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-
- Description:
- Metal–Organic Frameworks (MOFs) is a class of material comprising organic linkers and inorganic, metal-ion-containing nodes, with diverse functionalities and wide-range of applications. Because of their porous nature and functional nodes and linkers, they are competent candidates for gas storage, separation, catalysis, and so on. Most MOFs, however, are intrinsically insulating,...
- Keyword:
- Metal–Organic Frameworks, Electrochemistry, and Electrocatalysis
- Subject:
- Analytical chemistry, Chemistry, and Materials Science
- Creator:
- Duan, Jiaxin
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16539 and etdadmin_upload_984686
-
- Description:
- Renewable energy technology, more so than ever before, is critical to the survival of humanity. For decades, concentrated efforts into designing and developing such novel devices resulted in the innovation of solar-driven photovoltaics that were competitive with nonrenewable alternatives. This thesis explores the dynamic behavior of alternative material candidates that...
- Keyword:
- electronic, structural, perovskite, spectroscopy, two-dimensional, and nanomaterials
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Panuganti, Shobhana
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_1010644 and http://dissertations.umi.com/northwestern:16703
-
- Description:
- Large scale adoption of sustainable technologies for energy productionand storage can be greatly facilitated by scientific advances impacting efficiency, cost and availability. The study of materials is instrumental in both upgrading the performance of existing technologies and enabling the development of new ones, and ab-initio methods and machine learning represent...
- Subject:
- Materials Science and Energy
- Creator:
- Baldassarri, Bianca
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16729 and etdadmin_upload_1012768
-
- Description:
- The relationship between the structure and function of proteins is a fundamental problem in biology with implications for the future of biotechnology and global health. For example, changes to the structure of a coronavirus spike protein led to a global pandemic where our best defenses were vaccines that could only...
- Subject:
- Materials Science
- Creator:
- Waltmann, Curt
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16624 and etdadmin_upload_991536
-
- Description:
- Dental enamel is a complex bio-composite with compositional and structural features across a wide range of length scales. Defects in these features can compromise enamel’s ability to protect the tooth, resulting in adverse health outcomes. Acquired defects like tooth decay are familiar to most people and are the subject of...
- Keyword:
- Amelogenesis, Enamel, Neural networks, X-ray diffraction, Microcomputed tomography, and Mouse models
- Subject:
- Materials Science
- Creator:
- Cooley, Victoria Mae
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16769 and etdadmin_upload_1013954
-
- Description:
- The continuing increase in atmospheric CO2 to concentrations exceeding 400 ppm has attracted considerable attention from both scientists and policymakers. Industrial fossil fuel consumption generates a significant amount of CO2 emissions, and in particular, energy-intensive molecular separations that require thermal processes, such as distillation, drying, or evaporation, are responsible for...
- Keyword:
- Dimensionality, Noble Gases, Hexane, Xylene, Metal-Organic frameworks, and MOFs
- Subject:
- Inorganic chemistry, Chemistry, and Materials Science
- Creator:
- Idrees, Karam
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_991974 and http://dissertations.umi.com/northwestern:16625
-
- Description:
- Directional freeze-casting is a porous materials fabrication technique that is used to create materials with complex, three-dimensional pore structures. Particle suspensions are solidified under a thermal gradient, promoting anisotropic growth of dendrites and incorporation of particles within interdendritic space. A fully-solidified directional freeze-cast structure is composed of dendrites that are...
- Keyword:
- convection, microstructure, metals, porous, solidification, and freeze-casting
- Subject:
- Materials Science
- Creator:
- Scotti, Kristen
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16652 and etdadmin_upload_1000506
-
- Description:
- Herein, we present an overview of our studies of the morphology, dynamics, and formation of heterogeneous soft matter systems via the emerging technique of liquid phase transmission electron microscopy (LPTEM). This particular subset of materials, more commonly referred to as emulsions, is tremendously commercially and biologically relevant, encompassing applications in...
- Keyword:
- liquid phase transmission electron microscopy, soft matter, emulsions, surfactants, and polymers
- Subject:
- Polymer chemistry and Materials Science
- Creator:
- Vratsanos, Maria A.
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_1009969 and http://dissertations.umi.com/northwestern:16698
-
- Description:
- Drying oils have been used as a binding medium for oil paints since the 15th century. These oil paints transition from a liquid-like paste to a solid-like film as a result of crosslinks forming between the oil molecules. These reactions have been extensively studied chemically, but other material properties are...
