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-
- Description:
- Two-dimensional (2D) hybrid halide perovskites have been the response to their exciting but woefully unstable 3D counterparts. These 2D perovskites have been shown to have respectable stabilities as photovoltaic absorbers, yet they lag behind the 3D perovskites in terms of efficiency. With the need to catch up to the efficiencies...
- Keyword:
- solar cells, perovskites, films, GIWAXS, materials, and mechanisms
- Subject:
- Chemistry and Materials Science
- Creator:
- Hoffman, Justin Michael
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15609 and etdadmin_upload_827302
-
- Description:
- A framework is developed that models point defect diffusion and interaction with pre-existing microstructures during irradiation, including defect-defect interactions and defect sinks. This framework uses a modified diffusion potential that includes not only defect concentration, but also intrinsic stresses from the pre-existing microstructure. Various microstructures are studied in {Fe} by...
- Keyword:
- Grain boundaries, Voids, Point defects, Radiation, Crack tip, and Triple junctions
- Subject:
- Materials Science, Mechanical engineering, and Nuclear engineering
- Creator:
- Zarnas, Patrick
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15639 and etdadmin_upload_831637
-
- Description:
- The highly flexible nature of 2D materials has led to them becoming fundamental building blocks for achieving novel device physics and potential breakthroughs in practical technologies. 2D layers can be interfaced in a wide array of methods with themselves, other 2D layered materials, or materials of entirely different type or...
- Keyword:
- Heterojunction, Two-Dimensional, Low-Dimensional, Exciton, Heterostructure, and Monolayer
- Subject:
- Optics, Materials Science, and Condensed matter physics
- Creator:
- Stanev, Teodor Kosev
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15716 and etdadmin_upload_843489
-
- Description:
- Materials that exist as well-defined individual entities at the nanoscale typically have properties that sets them apart from their bulk form. Consequently, there has been much time and effort invested in developing new well-defined nanoscale entities, but few attempts to assemble them into bulk materials. On the other hand, there...
- Keyword:
- Processing, Nanowires, Scalability , Graphene, Conductive Polymer, and Metals
- Subject:
- Nanotechnology, Nanoscience, and Materials Science
- Creator:
- Prestowitz, Luke C
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15687 and etdadmin_upload_839947
-
- Description:
- Nanomaterials are increasingly incorporated in modern day life, from the biogenic viruses that cause pandemics and the mineral crystallites embedded alongside collagen in our bones, to the anthropogenic nanomaterials that are small but powerful components of sunscreen and paint, swimming pool algaecides and wound dressings, cancer treatments, bicycle frames, and...
- Subject:
- Nanoscience and Materials Science
- Creator:
- DiCorato, Allessandra Elizabeth
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_843461 and http://dissertations.umi.com/northwestern:15714
-
- Description:
- Metallic conductivity and broken inversion symmetry were long thought to be contraindicated properties, under the assumption that long-range Coulombic interactions (screened by free charge carriers) were necessary for coordinated polar displacements. Within the past decade, the discovery of polar metals has prompted a rethinking of the relationship between metallicity and...
- Keyword:
- first principles, contraindicated, polar, phase, ferroelectric, and metal
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Hickox-Young, Daniel Timothy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15762 and etdadmin_upload_845260
-
- Description:
- This thesis describes the synthesis and photophysical characterization of low-dimensionalmaterials—including thin-film semiconductors, colloidal quantum dots, and molecules—with the broader motivation of integrating them into mixed-dimensional heterostructures with novel responses to external stimuli. Due to their high surface area to volume ratio and incomplete dielectric screening, mixed-dimensional heterostructures have high sensitivity...
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Olding, Jack Nicklaus
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15691 and etdadmin_upload_840718
-
- Description:
- Soft materials in nature are formed through programmed self-assembly of biomolecules to create complex architectures and optimized physical properties. It is therefore a key challenge in biomaterials science and engineering to understand the principles that govern the structure and properties of such materials, and the interactions between their different components....
