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Filtering by: Creator Michael R Salata Resource type Dissertation

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Catalyst Nuclearity Effects in Olefin Polymerization

Description:

The new binuclear organo-zirconium and -titanium metal complexes {2,7-di-[(2,6diisopropylphenyl)imino]-1,8-naphthalenediolato group 4 metal complexes {1,8-(O)2C10H4-2,7[CH=N(2,6-iPr2C6H3)]2}Zr2Cl6(THF)2 (FI2-Zr2) and {1,8-(O)2C10H4-2,7-[CH=N(2,6- i 2 t Pr2C6H3)]2}Ti2Cl6(THF)2 (FI -Ti2) are compared to the mononuclear analogues {3- Bu-2(O)C6H3CH=N(2,6-iPr2C6H3)}ZrCl3(THF) (FI-Zr1) and {3-tBu-2-(O)C6H3CH=N(2,6- i Pr2C6H3)}TiCl3(THF) (FI-Ti1), respectively, in ethylene polymerization and ethylene + olefin copolymerization processes. The comonomers studied...

Keyword:

methylenecycloalkane, phenoxyiminato, olefin, bimetallic, and polymerization

Subject:

Chemistry

Creator:

Michael R Salata

Owner:

Scholarly Digital Publishing

Date Uploaded:

09/19/2018

Date Modified:

09/19/2018

Date Created:

2008-06-12

Resource Type:

Dissertation