- Keyword:
- ATR-FTIR, Linseed oil, Drying oils, and Mechanical Properties
- Subject:
- Polymer chemistry and Materials Science
- Creator:
- dePolo, Gwen Ellen
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16730 and etdadmin_upload_1012786
-
- Description:
- Recent progress in semiconductor synthesis and photophysics has revealed a host of new materials with exciting properties for applications in optoelectronic devices such as sensors, photovoltaics, solid state lighting, and more. One of the most significant recent additions to the field is the class of hybrid and inorganic materials that...
- Subject:
- Physical chemistry, Chemistry, and Materials Science
- Creator:
- Cuthriell, Shelby A
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16650 and etdadmin_upload_1000360
-
- Description:
- Herein, we present an overview of our studies of the morphology, dynamics, and formation of heterogeneous soft matter systems via the emerging technique of liquid phase transmission electron microscopy (LPTEM). This particular subset of materials, more commonly referred to as emulsions, is tremendously commercially and biologically relevant, encompassing applications in...
- Keyword:
- liquid phase transmission electron microscopy, soft matter, emulsions, polymers, and surfactants
- Subject:
- Polymer chemistry and Materials Science
- Creator:
- Vratsanos, Maria A.
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_1009969 and http://dissertations.umi.com/northwestern:16698
-
- Description:
- How molecular chirality manifests at the nano- to macroscale has been a scientific puzzle since Louis Pasteur discovered biochirality. In general, amphiphilic molecules can organize into a variety of assembly shapes including micelles, spherical vesicles, cylindrical micelles, and planar bilayers. However, when such amphiphilic molecules are chiral, helical ribbons, helicoidal...
- Keyword:
- self-assembly, soft mattter, electrostatics, membranes, chiral, and charge
- Subject:
- Physical chemistry, Physics, and Materials Science
- Creator:
- McCourt, Joseph
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16654 and etdadmin_upload_1000771
-
- Description:
- In the late 2000’s, scientific studies in cultural heritage saw a great advancement in macro X-ray fluorescence (XRF) imaging of paintings. These images are used to generate elemental distribution maps, which aid in identifying chemical elements and paint pig- ments as well as their locations throughout the layers of the...
- Keyword:
- machine learning, x-ray fluorescence, and image processing
- Subject:
- Artificial intelligence, Materials Science, and Computer science
- Creator:
- Chopp, Henry Hayashi
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_998414 and http://dissertations.umi.com/northwestern:16642
-
- Description:
- Polymers occupied nearly every facet of our daily lives, and enhancing their mechanical and fracture properties has long been an important topic in the field of polymer science. Based on the various need in applications, polymers are designed to have a range of characteristics such as tackiness, optical properties, mechanical...
- Keyword:
- Adhesive, Fatigue, Elastomer, Fracture, Composite, and Mechanical Properties
- Subject:
- Materials Science
- Creator:
- Chen, Qihua
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 08/23/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_1004779 and http://dissertations.umi.com/northwestern:16673
-
- Description:
- The extracellular matrix (ECM) is a masterwork of biology, and its development was a key part of the transformation from monocellular to multicellular life. With an ECM, cells acquired the ability to cooperatively build a dynamic support network that facilitated their movement, specialization, and communication. This ECM is a hierarchical...
- Keyword:
- microfluidic, biomaterial, and supramolecular
- Subject:
- Bioengineering and Materials Science
- Creator:
- Kolberg-Edelbrock, Jack
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16480 and etdadmin_upload_979260
-
- Description:
- Solid acid fuel cells confer unique advantages over nearby technologies, such as polymer electrolyte membrane fuel cells (PEMFCs) or solid oxide fuel cells (SOFCs), due to the solid acid electrolyte – a solid-state, anhydrous, intermediate-temperature proton conductor.Despite these encouraging unique properties, solid acid fuel cells have performed unfavorably in comparison...
- Keyword:
- Solid Acid Fuel Cells, proton conductor, CsH2PO4, Superprotonic, Solid Acid Electrolytes, and CDP
- Subject:
- Materials Science and Energy
- Creator:
- Wang, Louis Shen
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_971560 and http://dissertations.umi.com/northwestern:16452
-
- Description:
- Conventionally cross-linked polymers, which comprise the vast majority of commercial thermosets, cannot be decross-linked after curing or flow upon heating. Therefore, they cannot be effectively recycled into high-value products at end-of-life. Their lack of recyclability is due to the permanent cross-links, which restrict the flow of the chains in the...