- Subject:
- Materials Science and Biomedical engineering
- Creator:
- Sangji, Mohammad Hussain
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2020-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_816157 and http://dissertations.umi.com/northwestern:15536
-
- Description:
- Nanoparticle synthesis is capable of producing particles with any combination of structure, chemistry, size, shape, and surface. All of the different combinations of these physical properties can produce nanoparticles with almost countless materials properties suited for many applications. Given this interest in using nanoparticles in so many different fields, including...
- Keyword:
- nanoparticle growth, thermodynamics, nanoparticles, kinetics, hydrothermal synthesis, and crystal growth
- Subject:
- Inorganic chemistry, Chemistry, and Materials Science
- Creator:
- Ly, Tiffany
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15645 and etdadmin_upload_832870
-
- Description:
- One of the central challenges in solid-state chemistry is synthetic control over structure. Owing to limited reactivity of Pb with transition metals at ambient pressure and high temperature as well as the variety of properties that emerge from the few known binary transition-metal–Pb compounds, this research focuses on accessing and...
- Subject:
- Chemistry and Materials Science
- Creator:
- Tamerius, Alexandra
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 10/07/2021
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_845128 and http://dissertations.umi.com/northwestern:15755
-
- Description:
- This thesis focuses on identifying structure-property-performance relationships in supported nanoparticle catalysts, where an active catalyst material is supported on a high surface area substrate. Identifying these relationships in supported nanoparticle catalysts can be quite challenging, as the complex structure of these catalysts results in numerous potential sources for changes to...
- Keyword:
- Surfaces, Catalysis, Nanoparticles, Interfaces, Density Functional Theory, and Electron Microscopy
- Subject:
- Materials Science and Chemical engineering
- Creator:
- Mansley, Zachary Ryan
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15855 and etdadmin_upload_862543
-
- Description:
- At its core, the purpose of microscopy is to make objects and their underlying structures visible under high magnification. With the remarkable progress of electron microscopy, the sub-micron “high” magnification of light microscopy has been completely refashioned to encompass subatomic length scales. Unfortunately, higher-magnification does little to negate existing interpretability...
- Keyword:
- Image Similarity, Computer Vision, Atomic-Resolution Microscopy, Global Structure Optimization, Self-Annotated Datasets, and Information Extraction
- Subject:
- Materials Science, Computational physics, and Computer science
- Creator:
- Schwenker, Eric
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15860 and etdadmin_upload_862806
-
- Description:
- Plasmonic nanoparticles have very large absorption cross sections and can concentrate the local density of photon states on the nano scale. When they are coupled to molecules or semiconductor nanocrystals and form different hybrid nanostructures, various light-matter interaction processes can be significantly enhanced or manipulated, including optical responses like fluorescence...
- Keyword:
- plasmon, nanostructures, and surface-enhanced Raman spectroscopy
- Subject:
- Physical chemistry and Materials Science
- Creator:
- Wu, Yue
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15861 and etdadmin_upload_862992
-
- Description:
- Electrochemical devices play a vital role in the efforts towards a sustainable green future. Solid acid based electrochemical cells, employing super protonic CsH2PO4 (CDP) as the electrolyte component, offer unique application advantages due to their operability at intermediate temperatures 250°C. At these temperatures, one can achieve improved reaction kinetics over...
- Keyword:
- oxynitrides, fuel cells, solid acid fuel cells , atomic layer deposition, solid acid electrolyzer cells, and molybdenum oxynitrides
- Subject:
- Alternative energy, Materials Science, and Energy
- Creator:
- Pandey, Shobhit A
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15837 and etdadmin_upload_858454
-
- Description:
- Nanocarriers are drug delivery vehicles that have at least one dimension at the nanoscale (10-9 m). Engineering the nanocarrier surface is a strategy for targeting drug delivery to specific cell types to enhance efficacy and minimize side effects. A useful analogy is to consider how the chassis of an automotive...
