Metal and bimetallic nanoparticles are of interest and are widely used in various applications because of their unique optical, electronic, and catalytic properties, which differ from those of their bulk counterparts. Better understanding of the thermodynamic and kinetic properties of nanoparticles and their underlying growth mechanisms can serve as a...
Both chapters of this dissertation relate to the aggregate value of corporations in an economy. In particular, they relate to the ratio of the aggregate total market value of corporations over the replacement cost of their recorded capital. The first chapter introduces a model that can explain why this ratio...
Mobile traffic is expected to grow tenfold by 2019, topping 24 exabytes of monthly traffic and accounting for nearly half of all Internet traffic. This growth is driven by the increasing number of smart phones and tablets, and the data demands of high bandwidth services enabled by next-generation cellular networks...
The concept of deportation has become increasingly important in recent years, as states more and more turn to removal as a technique of control over population and territory. But within the field of political theory the concept of deportation has not yet received the attention it deserves. This dissertation helps...
Achievement gaps between students from different SES and racial/ethnic backgrounds stubbornly persist despite decades of policy interventions. My dissertation focuses on several unexpected sources of stress and disruption that may be related to the achievement gap: sunlight exposure, a sister’s teen childbearing, and nearby violent crime. I demonstrate that these...
Changing economic activities bring significant cultural, epidemiological, and nutritional transitions. These transitions have important and lifelong effects on the health of populations experiencing them. Infancy represents a critical period when rapid growth and metabolic programming occur, making infants particularly vulnerable to long-lasting biological changes due to such transitions. The objective...
This dissertation contains two studies. In Chapter 1, I implement a randomized intervention to measure the effect of reminders for timely payment of credit cards. While I find an 13% reduction in the cost of late payment fees paid, 31% of the users that avoid credit card late payments, incur...
Freeze casting is a technique for processing porous materials that has drawn significant attention for its effectiveness in producing a variety of tailorable pore structures for ceramics, metals, and polymers. With freeze casting, pores are generated based on a solidification process where ice crystals act as a sacrificial template which...
This work is concerned with the Laudau-Ginzburg $A$-model, or the Fukaya-Seidel category, associated with a Laurent polynomial $f: (\C^*)^n \ o \C$. We use constructible sheaves on a real $n$-dimensional torus to describe the Lagrangian thimbles associated to $f$. Then we discuss the application to Homological Mirror Symmetry for smooth...
We often criticize others for beliefs that are dogmatic, biased, or wishful. What, exactly, are we criticizing? Many epistemologists accept that such believing is problematic because it is not appropriately responsive to epistemic reasons. But why care about that? Or, to put it another way, why are epistemic norms authoritative...
This dissertation explores the relationship between institutions of political participation and environmental protection. What is the relationship and how is it constituted? How are participatory institutions put into motion, and how do they operate? What are the effects of these institutions? Are participatory institutions desirable from an environmental perspective and...
The scope of this thesis extends to the study of surface structures and electronic properties in a number of complex oxides. The c(6x2) surface reconstruction on SrTiO3 (001) was solved using a combination of plan view transmission electron microscopy imaging, atomic resolution secondary electron imaging, and density functional theory calculations....
We define multi-indexed Deligne extensions and multi-indexed log-variations of Hodge structures in the category of (filtered) logarithmic D-modules, via the idea of Bernstein– Sato polynomials and Kashiwara–Malgrange filtrations, generalizing the Deligne canonical extensions of flat vector bundles. We also obtain many comparison results with perverse sheaves via the logarithmic de...
This dissertation explores the renewed historical significance of the (geo)political demand to redraft national constitutions in the Americas. Building on previous work, my dissertation constructs a transnational lens to underline the intersectionality of the social struggles that catalyzed the Venezuelan Constituent Assembly process begun in 1999 and the Ecuadorian experience...
How can gatekeeping theory in the circulation of cultural objects, including knowledge production, inform the way cultural sociology investigates the role of the producer and the cultural object as “gated” entities? Using the case of producers working under the rubric of “Contemporary African art” to investigate opportunities and restrictions to...
Dopaminergic neurons in the substantia nigra pars compacta are richly innervated by GABAergic neurons. The postsynaptic effects of GABA on SNc DA neurons are mediated by a mixture of GABAA and GABAB receptors. Although activation of GABAA receptors inhibits spike generation, the consequences of GABAB receptor activation are less well...
This dissertation presents a Nuclear Magnetic Resonance (NMR) study of a novel anisotropic superconductor, HgBa$_{2}$CuO$_{4+\delta}$ (Hg1201) and unconventional strain dependence of the mean free path of silica aerogel. Hg1201 is one of the most structurally simple cuprates known. Therefore, it is an ideal compound in investigation of various phases in...
Age-related cognitive deficits are observed in both humans and animals. Yet, the molecular mechanisms underlying these deficits are not yet fully elucidated. In aged animals, a decrease in intrinsic excitability of pyramidal neurons from the CA1 sub-region of hippocampus is believed to contribute to age-related cognitive impairments, but the molecular...
The impacts of many important technologies are limited by the availability of better-performing materials. One factor limiting the ability of engineers to develop better materials is the speed at which they can search through possible formulations and processing schemes. Recently, machine learning algorithms have emerged as a possible route to...
Loss of inhibitory control from descending serotonergic (5-HT) fibers deregulates the excitability of spinal motoneurons and interneurons following spinal cord injury (SCI). Exaggerated synaptic activity triggers long-lasting excitatory postsynaptic potentials (long EPSPs) in hyperexcitable motoneurons to ultimately drive muscle spasms at the chronic stage of SCI. Deep dorsal horn (DDH)...