Over the past fifty years, techniques for synthesizing and manipulating matter on the 1-100 nanometer scale have led to the development of nanoparticle-based approaches to both disease diagnosis and treatment. The modification of nanoparticles with biological macromolecules such as proteins and nucleic acids has led to the development of highly...
Multimetallic nanoparticles represent an important class of electrocatalysts which are critical for many energy and environmental applications including fuel cells, hydrogen production, and greenhouse gas elimination. The properties of these nanoparticles depend on their composition, size, shape, and structure. Therefore, developing new strategies which provide a high level of control...
As demonstrated by efforts in graphene commercialization, scalable synthesis and high-quality material availability are primary limiting factors for the realization of technologies based on two-dimensional (2D) materials. Thus, in considering the fate of emergent 2D materials such as the metal chalcogenides, the challenge of scalable synthesis is a highly relevant...
Colloidal crystals are promising candidates for nanophotonic applications due to their strong interactions with light and the capability to tailor such interactions through crystal design and engineering. DNA-programmable assembly, in particular, allows for precise structural control down to the sub-nanometer length scale. In this thesis, ways of designing, synthesizing, and...
Transition Metal Dichalcogenides (TDMCs) are one of many families of two-dimensional (2D) beyond graphene, that started to gain more attention due to the need for miniaturization and their unique electrical, mechanical, and optical properties. Some members of TMDCs, such as MoS2, has direct band gap in its monolayer form, making...
Light trapping with standing waves has been achieved using photonic bandgap crystals, metal-dielectric waveguides and periodic metal nanocavity arrays. Compared with photonic materials, plasmonic metal nanocavities can provide light confinement at the sub-wavelength scale with strong near-field electric enhancement. The localized surface plasmons of individual metal nanoparticles can collectively couple...
Nucleic acid drugs promise to revolutionize the development of therapeutics. They offer a platform for digital medicine, where systematic changes to the nucleic acid sequence can be utilized to target the entire human genome. However, nucleic acids suffer from a number of drawbacks, such as negligible cellular uptake and rapid...
Two-dimensional (2D) materials and heterostructures have attracted significant attention for a variety of nanoelectronic and optoelectronic applications. At the atomically thin limit, the material characteristics and functionalities are dominated by surface chemistry and interface coupling. Therefore, methods for comprehensively characterizing and precisely controlling surfaces and interfaces are required to realize...
This dissertation presents a comprehensive study of thin-film LiMn2O4 (LMO) cathodes applied in lithium ion batteries (LIBs). The primary aim was to establish fundamental understanding of the relationship between interfacial LMO chemistry/electrochemistry and its detrimental drawback, i.e. fast capacity fade over long term cycling, and then develop effective mitigation methods....
Semiconductor nanowires, such as group IV and III-V nanowires, shows distinct electrical, optical and mechanical properties from their bulk counterparts due to their nanoscale size and 1-D morphology. For example, the quantum confinement effect modulates the band gap of a semiconductor nanowire when its diameter approaches or below the exciton...