- Keyword:
- Nanotechnology, Glaucoma, Immunomodulation, Protein Adsorption, Nanocarrier Chassis, and Targeted Drug Delivery
- Subject:
- Pharmaceutical sciences, Materials Science, and Biomedical engineering
- Creator:
- Vincent, Michael Patrick
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15870 and etdadmin_upload_863441
-
- Description:
- Semiconductor nanocrystals possess unique photophysical properties that make them desirable for many optoelectronic applications such as photovoltaics, LEDs, and quantum computing. When the size of a semiconductor is reduced to below the excitonic Bohr radius of the material, its carriers becomes quantum confined resulting in drastic changes to optical, electronic,...
- Keyword:
- Nanocrystals, Spin, Semiconductors, Spectroscopy, Thermal properties, and Carrier Dynamics
- Subject:
- Physical chemistry, Chemistry, and Materials Science
- Creator:
- Harvey, Samantha
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_857543 and http://dissertations.umi.com/northwestern:15830
-
- Description:
- Materials science has been central to human advancement since time immemorial. There has always been curiosity around studying the processes required to extract materials, examine their structure, and ultimately tailor their properties to meet human needs. Over the last few centuries, the ability to tailor material properties was driven by...
- Keyword:
- Gaussian Process, Mixed Variable Machine Learning, Data Centric Design, Multicriteria Optimization, and Microstructure
- Subject:
- Materials Science, Statistics, and Design
- Creator:
- Iyer, Akshay
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_851800 and http://dissertations.umi.com/northwestern:15801
-
- Description:
- Engineering heat transport in materials is essential for thermal management in a wide range of technologies, from batteries to thermoelectrics. Materials host a wide spectrum of heat-carrying phonons, which vary in their frequency, spatial extent, and degree of plane-wave character. This diversity in phonon properties leads to complex behavior, especially...
- Keyword:
- thermal modelling, thermal conductivity, semiconductors, phonons, and thermoelectrics
- Subject:
- Physics and Materials Science
- Creator:
- Gurunathan, Ramya
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/02/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_856415 and http://dissertations.umi.com/northwestern:15824
-
- Description:
- Over 10 billion tons of concrete are produced for the construction industry every year, making concrete the second most used substance on Earth, only surpassed by water. With such high importance as a building material, there is significant need for the ability to accurately model concrete behavior. As a quasi-brittle...
- Keyword:
- Lattice Discrete Particle Model, Concrete, Micromechanics, Dynamics, Numerical Models, and Size Effect
- Subject:
- Materials Science, Computational physics, and Civil engineering
- Creator:
- Troemner, Matthew
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_878306 and http://dissertations.umi.com/northwestern:15920
-
- Description:
- The development of functional materials with rationally designed hierarchical structure is an interdisciplinary challenge. Looking to nature for inspiration, we use small molecules that engage in directed self-assembly through carefully tuned intermolecular interactions to construct materials that have structure at multiple length scales. In this work, supramolecular structures formed using...
- Subject:
- Materials Science
- Creator:
- Cotey, Thomas James
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16069 and etdadmin_upload_902349
-
- Description:
- Engineering responses of soft materials at hierarchical time and length scales is of great interest to both fundamental science and technological applications. In recent years, the hybridization between emerging soft condense matters and conventional hard condense matters keeps enriching the materials library of humankind and opens another largely-uncharted venue for...
- Keyword:
- Collective Behavior, Soft Materials, Stimuli-responsive Materials, Active Colloids, Active Matter, and Stokesian Dynamics
- Subject:
- Physics, Materials Science, and Computational physics
- Creator:
- Yuan, Hang
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16039 and etdadmin_upload_900796
-
- Description:
- In the face of a changing climate caused by anthropomorphic release of carbon dioxide and other greenhouse gases, major governments have committed to the reduction of CO2 and other emissions over time, requiring increased reliance on forms of carbon-free renewable energy. The inherent intermittency of renewable electricity sources creates a...
