This dissertation analyses the ways in which football, known as soccer in the United States, has historically served as a diasporic space for the articulation of black politics in the second half of the twentieth century. While modern sport is characterized as an apolitical cultural practice, I am interested in...
Polyolefins are the most versatile and widely used polymers worldwide. Depending on the polymer microstructure, polyolefins can exhibit a wide range of useful and tailored properties and applications. Metal-catalyzed coordinative olefin polymerization plays a center role in advancing polyolefin synthesis. This dissertation explores two strategies to modulate the polymer microstructures...
Over a decade has passed since Hurricane Katrina impacted the Gulf Coast. The city of New Orleans, was one of the more severely damaged areas in the region, experiencing 80% damage. This dissertation analyzes the rebuilding of New Orleans and it questions the role that colonial legacies play in that...
Spherical Nucleic Acids (SNAs) are unique class of nanomaterial characterized by a dense nucleic acid shell conjugated to a nanoparticle core. This radial orientation of oligonucleotides and architecture distinguishes SNAs from the components from which they are comprised. Specifically, unique chemical and biological properties emerge that are not observed with...
Two unique structures make up the nucleus of our Galaxy on different scale sizes. On a broad scale of a few hundreds of parsecs, there is the well-known central molecular zone which comprises a substantial component of the gas in the Galaxy. The other, known as the mini-spiral, is streamers...
This thesis describes the relationships between nanoscale structure and particle transport in two systems: i) the transport and conversion of excitons in colloidal quantum dot (QD) assemblies and ii) the transport of carriers in flashing electron ratchets. One major crux in the creation of efficient photocatalytic systems is the low...
People evidence behaviors that engender hope for future behavior change, but also evidence this hope when there is no reason to believe that any behavior change will occur. For example, prior research suggests that temporal factors make people susceptible to change their minds over time, and a confluence of cognitive...
Bias pervades all stages of the American criminal justice system. The system is a human creation, run by fallible people who bring prejudices and biases to their work just like everyone else. The first step to ridding the system of those biases is to fully understand the way they manifest...
Context: Crowd logistics is a novel shipping concept where delivery operations are carried out by employing existing vehicle capacity and drivers from the crowd, relying on their planned tours, thereby offering potential for economic, social, and environmental benefits. Despite the promise of this new logistics model, little is known about...
Spin-orbit coupling (SOC) is a powerful phenomenon that dictates the functional properties of transition metal complexes essential for information processing, catalysis, and magnetism. Though it is relegated to lower energy scales within the orbital description of first-row transition metal complexes, SOC impacts crucial aspects of electronic structure such as promoting...