Both 1 and 2 are quantitatively converted to the neutrally charged, solvent-free dihalides (1-Cl2,...

Keyword:

Chemistry and Inorganic (0488)

Subject:

Chemistry

Creator:

Bryan D Stubbert

Owner:

Scholarly Digital Publishing

Date Uploaded:

05/07/2018

Date Modified:

05/07/2018

Date Created:

2006-12-05

Resource Type:

Dissertation