Electron transfer theory predicts reorganization energy to be one factor that determines the electrochemical potential of a metal ion. This paper describes part of a study that aims to increase understanding of solvent reorganization energy in noncovalent systems by systematically varying the environment around a metal ion, specifically ruthenium. The...
In this study, ligands modified to contain
a metal ion were synthesized and their
electrochemical properties were examined
alone and in the presence of a protein. We
chose to use avidin and biotin as a model
system. Probes have been developed in
which biotin is modified to coordinate to