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Filtering by: Creator Robert B. Lettan ii Resource type Dissertation Subject Chemistry

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I. Lewis Base-Promoted Additions of Trialkoxysilylalkynes II. Multi-component Homoenolate Reactions Using Acylsilanes

Description:

Two new methods have been developed employing silicon-containing molecules in novel organic transformations. The first strategy utilizes Lewis base-activation of triethoxysilylalkynes to deliver mild acetylide nucleophile equivalents. The second approach involves the use of enolate additions to acylsilanes to generate β-silyloxy homoenolate intermediates. Lewis base-catalyzed activation of triethoxysilylalkynes promotes the...

Keyword:

Organic Chemistry

Subject:

Chemistry

Creator:

Robert B. Lettan ii

Owner:

Scholarly Digital Publishing

Date Uploaded:

08/27/2018

Date Modified:

08/27/2018

Date Created:

2007-07-17

Resource Type:

Dissertation