- Keyword:
- additive manufacturing, Solid oxide electrolyzer, Solid oxide fuel cell, ceramics, exsolution , and 3D-printing
- Subject:
- Nanoscience, Materials Science, and Engineering
- Creator:
- Geisendorfer, Nicholas R
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_873708 and http://dissertations.umi.com/northwestern:15899
-
- Description:
- Solid oxide fuel and electrolysis cells (SOFCs and SOECs) must be engineered with the entire lifetime of their performance in mind. Electrochemical activity will decrease as degradative processes take effect, leading to higher overpotentials and decreased power outputs. Materials science and engineering can stave off these inefficiencies through an understanding...
- Keyword:
- electrochemistry, ALD, ionics, SOFC, exsolution, and transportation
- Subject:
- Alternative energy, Materials Science, and Energy
- Creator:
- Schmauss, Travis Anthony
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15966 and etdadmin_upload_885008
-
- Description:
- Dendritic microstructures form during the solidification of a variety of metal parts, from traditionally cast engine blocks to 3D-printed specialty tooling. These dendrites can evolve through growth, coarsening, fragmentation, and the formation of a Columnar-to-Equiaxed Transition (CET), which all can greatly affect material properties. However, the basic science behind these...
- Subject:
- Materials Science
- Creator:
- Thompson, Zachary
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15913 and etdadmin_upload_876872
-
- Description:
- Interfacial science brings together diverse areas of interest such as electronic materials, quantum materials, bio-membranes and catalysts. In-situ X-ray characterization techniques can be used to understand the assembly of atoms, molecules and supported nanoparticles at interfaces in complex environments. This thesis work focuses on the use of various X-ray characterization...
- Keyword:
- Atomic Layer Deposition, X-ray standing wave, Catalysis, Thin film, X-ray spectroscopy, and X-ray physics
- Subject:
- Physics and Materials Science
- Creator:
- Das, Anusheela
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15916 and etdadmin_upload_877997
-
- Description:
- Graphene oxide (GO) is a heavily oxidized version of graphene, which is often made by oxidative chemical exfoliation from graphite powders. The reaction decorates the graphene sheets with oxygen-containing functional groups including hydroxyl and epoxide groups on the basal plane, as well as carboxyl groups on the edge, rendering the...
- Subject:
- Materials Science
- Creator:
- Huang, Haiyue
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_887181 and http://dissertations.umi.com/northwestern:15970
-
- Description:
- The past decade has seen the rapid progress of deep learning, which becomes a game-changing technique in different data-intensive domains, with the availability of large scale data, cost-effective computing hardware and more advanced learning theory and algorithms. Despite of the rapid progress of deep learning methods in daily-life applications, such...
- Keyword:
- Computational Photography, Representation Learning, Dataset Construction, Data Science, Computer Vision, and Deep Learning
- Subject:
- Materials Science, Information technology, and Computer science
- Creator:
- Jiang, Weixin
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_899812 and http://dissertations.umi.com/northwestern:16024
-
- Description:
- The successful isolation of graphene marked the advent of two-dimensional (2D) materials. Their atomically thin structures enable unprecedented electrical, optical, and mechanical properties, which have triggered significant research interests in the past decade. For instance, they are promising candidates for the fabrication of flexible electronics, biological sensors, battery electrodes, and...
- Keyword:
- Toughening, Transmission Electron Microscopy, Molecular Dynamics Simulations, In Situ Fracture Test, Polymer, and Two-dimensional Materials
- Subject:
- Materials Science, Mechanical engineering, and Engineering
- Creator:
- Zhang, Xu
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15978 and etdadmin_upload_889878
-
- Description:
- Thermoelectric devices utilize semiconducting n-type and p-type thermoelectric materials to convert heat into electricity. Despite their promise for deep space power generation or waste heat recovery, most high-performing thermoelectric materials reported in literature are absent in practical applications - partially due to inconsistent synthesis and poor mechanical performance. This work...
