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Photoexcited Rylenediimide Radical Anions and Dianions for the Photoreduction of Carbon Dioxide Reduction Catalysts

Description:

The development and use of organic anionic chromophores that absorb the entire visible spectrum & into the near-infrared region while providing highly reducing equivalents is pinnacle for artificial photosynthesis. This dissertation investigates the rational design of new donor-acceptor systems for artificial photosynthesis that couple naphthalene diimide (NDI)/perylene diimide (PDI) radical...

Keyword:

Naphthalene Diimide, Perylene Diimide, Carbon Dioxide, Re(bpy)(CO)3, Mn(bpy)(CO)3, and Radical Anions

Subject:

Organic chemistry and Physical chemistry

Creator:

Martinez, Jose Fabian

Owner:

Scholarly Digital Publishing

Language:

en

Date Uploaded:

02/12/2020

Date Created:

2018-01-01

Resource Type:

Dissertation

Alternate Identifier:

etdadmin_upload_613990 and http://dissertations.umi.com/northwestern:14388
Charge Transport, Trapping, and Interfacial Effects in High Electron Affinity Arylene Diimide Semiconductor Thin Films

Description:

Small molecule organic materials based on perylene- and naphthalene- diimide are synthesized and characterized for use as semiconductor thin films in organic field-effect transistors. The orbital energetics of the materials are investigated via electrochemical, spectroscopic, and computational techniques. The thin film solids are characterized by x-ray diffraction techniques and surface...

Keyword:

Air-stable, Perylene Diimide, n-Type, Semiconductor, and Organic Electronics

Subject:

Chemistry

Creator:

Brooks A Jones

Owner:

Scholarly Digital Publishing

Date Uploaded:

08/07/2018

Date Modified:

08/07/2018

Date Created:

2007-09-21

Resource Type:

Dissertation

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Photoexcited Rylenediimide Radical Anions and Dianions for the Photoreduction of Carbon Dioxide Reduction Catalysts

Charge Transport, Trapping, and Interfacial Effects in High Electron Affinity Arylene Diimide Semiconductor Thin Films

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