- Keyword:
- Dynamic, Polymers, Sustainability, Plastics, Recycling, and Crosslinking
- Subject:
- Materials Science, Sustainability, and Chemical engineering
- Creator:
- Bin Rusayyis, Mohammed Abdulaziz
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_986182 and http://dissertations.umi.com/northwestern:16581
-
- Description:
- Recent developments have enabled L12-strengthened Co-based superalloys, which have thepotential to surpass Ni-based superalloys as the material of choice for the hottest sections of turbine blades due to cobalt’s 40 ºC higher melting point. The most-studied branch of Co-based superalloys are based on the L12 phase Co3(Al,W); however, there is...
- Keyword:
- Superalloys, Cobalt, Microstructure, Machine Learning, Creep, and High Entropy Alloys
- Subject:
- Materials Science
- Creator:
- Ohl, Brandon
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_971014 and http://dissertations.umi.com/northwestern:16450
-
- Description:
- Atomistic methods offer a powerful set of tools in the study of materials systems, as they allow materials scientists to ask questions with a high degree of specificity. They are well suited for studying and designing energy materials, critical due to the climate crisis, in part due to their ability...
- Subject:
- Materials Science
- Creator:
- Patel, Shane
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16415 and etdadmin_upload_962311
-
- Description:
- Heteroanionic materials are a class of materials of interest for their unique and tunable electronic, ionic, thermal, and optical properties, which are distinct from their homoanionic counterparts due to their multi-anionic nature. Oxynitrides, a type of heteroanionic material, are useful catalysts due to the effect of mixing oxygen and nitrogen...
- Keyword:
- Oxynitrides, In situ synthesis, Tantalum oxynitride, Molybdenum oxynitride, and X-ray diffraction
- Subject:
- Materials Science
- Creator:
- Goldfine, Elise Ann
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16477 and etdadmin_upload_978839
-
- Description:
- As more thermoelectric materials/devices make it into the market for various applications, severalaspects need to be explored and optimized, beyond simply targeting high conversion efficiency at the material levels. One critical aspect is the guarantee of mechanical stability at both the material and the device level, which demands deeper understanding...
- Subject:
- Materials Science
- Creator:
- Al Malki, Muath Mohammed
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_988614 and http://dissertations.umi.com/northwestern:16622
-
- Description:
- The on-going demand for miniaturized optical and on-chip photonic systems of the future has led to a few potential solutions in the literature. Recent advances in van der Waals and 2-dimensional materials signal a bright future for the next generation, compact electronic and photonic devices. With reduced dimensionality and material...
- Keyword:
- Polarization, Phonons, van der Waals, Plasmons, Wave plate, and 2D materials
- Subject:
- Optics, Materials Science, and Electromagnetics
- Creator:
- Abedini Dereshgi, Sina
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16396 and etdadmin_upload_958293
-
- Description:
- Nanomaterials present an exciting landscape of innovation at length scales below 100 nm, wherein controllable synthesis and materials metrology have led to tunable structure-property relationships and next-generation products. The disruptive field of nanotechnology is poised to capitalize upon the exotic chemistry and physics of these nanomaterials to enable more efficient...
- Keyword:
- graphene, scalable manufacturing, nanomaterials, nanomanufacturing, 2D materials, and electronic materials
- Subject:
- Nanotechnology, Materials Science, and Engineering
- Creator:
- Downing, Julia Rocio
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16548 and etdadmin_upload_985168
-
- Description:
- This thesis explores the potential of two-dimensional (2D) or van der Waals (vdW) materials for printed optoelectronic devices. The research focuses on the development of processing, imaging, and modeling of materials and thin-film devices to optimize performance and introduce novel properties. A gate-dependent resistor network model is presented that establishes...
- Keyword:
- scanning probe microscopy, transition metal dichalcogenides, thin-film transistors, finite element simulation, printed electronics, and 2D materials
- Subject:
- Materials Science
- Creator:
- Zhu, Zhehao
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16504 and etdadmin_upload_982806
-
- Description:
- Single-use plastic waste pollution will cause significant harm to the environment if left unaddressed. One possible mitigation strategy is to develop processes, e.g. catalytic hydrogenolysis, that can convert (i.e. upcycle) waste plastics into value-added products capable of participating in a circular economy. Platinum (Pt) catalysts on strontium titanate nanocuboid supports...
