Oxidation processes play an integral role in many industries, but questions still remain regarding the mechanisms of carbon-hydrogen bond activation and oxidation in free-radical and catalyzed processes. Microkinetic modeling is a powerful tool capable of examining oxidation processes at the mechanistic level to gain understanding and guide catalyst applications. This...
In the past decade, scholars, the news media, and the public have turned increased attention to the activity of atheists in the West. Atheism serves as a source of identity and community in todays society, signaling more than a simple lack of belief in god(s). This dissertation is a cultural...
In this dissertation thesis, I introduce three-dimensional (3D) image reconstruction algorithms for multi-focus microscopy (MFM). MFM provides a fast way to obtain 3D information of the sample by simultaneously capturing multiple focal planes on a single camera shot. However, stacking the sub-images from different focal planes does not provide a...
Small molecules such as indanes, chromanes, tetralins and their derivatives play a significant role in drug discovery due to their potent biological activity. This research herein presents a facile Brønsted acid-catalyzed allylsilane annulation methodology to generate fused ring systems such as indanes. The reaction goes through a homoallylic intermediate which...
This dissertation consists of three essays in Microeconomic Theory that study the interplay between mechanism and information design, provide insights into the design of efficient dispute resolution mechanisms for partnerships, and analyze the stability of fractional matchings in two-sided markets.', "In the first chapter, we study the optimal disclosure policy...
It is pertinent now more than ever that we find sustainable alternatives to produce chemicals. For decades, scientists and engineers have turned to biological systems to help meet societal needs in energy, medicine, materials, and moreespecially when chemical synthesis is untenable. Often, biologically-produced small molecules are insufficient for production at...
Holy Mediocrity: Saintly Matrons and the Dominicans in Late Medieval Italy', 'Julia Lauren Miglets', 'The task of this study is to explain why a cluster of female saints who were noted not for their miracles but for the moderate even boring quality of their sanctity, a paradigm I call holy...
This thesis studies three approaches for solving linear programs with complementarity constraints (LPCC). The focus of Chapter 2 lies on difference-of-convex (DC) penalty formulations and the associated difference-of-convex algorithm (DCA) for computing stationary solutions of LPCCs. We concentrate on three such formulations and establish connections between their stationary solutions and...
In this dissertation, efforts are detailed to utilize semiquinoid bridging ligands to impart strong magnetic coupling between metal centers. Chapter 1 introduces the synthetic challenge of realizing molecule-based magnets with high operating temperatures due to weak magnetic coupling between spin centers through large, diamagnetic ligands. An alternative strategy is described...
The cerebellum contributes to movement initiation, execution, and adaptation. Primary cerebellar neurons receive synaptic inputs related to sensory stimuli and motor commands, leading to modulation of their firing. Furthermore, synaptic input differs substantially between cerebellum-dependent behaviors. I have made voltage- and current-clamp recordings from Purkinje and eurydendroid neurons in the...