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Photocontrolled Polymerization of Aryl Grignards for Pi-Conjugated Polymer Synthesis

Description:

Part I:Current approaches to synthesize π-conjugated polymers are dominated by thermally driven, transition-metal-mediated reactions. Herein we7 show that electron-deficient Grignard monomers readily polymerize under visible-light irradiation at room temperature in the absence of a catalyst. The product distribution can be tuned by the wavelength of irradiation based on the absorption...

Keyword:

Photopolymerization, Polymer, and Grignard

Subject:

Organic chemistry, Polymer chemistry, and Chemistry

Creator:

Woods, Eliot Freshwater

Owner:

Scholarly Digital Publishing

Language:

en

Date Uploaded:

02/02/2022

Date Created:

2021-01-01

Resource Type:

Dissertation

Alternate Identifier:

etdadmin_upload_853517 and http://dissertations.umi.com/northwestern:15807
Design Driven Multi-scale Mechanical Property Characterization of Polymer Composites

Description:

There is no group of materials as diverse, complex, and ubiquitous as polymers. From plastic bags, to rubber tires, electronics, food packaging, water filtration and even aerospace applications, the penetration of polymer materials into all aspects of life make them very important materials throughout all engineering fields. However, this breadth...

Keyword:

Characterization, Materials Design, Polymer, Composite, and Mechanical Properties

Subject:

Mechanics, Polymer chemistry, and Materials Science

Creator:

Eaton, Matthew David

Owner:

Scholarly Digital Publishing

Language:

en

Date Uploaded:

04/15/2021

Date Created:

2020-01-01

Resource Type:

Dissertation

Alternate Identifier:

etdadmin_upload_763586 and http://dissertations.umi.com/northwestern:15243

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Photocontrolled Polymerization of Aryl Grignards for Pi-Conjugated Polymer Synthesis

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