Renewable energy technology, more so than ever before, is critical to the survival of humanity. For decades, concentrated efforts into designing and developing such novel devices resulted in the innovation of solar-driven photovoltaics that were competitive with nonrenewable alternatives. This thesis explores the dynamic behavior of alternative material candidates that...
Since its introduction as an artist’s pigment in the earth 20th century, titanium white has become one of the most common white pigments. The early formulations of titanium white contained anatase, which has been studied to facilitate degradation of oil paint under UV illumination. Around the 1940s production shifted to...
The Controlled, Site-Isolated Synthesis of Polyelemental Nanostructures in Polymer Nanoreactors Pengcheng Chen Polyelemental nanoparticles are an attractive class of materials due to their potential applications, which span the fields of catalysis, plasmonics, electronics, magnetics, targeted drug delivery, and bio-imaging. However, conventional synthetic methods for such structures are limited, especially when...
The development of functional materials with rationally designed hierarchical structure is an interdisciplinary challenge. Looking to nature for inspiration, we use small molecules that
engage in directed self-assembly through carefully tuned intermolecular interactions to construct
materials that have structure at multiple length scales. In this work, supramolecular structures
formed using...
NiTi shape memory alloy (SMA) has drawn a great deal of attention for its various applications in the medical field (orthodontics, cardiovascular stents technology, etc.) and in other engineering fields (aerospace, aircraft, automotive, etc.) as it shows shape memory effect, superelasticity and biocompatibility. The fatigue-related issues, however, are pronounced in...
Large scale adoption of sustainable technologies for energy productionand storage can be greatly facilitated by scientific advances impacting efficiency, cost and availability. The study of materials is instrumental in both upgrading the performance of existing technologies and enabling the development of new ones, and ab-initio methods and machine learning represent...
The high-temperature oxidation/reduction behaviors of iron and its oxides are important to a variety of energy conversion and storage technologies, such as the solid-oxide iron-air battery and chemical looping combustion. The useful lifetime of iron redox materials is limited, however, by structural degradation arising from (i) sintering, accelerated by phase...
High performance polymers and their composites have wide ranging application in advanced and emerging material systems. The macroscale performance of these advanced materials is often defined by interfaces that induce nanoscale changes in the microstructure or molecular conformations (termed the ‘interphase’) of the polymer. Atomic force microscopy (AFM) is an...
Engineering responses of soft materials at hierarchical time and length scales is of great interest to both fundamental science and technological applications. In recent years, the hybridization between emerging soft condense matters and conventional hard condense matters keeps enriching the materials library of humankind and opens another largely-uncharted venue for...
Localized corrosion involves the selective attack of a metal at a small, exposed site. This can be particularly devastating for load-bearing structures like bridges, which can fail catastrophically even with very little material loss. Unfortunately, such corrosion is very hard to prevent, predict, and detect. Corrosion can be prevented by...