- Keyword:
- Thermoelectrics, Doping, Phase Equilibrium, Defects, Mechanical Properties, and Semiconductors
- Subject:
- Physical chemistry, Materials Science, and Energy
- Creator:
- Male, James Patrick
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_879755 and http://dissertations.umi.com/northwestern:15943
-
- Description:
- As the interest in rational synthesis for solid-state materials accelerates, there is an urgent need to understand the design principles concealed within these reactions. In situ material synthesis provides such an avenue to not only uncover these assembling rules, but also for finding new materials even in seemingly familiar phase...
- Keyword:
- Material Synthesis, Heteroanionic, In Situ, X-ray Diffraction, Solid-State Synthesis, and Rational Design
- Subject:
- Chemistry and Materials Science
- Creator:
- McClain, Rebecca
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15949 and etdadmin_upload_880527
-
- Description:
- Part I: Evaluating the relationship between Crosslink Kinetics and Thermodynamics with the hydrogel mechanics. The past two decades have witnessed a surge of applications built upon dynamic covalent chemistry (DCC), both attributed to the scope of developed reactions as well as their modularity.1-3 These reactions have comparable strengths to their...
- Keyword:
- Hydrogels, Rheology, Photoswitch, and Kinetics
- Subject:
- Organic chemistry, Polymer chemistry, and Materials Science
- Creator:
- Accardo, Joseph
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2021-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:15898 and etdadmin_upload_873494
-
- Description:
- The ability to control the crystalline ordering and morphology of polymeric nanomaterials is a grand challenge in the field of materials science, which could enable the development of functional materials able to solve long-standing problems in renewable energy and medicine. In this work, we explore a combination of supramolecular chemistry...
- Keyword:
- Regenerative Medicine, Supramolecular Polymer, Peptide Amphiphiles, Covalent Polymer, Photocatalysis, and Machine Learning
- Subject:
- Nanotechnology and Materials Science
- Creator:
- Bruckner, Eric Paul
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_894432 and http://dissertations.umi.com/northwestern:15994
-
- Description:
- Scalable processing of well-defined interfaces is key not only for wider application of two-dimensional (2D) materials in technology but also for improved fundamental understanding. Atomic layer deposition has useful characteristics, especially self-limited growth at low temperatures, that make it well suited for the production of uniform interfaces. Related processes, such...
- Keyword:
- van der Waals epitaxy, 2D material, and atomic layer deposition
- Subject:
- Nanotechnology and Materials Science
- Creator:
- Moody, Michael
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_889957 and http://dissertations.umi.com/northwestern:15979
-
- Description:
- Nanotechnology research broadly encompasses the exploration of the unique chemical,optical, electronic, or biological properties of materials with dimensions < 1 µm. Inorganic nanoparticles are one such class of materials, with properties that are exceptionally sensitive to particle size and structure. This is especially evident in the field of heterogeneous chemical...
- Keyword:
- Parallelized, Catalysis, Nanoreactor, Nanoparticle, and Synthesis
- Subject:
- Nanotechnology, Materials Science, and Chemical engineering
- Creator:
- Jibril, Liban
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 06/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16023 and etdadmin_upload_899605
-
- Description:
- Protein-based biomaterials are widely used in biomedical applications and mechanical support because of their novel structural flexibility, biocompatibility and mechanical properties. Protein-based biomaterials outperform traditional synthetic materials in various environments as traditional materials lack the diverse chemical functionalities that proteins offer. Novel bioinspired techniques such as directed evolution offer the...
- Subject:
- Bioengineering, Materials Science, and Chemical engineering
- Creator:
- Chen, Yusu
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16130 and etdadmin_upload_912201
-
- Description:
- Sea urchins are virtuosi of biomineralization, the process by which organisms build mineralized tissues. The embryonic animal exemplifies this with the formation of its endoskeletal spicule. The primary mesenchyme cells (PMCs) undertake spicule synthesis, which involves deposition of the initial granule, elongation of the spicule, and several choreographed changes...
