The work presented in this dissertation focuses on ceramic anode materials for solid oxide fuel cells (SOFCs). The primary goal was to characterize the anode and relate the electrochemical behavior to the microstructure. The anode that was most extensively studied in this work was a composite of Gd0.10Ce0.90O1.95 (GDC) and...
The addition of nanoparticles into polymer materials has been observed to dramatically change the mechanical, thermal, electrical, and diffusion properties of the host polymers, promising a novel class of polymer matrix composite materials with superior properties and added functionalities that are ideal candidates in many applications, including aerospace, automobile, medical...
This dissertation combines critical ethnography, critical performance and historical analysis to examine three Trinidadian dance companies - Malick Folk Performing Company, Shiv Shakti Dance Company, and Noble Douglas Dance Company Inc. - asking how each choreographs Trinidadian discourses of race/ethnicity, class and national belonging through its own uniquely crafted embodied...
The neurotropic alphaherpesviruses infect and spread trans-synaptically within the vertebrate nervous system. Recurrent diseases are often manifested at the periphery of the host organism but occasional dissemination of the virus to the brain results in fatal encephalitis. Interactions between viral and host cellular proteins are integral to the success of...
The kinetics of nanoscale Cu-rich precipitates of multicomponent concentrated steels has been investigated utilizing primarily APT and supplemented with a synchrotron radiation experiment, first-principles calculations, Thermo-Calc study, and CTEM (at the longest aging time). Results on mechanical properties and microstructure at a greater length scale are also presented. The studied...
Conjugated organic molecules and polymers hold significant promise for use as active materials in electronic devices. Employing such "soft" materials can decrease cost of device fabrication, while enabling unique properties such as mechanical flexibility, large-area coverage, and highly tunable materials properties. A primary roadblock to the realization of this dream...
The recent tightening of permissible NOx release from diesel-powered engines has intensified the search for a catalytic system that can effectively remove NOx under challenging diesel exhaust conditions. Hydrogen-assisted selective catalytic reduction (H2-SCR) using supported palladium catalysts offers significant promise for lean NOx treatment due to its high activity at...
In the first chapter of my dissertation, I study the effects of an exogenous increase in government spending in models incorporating price and wage nominal rigidities. I find that the effects of price stickiness on the output multiplier depend crucially on the behavior of the monetary authority. If the monetary...
The prediction of multicomponent adsorption equilibria from pure component data alone has been an active research area for over forty years. The Ideal Adsorbed Solution theory (IAS) has been the standard method of doing so, but contains an embedded assumption of Langmuir mixing. This assumption causes its predictions to be...
Drawing on seven years of ethnographic fieldwork, as well as interviews, crime statistics, and census data, this study documents the demolition and redevelopment of a predominately African-American housing development in Chicago. I describe how living in a hypersegregated, high crime neighborhood affects the way residents use, affectively feel, and navigate...
Humans routinely answer questions, make decisions, and provide explanations in the face of incomplete knowledge and time constraints. From everyday questions like "What will it cost to take that vacation?" to policy questions like "How can a carbon taxing scheme affect climate change?" we often do not have all the...
This dissertation is a textual history of Thomas Paine's Common Sense and the American independence movement during the first half of 1776. The study uses the methodologies and vocabularies of rhetorical studies, early modern history, and political theory to analyze the 180-degree turn in colonial public opinion away from a...
Cellular interactions are important for the development and maintenance of tissue structural integrity. In the developing neuroepithelium, the adherens junction proteins, N-cadherin and β-catenin, are highly enriched at the apical surface of the proliferative ventricular zone and have been suggested to have critical functions in ensuring the proper development of...
This dissertation aims at contributing to the literature of organizational learning and organizational change. More specifically, this dissertation focuses on three fundamental issues of exploitation and exploration: the relationship between exploitation and exploration, the balance of exploitation and exploration, and the performance implications of exploitation and exploration. This dissertation comprises...
In three essays, this dissertation examined the associations between child characteristics, interparental discord and various aspects of child development and physiological functioning. In the first essay, using longitudinal, nationally representative data on infants and their families from the early childhood longitudinal study (ECLS-B), results revealed small, but significant associations between...
We can represent many real-world data sets as data streams and/or high-dimensional data. Major stock market such as New York Stock Exchange (NYSE) trades more than 8000 financial products daily, which generates massive trading time series in the form of data streams. NetFlow and DNS querying data generated by real-time...
The perinucleolar compartment is a nuclear substructure that is associated with, but structurally distinct from the nucleolus. Previous studies have shown that the PNC preferentially forms in cancer cells and PNC prevalence (% of non-mitotic and non-apoptotic cells in a population with one or more PNC) is a prognostic in...
In the same way that a sculptor shapes a block of stone to reveal the ideal form within, one's relationship partner can help one to become more like one's ideal self (Drigotas, Rusbult, Wieselquist, & Whitton, 1999). This interpersonal process is called "the Michelangelo phenomenon." The current research examines whether...
A study of the optical properties and superconductivity in semiconductors is presented using the highly precise all-electron full-potential linearized augmented plane wave (FLAPW) density functional calculations.
Optical properties [$\varepsilon(\omega)$,$n(\omega)$,$k(\omega)$,$R(\omega)$ and $\alpha(\omega)$] of some III-V semiconductors [InAs, InSb, GaSb, and AlSb] and their critical point (CP) energies, are calculated from the...
On average, homosexual people are more gender nonconforming than heterosexual people. They also show increased distress, possibly due to their stigmatized minority status. Not surprisingly, gender nonconformity and psychological distress may be related, particularly in homosexual men (e.g., Skidmore, Linsenmeier, & Bailey, 2006), although the mechanisms explaining this relationship have...