Preventing the build-up of indoor pollutants represents an emerging goal in environmental chemistry. Heterogeneous catalysis provides an attractive method of remediating indoor air pollution, but optimization through rational catalyst design requires a detailed understanding of the catalytic surface and surface-pollutant interactions. In this work, a chemical ionization mass spectrometry (CIMS)...
What is the nature of the relation between a verb and its arguments? In this dissertation, I look to evidence from language acquisition for answers.
Any theory of ditransitives must explain certain structural asymmetries noted for both double-object (DO) datives (e.g. Alfonso gave Derek the bat) and prepositional datives (Alfonso...
This thesis contains four essays on the organization (both internal and external) of health care in the US. The first essay examines a mechanism through which individual workers acquire (or maintain) competence, namely that of experience. Specifically, I analyze whether cardiac surgeons who perform more procedures experience an improvement in...
This dissertation examines and seeks to revitalize the concept of "distraction," through an analysis of the changes it underwent in German-speaking philosophy, critical theory, and literature between the World Wars. Defying the sociological and psychological norms of the period, Franz Kafka, Martin Heidegger, and Walter Benjamin refused to treat distraction...
Constructing 3D objects from 2D images has been an active research area for decades. Given captured 2D information from various devices, different techniques were developed to assign 3D positions to the target object. However, methods for reconstructing a 3D model from a single 2D image remain largely manual and labor-intensive....
Small molecule organic materials based on perylene- and naphthalene- diimide are synthesized and characterized for use as semiconductor thin films in organic field-effect transistors. The orbital energetics of the materials are investigated via electrochemical, spectroscopic, and computational techniques. The thin film solids are characterized by x-ray diffraction techniques and surface...
One of the current goals in the biomaterials research is to develop implants with improved osteoconductivity and long-term stability. Thanks to its chemical similarity to the mineral phase of natural bone, hydroxyapatite (HA) has been extensively studied and clinically tested as a coating on metallic substrates, to obtain bioactive implants...
Age-related maculopathy (ARM) is a leading cause of legal blindness in the elderly in the world. Currently, the physiological and ultrastructural bases for the development of ARM remain unclear. Many studies have proposed that the morphological changes, particularly the accumulations of lipids with aging, in Bruch's membrane - an extracellular...
Direct dynamics quasiclassical trajectory (QCT) calculations are performed to study the dynamics of model atom + polyatom reactions. In the first part of this thesis, we examine adiabatic dynamics of H/O reaction with simple alkanes, CD4 and C2H6. Overall good agreement with state-of-the-art experiments shows that the molecular motion is...
Barbed end regulation is critical to the formation of the actin-based protrusive structures, lamellipodia and filopodia. In this body of work we have chosen to focus on two main activities, filament termination by the heterodimeric Capping protein (CP) and continued filament elongation by the Ena/VASP family of proteins. We demonstrate...