Recent advances in high-performance computing have resulted in massive databases of materials properties calculated with techniques such as ab initio density functional theory. In fact, some of the largest of such databases have calculations of nearly all distinct, ordered, experimentally-reported compounds. This thesis discusses the application of data in one...
Central nervous system (CNS) regeneration is one of the most challenging regenerative medicine targets in mammals due to the natural inhibitory mechanisms that occur in response to injury. In the case of spinal cord injury (SCI), the initial inflammatory response protects damaged tissue, but over time creates a hostile microenvironment...
Transition Metal Dichalcogenides (TDMCs) are one of many families of two-dimensional (2D) beyond graphene, that started to gain more attention due to the need for miniaturization and their unique electrical, mechanical, and optical properties. Some members of TMDCs, such as MoS2, has direct band gap in its monolayer form, making...
Living organisms undergo morphogenesis as they develop and change shape to fit their evolved niche in natural ecosystems. The biological processes underlying morphogenesis involve sophisticated feedback loops between spatiotemporal release of morphogenic molecules that diffuse and signal cell differentiation, as well as contextual interaction with the physical surroundings of the...
Natural gas is likely to become one of the main sources of carbon-based chemicals in the next century due to rapidly increasing natural gas production levels. This has created new incentives to find materials that are active and selective towards alkane partial oxidation reactions that are relevant for natural gas...
The unique ability of plasmonic nanoparticles to localize and enhance resonant electromagnetic fields has enabled a wealth of discoveries from enhanced spectroscopies to driving chemical reactions on the nanoscale. In this thesis, we strive to both drive and observe chemistry on plasmonic surfaces. First, we examine the possibility of driving...
Subchalcogenides are rare compounds that have both metal-metal and metal-chalcogenide (sulfur, selenium, tellurium) interactions. Unlike conventional semiconductors, the metals do not obey the so-called 8-N octet rule for oxidation states, often resulting in low or zero valent metal atoms. The presence of both metal-metal and metal-chalcogenide bonding can also lead...
Super-resolution (SR) has become one of the most critical problems in image and video processing. In Chapter 2 of this thesis, a detailed review of existing Deep Learning (DL) techniques for addressing the SR task, with an emphasis on how DL and analytical techniques can be combined, is provided. Chapter...
Conventional cross-linked polymers are widely used owing to their outstanding stability and performance. However, permanent cross-links in these polymer networks prevent them from being recycled or reprocessed at the end of life, leading to major sustainability and economic losses. The recycling issue associated with polyurethane (PU) thermoset wastes exemplifies such...
This dissertation examines three empirical questions related to human capital in developing countries. Chapter 1 studies the educational and labor market impacts of the telesecundarias, Mexican secondary schools that use televisions to deliver instruction. In areas where there is an insufficient supply of qualified teachers, delivering instruction through technology may...
This dissertation offers a novel interpretation of Aristotle’s notion of teaching (didaskalia). In Part I, I defend my claim that we can find in Aristotle’s works a conception of teaching, which is a crucial yet under-explored part of his theory of education. In Part II, I use this interpretation to...
Light trapping with standing waves has been achieved using photonic bandgap crystals, metal-dielectric waveguides and periodic metal nanocavity arrays. Compared with photonic materials, plasmonic metal nanocavities can provide light confinement at the sub-wavelength scale with strong near-field electric enhancement. The localized surface plasmons of individual metal nanoparticles can collectively couple...
The social groups to which individuals belong, as well as the identities that result from these group memberships, exert powerful influences on their political attitudes. Additionally, political elites offer cues that shape these same preferences—often by targeting and interacting with identities. However, there remain underexplored pathways by which elites can...
Dynamic decision-making is a complex process that relies on our ability to generate, evaluate and implement a variety of strategies. Understanding how people navigate this process is a difficult problem that requires a wide range of methodologies. This study details a combination of behavioral experiments, computational modeling, and neuroimaging that...
The term compaction band identifies a rich variety of structural features of the Earth's crust that affect formations of sedimentary rocks. The most common definition for compaction band often found in the literature describes them as narrow planar zones of concentrated porosity reduction, which may involve limited to none shear...
As technology scales down, challenges in fabrication, thermal stress, and in-field degradation have put the reliability of processors at risk. Among different fault types, transient faults manifest themselves frequently due to high chip density, aggressive voltage scaling, and high clock frequency. Some dependable processor architectures have been proposed to counter...
This thesis investigates various aspects of productivity. In the first chapter I investigate the role of consumer demand in generating productivity dispersion. In particular, I study how differences in consumer preferences across the household income distribution generate dispersion in markups across the Indian manufacturing sector. I find that this consumer...
The high-temperature oxidation/reduction behaviors of iron and its oxides are important to a variety of energy conversion and storage technologies, such as the solid-oxide iron-air battery and chemical looping combustion. The useful lifetime of iron redox materials is limited, however, by structural degradation arising from (i) sintering, accelerated by phase...
Abstract Kaposi sarcoma (KS) is the most common cancer associated with human immunodeficiency virus/ Acquired Immunodeficiency Syndrome (HIV/AIDS) infection worldwide and it is the most prevalent cancer in some countries in sub-Saharan Africa (SSA). The introduction of combination antiretroviral therapy (ART), led to dramatic declines in KS morbidity and mortality,...
The effect of Alkali-Silica Reaction (ASR) on concrete mechanical behavior and the multi-physics considerations that come along are highly complex. Hydration and other chemical reactions occur at the micrometer scale. Hygro-thermal phenomena and concrete cracks due to ASR are typically studied at the meso-scale, i.e. at the aggregate level. At...