A multicomponent bimodal poly(vinyl acetate) (PVAc) polymer composite has been scientifically designed to increase biaxial plastic flow stabilization for the achievement of large biaxial deformations. For this, a systems-based approach was used for the computational materials design of a high performance bubblegum whose mean in-vivo bubble diameter exceeds that of...
This dissertation examines growth of platinum nanoparticles from vapor deposition on SrTiO3 using a characterization approach that combines imaging techniques and X-ray methods. The primary suite of characterization probes includes atomic force microscopy (AFM), grazing-incidence small-angle X-ray scattering (GISAXS), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and X-ray absorption spectroscopy...
Recent assessment of material property requirements for blast resistant applications, especially for the naval ship hulls, has defined the need to design steels with high stretch ductility and fragment penetration resistance, along with high strength and adequate toughness. Using a system based computational materials design approach, two series of austenitic...
Atrial fibrillation (AF) is the most common supraventricular tachyarrhythmia and its prevalence is expected to increase with the aging population. However, the mechanisms AF initiation, maintenance and termination are not completely understood. The surface electrocardiogram (ECG) characteristics are a direct reflection of pathophysiologic events in the atria and can be...
The work presented in this dissertation focuses on ceramic anode materials for solid oxide fuel cells (SOFCs). The primary goal was to characterize the anode and relate the electrochemical behavior to the microstructure. The anode that was most extensively studied in this work was a composite of Gd0.10Ce0.90O1.95 (GDC) and...
This dissertation examines the impact of product returns on effective supply chain management. Within this area of research, known as Closed-Loop Supply Chain Management, we consider both strategic and tactical level reverse logistics and inventory management problems from the perspective of a firm which must efficiently process returned items. More...
Next generation of high performance nano-optoelectronic integrated circuits will require an integral combination of highly efficient all-optical nanophotonic devices and electrically-pumped nanophotonic devices, which will enable the chip to process optical information all optically with ultrafast speed and electro-optically to interface with the electronic control plane. The realizations of such...
In composite manufacturing, Vacuum Assisted Resin Transfer Molding (VARTM) is becoming increasingly important as a cost effective manufacturing method of structural composites. In this process the dry preform (reinforcement) is placed on a rigid tool and covered by a flexible film to form an airtight vacuum bag. Liquid resin is...
Structural dynamics in three polymer blend systems, differing largely with respect to morphology, have been investigated. The first system, composed of two immiscible homopolymers, exhibits a microstructure of micron-sized droplets dispersed in a matrix phase. We have examined small-angle x-ray scattering (SAXS) as a new approach for conducting in situ...
Oxide surface structures play a key role in many technological processes, including catalysis, thin film growth, and layered structures, and a thorough understanding of surface structures and surface structure dynamics is required in order to better engineer materials systems for these processes. This research works towards understanding these fundamental principles...