- Keyword:
- Biomineralization, Spicule, Sea urchins, and Calcite
- Subject:
- Materials Science
- Creator:
- Moreno, Bradley Keck
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16210 and etdadmin_upload_926575
-
- Description:
- Van der Waals, or layered, materials offer a flexible platform to tune properties via exfoliation down to the single- or few-layer limit; they are at the forefront of cutting-edge materials science and engineering research because of the innumerable ways to tune materials as a function of thickness or composition. Due...
- Keyword:
- liquid-phase exfoliation, van der Waals materials, ambient-reactive, two-dimensional materials, and solution processing
- Subject:
- Materials Science
- Creator:
- Lam, David
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_913984 and http://dissertations.umi.com/northwestern:16137
-
- Description:
- Polymer and polymer/ceramic composites known as bone cements are commonly used in musculoskeletal reconstructive surgeries where bone tissue fixation, reinforcement, or void filling may be needed. Polymethylmethacrylate, PMMA, was the initial (and currently only) FDA-approved bone cement for bone-void filling applications yet faces many inherent material-based challenges that impacts its...
- Keyword:
- Citrate-based biomaterials, V70, Hydroxyapatite, Bone Cement, Vertebral Body Fractures, and Polymethylmethacrylate
- Subject:
- Polymer chemistry, Materials Science, and Biomedical engineering
- Creator:
- Huddleston, Samantha
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 09/22/2022
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16143 and etdadmin_upload_915696
-
- Description:
- A fundamental materials science question is “why and how will this material form?” The experimental,computation, and time resources necessary to answer this question consume significant resources due to the predominantly trial-and-error based approaches common in materials research. This dissertation reintroduces a number of fundamental thermodynamics-based tools for the study of...
- Keyword:
- Density Functional Theory, Aqueous Synthesis, Driving Force, Thermodynamics, Pourbaix Diagram, and Speciation
- Subject:
- Physics, Chemistry, and Materials Science
- Creator:
- Walters, Lauren Nichole
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16360 and etdadmin_upload_946544
-
- Description:
- Understanding organization of soft materials on mesoscopic and nanoscopic scales is importantfor materials design. In this regard, non-van der Waals interactions such as hydrogen bonding and electrostatic interactions offer great opportunities due to the richness and diversity in morphological structures they produce. The primary reason for this is that these...
- Subject:
- Molecular physics and Materials Science
- Creator:
- Prusty, Debadutta
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16315 and etdadmin_upload_938426
-
- Description:
- Since its introduction as an artist’s pigment in the earth 20th century, titanium white has become one of the most common white pigments. The early formulations of titanium white contained anatase, which has been studied to facilitate degradation of oil paint under UV illumination. Around the 1940s production shifted to...
- Subject:
- Materials Science and Computational chemistry
- Creator:
- Schmitt, Thomas
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_941215 and http://dissertations.umi.com/northwestern:16325
-
- Description:
- Wireless power strategies are critical to system level implementation of bio-integrated devices. To achieve mechanically robust, manufacturable systems, batteries are often integrated as an on-board power source to support sensing, wireless communication and signal conditioning. Unfortunately, most sources of battery power use hazardous and environmentally harmful materials, which frustrate incorporation...
- Subject:
- Chemistry, Materials Science, and Biomedical engineering
- Creator:
- Huang, Ivy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_934213 and http://dissertations.umi.com/northwestern:16294
-
- Description:
- Biomineralization relies on the regulation of localized environments to control how minerals are formed. Through the use of confinement and specific additives, the organism is able to change the energy landscape of nucleation and growth to build single crystals with unusual morphologies. In order to better understand the environments in...
- Subject:
- Materials Science
- Creator:
- Duggins, Danielle
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_937458 and http://dissertations.umi.com/northwestern:16309
-
- Description:
- Industrial processes heavily rely on catalysts to control product selectivity and lower energy barriers required for chemical transformations. Catalysts are most commonly solid heterogeneous catalysts that facilitate separations from reaction mixtures and enhance recyclability. Heterogeneous catalysts used in industrial processes exhibit efficacious results, but in certain instances drawing structure-function relationships...
