Organic photovoltaics (OPVs) are an attractive solar energy technology for low-current applications. Herein is described the supramolecular design and methodology to manipulate intermolecular interactions in order to create an active layer in OPVs devices composed of crystalline and amorphous donor-acceptor domains, which has been proposed as the ideal morphology for...
Amyotrophic lateral sclerosis (ALS) is characterized by progressive motoneuron loss. Autopsy from thoracic spinal tissues of sALS patients revealed a significant loss of large motoneurons while medium and small motoneurons were relatively unaffected. Using two-photon microscopy, we observed a soma hypertrophy of neonatal motoneurons in mice overexpressing mutant human G93A-superoxide...
This dissertation explores the extent to which Portuguese theologian, papal penitentiary, bishop, and abbot Andreas de Escobar, O.S.B. (1348-1448) benefited from contemporary trends in manuscript culture and thereby functioned as a late-medieval public intellectual. Recent research suggests that early-fifteenth-century university-trained theology masters used their expertise and authority to intervene into...
In yeast, inducible genes such as INO1, PRM1 and HIS4 reposition from the nucleoplasm to nuclear periphery upon activation. This leads to a physical interaction with nuclear pore complex (NPC), interchromosomal clustering, and stronger transcription. Repositioning to the nuclear periphery is controlled by cis-acting transcription factor (TF) binding sites located...
In this thesis I present the theoretical work on Fermionic surface states, and bulk Bosonic collective excitations in topological superfluids and superconductors. Broken symmetries in topological condensed matter systems have implications for the spectrum of Fermionic excitations confined on surfaces or topological defects.
For the B-phase of superfluid 3He, which...
This dissertation aims to address a gap in the literature regarding the effect of the achievement-focused student identity on prosocial values and behaviors, specifically among students who predominantly value prosociality. Largely, research on identity and motivation addresses academic outcomes and psychological well-being outcomes (Settles, Sellers, & Damas, 2002; Jaret &...
This thesis discusses the application of advanced digital signal and image processing techniques, particularly the technique known as super-resolution (SR), to enhance the imagery produced by cameras mounted on an airborne platform such as an unmanned aircraft system (UAS). SR is an image processing technology applicable to any digital, pixilated...
Raman spectroscopy is an established and versatile molecular sensing technique, but it is limited by its modest chemical sensitivity. Surface-enhanced Raman spectroscopy (SERS) can amplify otherwise weak normal Raman signals up to nine to ten orders of magnitude, giving rise to its application in many molecular sensing problems, including those...
This dissertations consists of three chapters. The first chapter is on the topic of environmental economics and studies the question of the effects of air pollution on students’ school absences, finding significant and positive effects for air pollution, and PM10 in particular, on school absences. The second chapter is on...
We introduce and advocate a new paradigm in simulation experiment design and analysis, called ``green simulation,'' for the setting in which experiments are performed repeatedly with the same simulation model but different input parameters. In this dissertation three classes of green simulation estimators are proposed: the likelihood-ratio-based estimators, the metamodeling-based...