- Subject:
- Chemistry and Materials Science
- Creator:
- Peczak, Ian Lukasz
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16513 and etdadmin_upload_983506
-
- Description:
- Thermoelectric devices convert between temperature gradients and electricity, implying numerous applications, such as powering exploratory space vehicles, industrial waste-heat recovery, and solid- state refrigeration. Thermoelectric devices consist of doped p-type and n-type semiconductor legs, and the overall device efficiency depends on the transport properties of these semiconductor materials. High-performing thermoelectric...
- Keyword:
- band engineering, electronic structure, density functional theory, thermoelectrics, group theory, and tight-binding
- Subject:
- Materials Science
- Creator:
- Brod, Madison K
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16437 and etdadmin_upload_967109
-
- Description:
- The field of materials discovery is undergoing an unprecedented transition from laboratory tocomputer. Behind this transition is the new ability to accurately compute material properties, especially energetic stability, from first principles with density functional theory (DFT). However, DFT remains computationally expensive, and DFT-based materials discovery is intractable, especially in high...
- Keyword:
- High throughput, Inorganic compounds, Big data, Density functional theory, Materials discovery, and Machine learning
- Subject:
- Materials Science, Condensed matter physics, and Computational chemistry
- Creator:
- Griesemer, Sean Darius
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 05/31/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16606 and etdadmin_upload_986816
-
- Description:
- The on-going demand for miniaturized optical and on-chip photonic systems of the future has led to a few potential solutions in the literature. Recent advances in van der Waals and 2-dimensional materials signal a bright future for the next generation, compact electronic and photonic devices. With reduced dimensionality and material...
- Keyword:
- Polarization, Phonons, van der Waals, Plasmons, Wave plate, and 2D materials
- Subject:
- Optics, Materials Science, and Electromagnetics
- Creator:
- Abedini Dereshgi, Sina
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 03/24/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16396 and etdadmin_upload_958293
-
- Description:
- Atomistic methods offer a powerful set of tools in the study of materials systems, as they allow materials scientists to ask questions with a high degree of specificity. They are well suited for studying and designing energy materials, critical due to the climate crisis, in part due to their ability...
- Subject:
- Materials Science
- Creator:
- Patel, Shane
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 03/24/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16415 and etdadmin_upload_962311
-
- Description:
- A fundamental materials science question is “why and how will this material form?” The experimental,computation, and time resources necessary to answer this question consume significant resources due to the predominantly trial-and-error based approaches common in materials research. This dissertation reintroduces a number of fundamental thermodynamics-based tools for the study of...
- Keyword:
- Density Functional Theory, Aqueous Synthesis, Driving Force, Thermodynamics, Pourbaix Diagram, and Speciation
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Walters, Lauren Nichole
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16360 and etdadmin_upload_946544
-
- Description:
- Understanding organization of soft materials on mesoscopic and nanoscopic scales is importantfor materials design. In this regard, non-van der Waals interactions such as hydrogen bonding and electrostatic interactions offer great opportunities due to the richness and diversity in morphological structures they produce. The primary reason for this is that these...
- Subject:
- Molecular physics and Materials Science
- Creator:
- Prusty, Debadutta
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16315 and etdadmin_upload_938426
-
- Description:
- Since its introduction as an artist’s pigment in the earth 20th century, titanium white has become one of the most common white pigments. The early formulations of titanium white contained anatase, which has been studied to facilitate degradation of oil paint under UV illumination. Around the 1940s production shifted to...
- Subject:
- Materials Science and Computational chemistry
- Creator:
- Schmitt, Thomas
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_941215 and http://dissertations.umi.com/northwestern:16325
-
- Description:
- Wireless power strategies are critical to system level implementation of bio-integrated devices. To achieve mechanically robust, manufacturable systems, batteries are often integrated as an on-board power source to support sensing, wireless communication and signal conditioning. Unfortunately, most sources of battery power use hazardous and environmentally harmful materials, which frustrate incorporation...
- Subject:
- Chemistry, Materials Science, and Biomedical engineering
- Creator:
- Huang, Ivy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_934213 and http://dissertations.umi.com/northwestern:16294
-
- Description:
- Biomineralization relies on the regulation of localized environments to control how minerals are formed. Through the use of confinement and specific additives, the organism is able to change the energy landscape of nucleation and growth to build single crystals with unusual morphologies. In order to better understand the environments in...
