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Filtering by: Creator John Andrew Stevens Roberts Keyword metallocene Resource type Dissertation

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Description:: Counteranion effects on the rate and stereochemistry of propylene polymerization mediated by ion-pair complexes derived from dimethylzirconocene precatalysts activated with strongly Lewis-acidic perfluoroarylmetalloid cocatalyst/activators are shown to arise from the strength of the cation-anion interaction. This is quantified using CS-symmetric Me2C(Cp)(Flu)ZrMe2 (Cp = C5H4, &#951;5 cyclopentadienyl; Flu = C13H8, &#951;5...
Keyword:: cocatalyst, polyolefin, microstructure, ion pair, metallocene, and polymerization
Subject:: Chemistry
Creator:: John Andrew Stevens Roberts
Owner:: Scholarly Digital Publishing
Date Uploaded:: 05/09/2018
Date Modified:: 05/09/2018
Date Created:: 2006-11-28
Resource Type:: Dissertation

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