Organic chromophores show great promise for energy and optoelectronic devices, due to their synthetic tunability and low production costs. In order to achieve this potential, their fundamental photophysical processes must be better understood. It has long been documented that chromophore packing at the molecular level has dramatic effect on electronic...
The philosophical literature on modals is dominated by the following paradigm: modals are modeled as quantifiers over sets of possible worlds. The diversity of modal “fla- vors” (e.g., epistemic, deontic, teleological interpretations of modals) is accommodated within the paradigm by logical mechanisms that allow extralinguistic factors to restrict the quantificational...
There is a paradox at the center of twenty-first century American poverty. On the one hand, American poverty seems to have become an object of significant interest (at least to scholars and to the reading public)—as evidenced through the surge of wildly successful non-fiction books about poverty. On the other...
I analyze a new mechanism through which changes in aggregate income can result in changes in the labor income distribution. This mechanism arises from heterogeneity in the expenditure elasticity of different sectors and in their employment composition. Once total income increases the mechanism suggests that consumption will be re-allocated towards...
Computational imaging (CI) is a class of imaging systems that optimize both the opto-electronic hardware and computing software to achieve task-specific improvements. Machine/deep learning models have proven effective in drawing statistical priors from adequate datasets. Yet when designing computational models for CI problems, physics-based models derived from the image formation...
An extensive set of functional electronic properties depends on the electronic structure. These properties are directly connected to the reciprocal-space representation of electronic structure. However, there is a complementary, real-space perspective that is described by combinations of atomic orbitals. Atomic orbitals are the components of electronic structures, analogous to how...
Cyclodextrin-based polymers (CDPs) are adsorbents based on supramolecular receptor chemistry and have emerged as a promising technology for organic micropollutant remediation. Micropollutants are small organic molecules which contaminate water systems from human related activities. The occurrence of micropollutants in water sources is associated with many negative health, economic, and ecological...
This dissertation describes the study of photoinduced charge transfer between QDs and molecular acceptors as a probe of the defects within ligand shells of QDs and as means to photocatalyze redox reactions. For charge transfer reactions to occur between QDs and molecules in bulk solution, the molecules must interact with...
This dissertation explores mid-twentieth century US stand-up comedy recordings and how they elaborate upon definitions of the avant-garde in theatre and performance studies. Weaving theories of comedy, aesthetics, radical performance, and sound studies, I argue for the reconceptualization of the avant-garde as an intellectual impulse outside of the parameters of...
Difficulties in prosody (e.g., intonation, volume, rate), turn-taking, and overly formal speech constitute common social communication deficits in autism spectrum disorder (ASD), which can significantly hinder social interactions (Paul et al., 2009). Subtle parallel differences in social communication have also been noted in parents of individuals with ASD, suggesting that...