- Subject:
- Materials Science
- Creator:
- Duggins, Danielle
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_937458 and http://dissertations.umi.com/northwestern:16309
-
- Description:
- Industrial processes heavily rely on catalysts to control product selectivity and lower energy barriers required for chemical transformations. Catalysts are most commonly solid heterogeneous catalysts that facilitate separations from reaction mixtures and enhance recyclability. Heterogeneous catalysts used in industrial processes exhibit efficacious results, but in certain instances drawing structure-function relationships...
- Keyword:
- Polymerization, Oligomerization, Metal–Organic Frameworks, Structure-property relationships, and Heterogeneous catalysis
- Subject:
- Chemistry and Materials Science
- Creator:
- Goetjen, Timothy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_938937 and http://dissertations.umi.com/northwestern:16320
-
- Description:
- Selecting the best material to deliver optimum performance in real-world applications is one of the most significant challenges in engineering. Hundreds of thousands of computationally-predicted, but experimentally unexplored materials exist today in the public inorganic material databases as candidates for consideration. This thesis discusses three projects in the domain of...
- Keyword:
- statistical modeling, materials design, uncertainty quantification, materials selection, computational materials, and materials informatics
- Subject:
- Materials Science
- Creator:
- Gopakumar, Abhijith Mini
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_947056 and http://dissertations.umi.com/northwestern:16368
-
- Description:
- From the early usage of metallic thin films as mirrors tracing back to 2900 BC, to the modern thin film photonic circuits as a mature optical processing platform, and to the growing class of atomically-thin two-dimensional (2D) materials with diverse and tailorable properties, thin film materials have played an important...
- Keyword:
- Two-dimensional materials, Photonic circuits, Thin film materials, Topological photonics, Electron-beam lithography, and Optical materials
- Subject:
- Physics and Materials Science
- Creator:
- Liu, Pufan
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_946295 and http://dissertations.umi.com/northwestern:16358
-
- Description:
- In this dissertation, I summarize my findings of the dynamics of colloidal suspensions over a large range of volume fractions in two systems: drop impact and film rupture. The existence of a deformable surface in both these systems allows me to capture the consequences of non-Newtonian flow using high-speed imaging....
- Keyword:
- shear rheology, drop impact, Fluid dynamics, High-speed imaging, Soft matter, and Colloidal suspensions
- Subject:
- Physics and Materials Science
- Creator:
- Shah, Phalguni S.
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_937776 and http://dissertations.umi.com/northwestern:16311
-
- Description:
- Elemental powder blends are an emerging alternative to prealloyed powders for high-throughput alloy design via additive manufacturing techniques due to their flexibility, low cost, and ease of customization. This dissertation investigates elemental alloying elements (Sc and Zr) which are high-melting and highly reactive, unlike previous work which focused on more...
- Keyword:
- additive manufacturing, in situ diffraction, elemental blends, laser powder-bed fusion, aluminum, and creep
- Subject:
- Materials Science
- Creator:
- Glerum, Jennifer Anne
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16304 and etdadmin_upload_936163
-
- Description:
- Protein-based biomaterials are widely used in biomedical applications and mechanical support because of their novel structural flexibility, biocompatibility and mechanical properties. Protein-based biomaterials outperform traditional synthetic materials in various environments as traditional materials lack the diverse chemical functionalities that proteins offer. Novel bioinspired techniques such as directed evolution offer the...
- Subject:
- Bioengineering, Materials Science, and Chemical engineering
- Creator:
- Chen, Yusu
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16130 and etdadmin_upload_912201
-
- Description:
- Sea urchins are virtuosi of biomineralization, the process by which organisms build mineralized tissues. The embryonic animal exemplifies this with the formation of its endoskeletal spicule. The primary mesenchyme cells (PMCs) undertake spicule synthesis, which involves deposition of the initial granule, elongation of the spicule, and several choreographed changes...
- Keyword:
- Biomineralization, Spicule, Sea urchins, and Calcite
- Subject:
- Materials Science
- Creator:
- Moreno, Bradley Keck
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16210 and etdadmin_upload_926575
-
- Description:
- Van der Waals, or layered, materials offer a flexible platform to tune properties via exfoliation down to the single- or few-layer limit; they are at the forefront of cutting-edge materials science and engineering research because of the innumerable ways to tune materials as a function of thickness or composition. Due...
