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Metal Semiquinoid Magnets: From Molecules to Materials

Description:

In this dissertation, efforts are detailed to utilize semiquinoid bridging ligands to impart strong magnetic coupling between metal centers. Chapter 1 introduces the synthetic challenge of realizing molecule-based magnets with high operating temperatures due to weak magnetic coupling between spin centers through large, diamagnetic ligands. An alternative strategy is described...

Keyword:

Inorganic chemistry

Subject:

Chemistry

Creator:

Jordan DeGayner

Owner:

Scholarly Digital Publishing

Date Uploaded:

10/14/2019

Date Modified:

10/14/2019

Date Created:

2018-01-01

Resource Type:

Dissertation
Non-equilibrium processing leads to record high thermoelectric figure of merit in PbTe–SrTe

Description:

The broad-based implementation of thermoelectric materials in converting heat to electricity hinges on the achievement of high conversion efficiency. Here we demonstrate a thermoelectric figure of merit ZT of 2.5 at 923 K by the cumulative integration of several performance-enhancing concepts in a single material system. Using non-equilibrium processing we show...

Keyword:

Inorganic chemistry, Thermoelectrics, and Electronic properties and materials

Creator:

Gangjian Tan, Hang Chi, Chris Wolverton, Li-Dong Zhao, Ctirad Uher, Fengyuan Shi, Shiqiang Hao, Xiaomi Zhang, Mercouri G. Kanatzidis, and Vinayak P. Dravid

Owner:

Chris Diaz

Publisher:

Springer Nature

Date Uploaded:

05/08/2017

Date Modified:

05/08/2017

Date Created:

2016-07-07

Resource Type:

Article

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Metal Semiquinoid Magnets: From Molecules to Materials

Non-equilibrium processing leads to record high thermoelectric figure of merit in PbTe–SrTe

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