- Keyword:
- Polymerization, Oligomerization, Metal–Organic Frameworks, Structure-property relationships, and Heterogeneous catalysis
- Subject:
- Chemistry and Materials Science
- Creator:
- Goetjen, Timothy
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_938937 and http://dissertations.umi.com/northwestern:16320
-
- Description:
- Selecting the best material to deliver optimum performance in real-world applications is one of the most significant challenges in engineering. Hundreds of thousands of computationally-predicted, but experimentally unexplored materials exist today in the public inorganic material databases as candidates for consideration. This thesis discusses three projects in the domain of...
- Keyword:
- statistical modeling, materials design, uncertainty quantification, materials selection, computational materials, and materials informatics
- Subject:
- Materials Science
- Creator:
- Gopakumar, Abhijith Mini
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_947056 and http://dissertations.umi.com/northwestern:16368
-
- Description:
- From the early usage of metallic thin films as mirrors tracing back to 2900 BC, to the modern thin film photonic circuits as a mature optical processing platform, and to the growing class of atomically-thin two-dimensional (2D) materials with diverse and tailorable properties, thin film materials have played an important...
- Keyword:
- Two-dimensional materials, Photonic circuits, Thin film materials, Topological photonics, Electron-beam lithography, and Optical materials
- Subject:
- Physics and Materials Science
- Creator:
- Liu, Pufan
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_946295 and http://dissertations.umi.com/northwestern:16358
-
- Description:
- In this dissertation, I summarize my findings of the dynamics of colloidal suspensions over a large range of volume fractions in two systems: drop impact and film rupture. The existence of a deformable surface in both these systems allows me to capture the consequences of non-Newtonian flow using high-speed imaging....
- Keyword:
- shear rheology, drop impact, Fluid dynamics, High-speed imaging, Soft matter, and Colloidal suspensions
- Subject:
- Physics and Materials Science
- Creator:
- Shah, Phalguni S.
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- etdadmin_upload_937776 and http://dissertations.umi.com/northwestern:16311
-
- Description:
- Elemental powder blends are an emerging alternative to prealloyed powders for high-throughput alloy design via additive manufacturing techniques due to their flexibility, low cost, and ease of customization. This dissertation investigates elemental alloying elements (Sc and Zr) which are high-melting and highly reactive, unlike previous work which focused on more...
- Keyword:
- additive manufacturing, in situ diffraction, elemental blends, laser powder-bed fusion, aluminum, and creep
- Subject:
- Materials Science
- Creator:
- Glerum, Jennifer Anne
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 02/16/2023
- Date Created:
- 2022-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16304 and etdadmin_upload_936163
-
- Description:
- The on-going demand for miniaturized optical and on-chip photonic systems of the future has led to a few potential solutions in the literature. Recent advances in van der Waals and 2-dimensional materials signal a bright future for the next generation, compact electronic and photonic devices. With reduced dimensionality and material...
- Keyword:
- Polarization, Phonons, van der Waals, Plasmons, Wave plate, and 2D materials
- Subject:
- Optics, Materials Science, and Electromagnetics
- Creator:
- Abedini Dereshgi, Sina
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 03/24/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16396 and etdadmin_upload_958293
-
- Description:
- Atomistic methods offer a powerful set of tools in the study of materials systems, as they allow materials scientists to ask questions with a high degree of specificity. They are well suited for studying and designing energy materials, critical due to the climate crisis, in part due to their ability...
- Subject:
- Materials Science
- Creator:
- Patel, Shane
- Owner:
- Scholarly Digital Publishing
- Language:
- en
- Date Uploaded:
- 03/24/2023
- Date Created:
- 2023-01-01
- Resource Type:
- Dissertation
- Alternate Identifier:
- http://dissertations.umi.com/northwestern:16415 and etdadmin_upload_962311
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