Over the last several decades, market-driven needs created a vast assortment of products with micron-sized features. To achieve the necessary levels of precision and accuracy, a synergistic approach was undertaken, where both material addition and subtraction was employed in the creation of the desired parts. However, currently employed micromanufacturing processes...
Molecular self-assembly is a process in which molecules spontaneously form ordered aggregates, the process of which is important in the natural world, considering those ordered systems and complex architectures contained in a living cell. The goal of chemists is to design simple molecules or chemical systems that can undergo molecular...
How molecular chirality manifests at the nano- to macroscale has been a scientific puzzle since Louis Pasteur discovered biochirality. In general, amphiphilic molecules can organize into a variety of assembly shapes including micelles, spherical vesicles, cylindrical micelles, and planar bilayers. However, when such amphiphilic molecules are chiral, helical ribbons, helicoidal...
Developing materials with comparable structural complexity and programmed hierarchy as those found in nature is a grand challenge in materials science. One way to synthesize soft materials with these complex architectures is to use bottom-up self-assembly of nanoscale building blocks, mimicking how organisms grow tissues with specific functions from peptides,...
Bio-inspired materials have a distinct advantage over other materials by virtue of their mimicry of nature’s own products, which have been subjected to the inimitable tests of time and evolutionary pressure. Here we have taken instruction from natural nanostructures that are ubiquitous across the animal kingdom, namely high-density lipoproteins (HDL)....
This dissertation investigates the use of organic and semiconductor nanomaterials as chromophores in solar fuels production and energy transfer-mediated [2+2] cycloadditions. A series of novel N-annulated perylene chromophore amphiphiles was synthesized via a modular synthesis. These perylene amphiphiles were found to self-assemble in aqueous solution, forming extended ribbon-like nanostructures that...
High relaxivity contrast agents are of great importance in the advancement of magnetic resonance imaging diagnostics for use in biomaterials. Biomaterials that are implanted into the body, with the goal of repairing or regenerating lost or damaged tissue, need to be tracked noninvasively, over time. I have completed work using...
For bone regeneration, there is need for biodegradable, synthetic scaffolds that direct the formation of <em>de novo</em> mineralized tissue. Orthopaedic implants additionally require mechanical function. The work described herein attempts to address both of these needs. The general strategy involves integrating molecularly designed tissue engineering scaffolds with porous metallic foams...
The important application for the infrared photodetectors is mainly thermal imaging by focal plane arrays (FPAs) for military and commercial purposes. So far, most mid-wavelength infrared (MWIR) and long-wavelength infrared (LWIR) FPAs are based either on HgCdTe (MCT) or quantum well infrared photodetectors (QWIPs). Even though those technologies are well...
Intermolecular charge transfer between electron-rich donor and electron-poor acceptor molecules offer great promise in the development of novel, low-cost electronic materials. It is hypothesized that control over the intermolecular interactions and supramolecular self-assembly of these systems could tune electronic properties and discover new functions. To that end, a series of...