Magnetic resonance imaging (MRI) is a technique widely used in both clinical and experimental settings to produce high-resolution images of opaque living organisms without utilizing ionizing radiation. Currently, MR imaging is augmented by contrast agents; however, these small molecule Gd(III) chelates are confined to extracellular and vascular regions of the...
N-Heterocyclic carbene catalysis has recently emerged as an important field in organic chemistry. Two new strategies have been developed to advance the use of N-heterocyclic carbenes (NHCs) as Lewis-base organic catalysts. The first approach utilizes NHCs to catalyze the generation of homoenolates and the conjugated Breslow intermediate is added to...
Chapter 1 describes the homopolymerization of styrene and the copolymerization of ethylene and styrenic comonomers mediated by the single-site bimetallic "constrained geometry catalysts" (CGCs), (µ-CH2CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](TiMe2)}2 [EBICGC(TiMe2)2; Ti2], (µ-CH2CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](ZrMe2)}2 [EBICGC(ZrMe2)2; Zr2], (µ-CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](TiMe2)}2 [MBICGC(TiMe2)2; C1-Ti2], and (µ-CH2-3,3'){(η5-indenyl)[1-Me2Si(tBuN)](ZrMe2)}2 [MBICGC(ZrMe2)2; C1-Zr2], in combination with the borate activator/cocatalyst Ph3C+B(C6F5)4- (B1). Under identical styrene homopolymerization conditions,...
Metal nanoprisms are a novel class of anisotropic nanomaterials with unique optical properties dependent on their size, shape, and composition. Silver nanoprisms are of particular interest because their surface plasmon resonance bands are readily tunable in the visible and near-IR region. The objectives of this thesis research focus on photochemical...
Conjugated organic molecules and polymers hold significant promise for use as active materials in electronic devices. Employing such "soft" materials can decrease cost of device fabrication, while enabling unique properties such as mechanical flexibility, large-area coverage, and highly tunable materials properties. A primary roadblock to the realization of this dream...
Chemical vapor deposition (CVD) is a well-developed technique for growing thin films of a wide variety of materials, which relies on the development of new and better performing metal-organic precursors. To this end, three studies have been conducted into the compatibility of sulfur and phosphine containing ligands with low- and...
This thesis summarizes our research efforts on the application of the nano-structured anodic aluminum oxide (AAO) membrane in heterogeneous catalysis. Procedures for growing the AAO membrane in the center of an aluminum disc have been developed by appropriately masking the disk's perimeter during the anodization and etching steps. The remaining...
Metallic nanostructures are able to confine and manipulate electromagnetic fields because light can couple to free electron oscillations called surface plasmons (SPs). These plasmons exist on metal surfaces as localized (short-range) or as propagating (long-range) modes depending upon the size and geometry of the nanostructure. This dichotomy is primarily an...
This thesis investigates singlet exciton fission, a physical process that converts one singlet exciton to a pair of triplet excitons. Singlet fission was discovered nearly forty years ago, but the mechanism for this process is still not well understood. Recent work has suggested that singlet fission may be capable of...
This thesis attempts a combined theoretical/experimental investigation of two fundamental scaling laws in charge transfer reactions: how the rate of those reactions varies as a function of distance between an electron donor and an electron acceptor and how the rate varies as a function of the number of distinct pathways...