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Filtering by: Keyword N-Heterocyclic carbene Keyword Thiazolium

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New Thiazolium-Based Strategies for Acyl Anion Addition Reactions

Description:

Two new strategies have been developed to accomplish direct nucleophilic acylation reactions. In the first approach, acylsilanes are added to various electrophiles using N-heterocyclic carbenes as catalysts. The second method utilizes O-silyl thiazolium carbinols as stoichiometric acyl anion precursors to afford acylated products under mild reaction conditions. N-heterocyclic carbenes generated...

Keyword:

Nucleophilic Acylation, Acyl anion, N-Heterocyclic carbene, and Thiazolium

Subject:

Chemistry

Creator:

Anita Mattson

Owner:

Scholarly Digital Publishing

Date Uploaded:

05/14/2018

Date Modified:

05/14/2018

Date Created:

2007-04-05

Resource Type:

Dissertation