Composites of metal nanoparticles encapsulated by metal-organic frameworks (NP@MOFs) have recently emerged as intriguing heterogeneous catalysts for regioselective reactions. Sharing qualities of both zeolites and enzymes, these catalysts employ the pore system of a MOF to direct reactant access to the surface of nanoparticles. This dissertation seeks to better understand...
The safe and efficient storage of hydrogen is possibly the chief obstacle to its use as a fuel on a large scale. Metal-organic frameworks (MOFs) are well poised to provide unique solutions to hydrogen storage, and gas storage in general, a result of their crystalline, porous networks that present the...