- Keyword:
- liquid-phase exfoliation, van der Waals materials, ambient-reactive, two-dimensional materials, and solution processing
- Subject:
- Materials Science
- Creator:
- Lam, David
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_913984 and http://dissertations.umi.com/northwestern:16137
-
- Description:
- Polymer and polymer/ceramic composites known as bone cements are commonly used in musculoskeletal reconstructive surgeries where bone tissue fixation, reinforcement, or void filling may be needed. Polymethylmethacrylate, PMMA, was the initial (and currently only) FDA-approved bone cement for bone-void filling applications yet faces many inherent material-based challenges that impacts its...
- Keyword:
- Citrate-based biomaterials, V70, Hydroxyapatite, Bone Cement, Vertebral Body Fractures, and Polymethylmethacrylate
- Subject:
- Polymer chemistry, Materials Science, and Biomedical engineering
- Creator:
- Huddleston, Samantha
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16143 and etdadmin_upload_915696
-
- Description:
- Over 10 billion tons of concrete are produced for the construction industry every year, making concrete the second most used substance on Earth, only surpassed by water. With such high importance as a building material, there is significant need for the ability to accurately model concrete behavior. As a quasi-brittle...
- Keyword:
- Lattice Discrete Particle Model, Concrete, Micromechanics, Dynamics, Numerical Models, and Size Effect
- Subject:
- Materials Science, Computational physics, and Civil engineering
- Creator:
- Troemner, Matthew
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_878306 and http://dissertations.umi.com/northwestern:15920
-
- Description:
- The development of functional materials with rationally designed hierarchical structure is an interdisciplinary challenge. Looking to nature for inspiration, we use small molecules that engage in directed self-assembly through carefully tuned intermolecular interactions to construct materials that have structure at multiple length scales. In this work, supramolecular structures formed using...
- Subject:
- Materials Science
- Creator:
- Cotey, Thomas James
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16069 and etdadmin_upload_902349
-
- Description:
- Engineering responses of soft materials at hierarchical time and length scales is of great interest to both fundamental science and technological applications. In recent years, the hybridization between emerging soft condense matters and conventional hard condense matters keeps enriching the materials library of humankind and opens another largely-uncharted venue for...
- Keyword:
- Collective Behavior, Soft Materials, Stimuli-responsive Materials, Active Colloids, Active Matter, and Stokesian Dynamics
- Subject:
- Physics, Materials Science, and Computational physics
- Creator:
- Yuan, Hang
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16039 and etdadmin_upload_900796
-
- Description:
- In the face of a changing climate caused by anthropomorphic release of carbon dioxide and other greenhouse gases, major governments have committed to the reduction of CO2 and other emissions over time, requiring increased reliance on forms of carbon-free renewable energy. The inherent intermittency of renewable electricity sources creates a...
- Keyword:
- additive manufacturing, Solid oxide electrolyzer, Solid oxide fuel cell, ceramics, exsolution , and 3D-printing
- Subject:
- Nanoscience, Materials Science, and Engineering
- Creator:
- Geisendorfer, Nicholas R
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_873708 and http://dissertations.umi.com/northwestern:15899
-
- Description:
- Solid oxide fuel and electrolysis cells (SOFCs and SOECs) must be engineered with the entire lifetime of their performance in mind. Electrochemical activity will decrease as degradative processes take effect, leading to higher overpotentials and decreased power outputs. Materials science and engineering can stave off these inefficiencies through an understanding...
- Keyword:
- electrochemistry, ALD, ionics, SOFC, exsolution, and transportation
- Subject:
- Alternative energy, Materials Science, and Energy
- Creator:
- Schmauss, Travis Anthony
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15966 and etdadmin_upload_885008
-
- Description:
- Dendritic microstructures form during the solidification of a variety of metal parts, from traditionally cast engine blocks to 3D-printed specialty tooling. These dendrites can evolve through growth, coarsening, fragmentation, and the formation of a Columnar-to-Equiaxed Transition (CET), which all can greatly affect material properties. However, the basic science behind these...
- Subject:
- Materials Science
- Creator:
- Thompson, Zachary
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15913 and etdadmin_upload_876872
-
- Description:
- Interfacial science brings together diverse areas of interest such as electronic materials, quantum materials, bio-membranes and catalysts. In-situ X-ray characterization techniques can be used to understand the assembly of atoms, molecules and supported nanoparticles at interfaces in complex environments. This thesis work focuses on the use of various X-ray characterization...
- Keyword:
- Atomic Layer Deposition, X-ray standing wave, Catalysis, Thin film, X-ray spectroscopy, and X-ray physics
- Subject:
- Physics and Materials Science
- Creator:
- Das, Anusheela
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15916 and etdadmin_upload_877997
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