Since its introduction as an artist’s pigment in the earth 20th century, titanium white has become one of the most common white pigments. The early formulations of titanium white contained anatase, which has been studied to facilitate degradation of oil paint under UV illumination. Around the 1940s production shifted to...
Wireless power strategies are critical to system level implementation of bio-integrated devices. To achieve mechanically robust, manufacturable systems, batteries are often integrated as an on-board power source to support sensing, wireless communication and signal conditioning. Unfortunately, most sources of battery power use hazardous and environmentally harmful materials, which frustrate incorporation...
Biomineralization relies on the regulation of localized environments to control how minerals are formed. Through the use of confinement and specific additives, the organism is able to change the energy landscape of nucleation and growth to build single crystals with unusual morphologies. In order to better understand the environments in...
Industrial processes heavily rely on catalysts to control product selectivity and lower energy barriers required for chemical transformations. Catalysts are most commonly solid heterogeneous catalysts that facilitate separations from reaction mixtures and enhance recyclability. Heterogeneous catalysts used in industrial processes exhibit efficacious results, but in certain instances drawing structure-function relationships...
Selecting the best material to deliver optimum performance in real-world applications is one of the most significant challenges in engineering. Hundreds of thousands of computationally-predicted, but experimentally unexplored materials exist today in the public inorganic material databases as candidates for consideration. This thesis discusses three projects in the domain of...
From the early usage of metallic thin films as mirrors tracing back to 2900 BC, to the modern thin film photonic circuits as a mature optical processing platform, and to the growing class of atomically-thin two-dimensional (2D) materials with diverse and tailorable properties, thin film materials have played an important...
In this dissertation, I summarize my findings of the dynamics of colloidal suspensions over a large range of volume fractions in two systems: drop impact and film rupture. The existence of a deformable surface in both these systems allows me to capture the consequences of non-Newtonian flow using high-speed imaging....
Elemental powder blends are an emerging alternative to prealloyed powders for high-throughput alloy design via additive manufacturing techniques due to their flexibility, low cost, and ease of customization. This dissertation investigates elemental alloying elements (Sc and Zr) which are high-melting and highly reactive, unlike previous work which focused on more...
The on-going demand for miniaturized optical and on-chip photonic systems of the future has led to a few potential solutions in the literature. Recent advances in van der Waals and 2-dimensional materials signal a bright future for the next generation, compact electronic and photonic devices. With reduced dimensionality and material...
Atomistic methods offer a powerful set of tools in the study of materials systems, as they allow materials scientists to ask questions with a high degree of specificity. They are well suited for studying and designing energy materials, critical due to the climate crisis, in part due to their ability...
The extracellular matrix (ECM) is a masterwork of biology, and its development was a key part of the transformation from monocellular to multicellular life. With an ECM, cells acquired the ability to cooperatively build a dynamic support network that facilitated their movement, specialization, and communication. This ECM is a hierarchical...
Solid acid fuel cells confer unique advantages over nearby technologies, such as polymer electrolyte membrane fuel cells (PEMFCs) or solid oxide fuel cells (SOFCs), due to the solid acid electrolyte – a solid-state, anhydrous, intermediate-temperature proton conductor.Despite these encouraging unique properties, solid acid fuel cells have performed unfavorably in comparison...
Conventionally cross-linked polymers, which comprise the vast majority of commercial thermosets, cannot be decross-linked after curing or flow upon heating. Therefore, they cannot be effectively recycled into high-value products at end-of-life. Their lack of recyclability is due to the permanent cross-links, which restrict the flow of the chains in the...
Recent developments have enabled L12-strengthened Co-based superalloys, which have thepotential to surpass Ni-based superalloys as the material of choice for the hottest sections of turbine
blades due to cobalt’s 40 ºC higher melting point. The most-studied branch of Co-based
superalloys are based on the L12 phase Co3(Al,W); however, there is...
Atomistic methods offer a powerful set of tools in the study of materials systems, as they allow materials scientists to ask questions with a high degree of specificity. They are well suited for studying and designing energy materials, critical due to the climate crisis, in part due to their ability...
Heteroanionic materials are a class of materials of interest for their unique and tunable electronic, ionic, thermal, and optical properties, which are distinct from their homoanionic counterparts due to their multi-anionic nature. Oxynitrides, a type of heteroanionic material, are useful catalysts due to the effect of mixing oxygen and nitrogen...
As more thermoelectric materials/devices make it into the market for various applications, severalaspects need to be explored and optimized, beyond simply targeting high conversion efficiency at
the material levels. One critical aspect is the guarantee of mechanical stability at both the material
and the device level, which demands deeper understanding...
The on-going demand for miniaturized optical and on-chip photonic systems of the future has led to a few potential solutions in the literature. Recent advances in van der Waals and 2-dimensional materials signal a bright future for the next generation, compact electronic and photonic devices. With reduced dimensionality and material...
Nanomaterials present an exciting landscape of innovation at length scales below 100 nm, wherein controllable synthesis and materials metrology have led to tunable structure-property relationships and next-generation products. The disruptive field of nanotechnology is poised to capitalize upon the exotic chemistry and physics of these nanomaterials to enable more efficient...
This thesis explores the potential of two-dimensional (2D) or van der Waals (vdW) materials for printed optoelectronic devices. The research focuses on the development of processing, imaging, and modeling of materials and thin-film devices to optimize performance and introduce novel properties. A gate-dependent resistor network model is presented that establishes...