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Studies in Natural Product Synthesis: Towards (1) Tambromycin and (2) the Solamin Stereoisomers

Description:

Total synthesis of natural products provides an avenue for investigation of complex chemical scaffolds, not only delivering access to biologically impactful molecules but also lending a deeper understanding of their inherent chemical reactivity. Expansion of reaction methodology, optimization of biological activity, and absolute structural confirmation can all be accomplished via...

Keyword:

allene, total synthesis, peptide, traceless Petasis reaction, natural product, and organic synthesis

Subject:

Organic chemistry and Chemistry

Creator:

Rote, Jennifer

Owner:

Scholarly Digital Publishing

Language:

en

Date Uploaded:

02/01/2021

Date Created:

2020-01-01

Resource Type:

Dissertation

Alternate Identifier:

http://dissertations.umi.com/northwestern:15164 and etdadmin_upload_750061
Studies Directed Towards the Total Synthesis of Okilactomycin and Chrolactomycin

Description:

Okilactomycin and chrolactomycin are antitumor antibiotics isolated in 1987 and 2001, respectively. These tetracyclic natural products possess a unique 6-5 fused tetrahydropyrone-butyrolactone. The spirocenter is part of a highly functionalized cyclohexene ring, which together with the aforementioned 6-5 system compose the core of these molecules. A six carbon, 1,3-dialkyl-substituted carbon...

Keyword:

natural products and total synthesis

Subject:

Chemistry

Creator:

William Joseph Morris

Owner:

Scholarly Digital Publishing

Date Uploaded:

08/13/2018

Date Modified:

08/13/2018

Date Created:

2007-06-26

Resource Type:

Dissertation

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Studies in Natural Product Synthesis: Towards (1) Tambromycin and (2) the Solamin Stereoisomers

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