Global energy demands are expected to increase by about one-third between 2014 and 2040 and will surely be met from a combination of wind, solar, and among other renewable sources. The shift away from fossil fuels and towards renewable energies will ensure a clean and sustainable future. The main issue...
The lanthanides, with their limited orbital effects and high oxophilicity, represent a class of catalytic metals highly distinguished from more commonly-utilized transition metals. Homogeneous lanthanide catalysts often afford high catalytic rates and impressive selectivity. However, challenges regarding the synthesis and utilization of highly air- and water-sensitive organo-lanthanide complexes have limited...
Sulfur mustard (HD), also known as the King of the Battle Gases, was one of the earliest and strongest CWAs to be deployed in war-time conflicts. Unfortunately, its low cost and facile production have resulted consistent use in the present day by rogue elements. As a result, the development of...
Electrochemical cell devices are increasingly being sought for energy conversion and storage applications due to their high efficiencies and their potential for operating free of greenhouse gas (GHG) emissions. Solid Acid Electrochemical Cells (SAECs), which most commonly employ CsH2PO4 (CDP) as the electrolyte component, are uniquely suited to meet the...
In the vertebrate retina, neurons process visual signals, generating feature selectivity in their activity levels. We use computational models to understand these behaviors by interpreting them mathematically. One component of this analysis is the spatial selectivity or receptive field, a property found in all visual sensory neurons. The neurons found...
Having an emotion involves having an evaluative point of view on one’s circumstances. For example, there is a sense in which being angry involves taking oneself to have been wronged, and fear seems to paint the scene as one of danger. A significant debate in contemporary philosophy of mind concerns...
Our experience of the physical world is mediated by our senses, but while most people have five senses, interactions with computer systems are largely limited to the visual sense. When working with nonvisual artifacts, like sound, on computers, such artifacts are typically transformed, or re-encoded, into something visual. Determining how...
This dissertation investigates the use of organic and semiconductor nanomaterials as chromophores in solar fuels production and energy transfer-mediated [2+2] cycloadditions. A series of novel N-annulated perylene chromophore amphiphiles was synthesized via a modular synthesis. These perylene amphiphiles were found to self-assemble in aqueous solution, forming extended ribbon-like nanostructures that...
Recent advancements in processing and manufacturing techniques have spurred an exponential increase in use of polymer nanocomposites in a variety of applications. A key challenge in using these nanocomposites effectively is the dispersion of nanoparticles in the polymer matrix. Matrix-free assemblies of polymer grafted nanoparticles, called hairy nanoparticles assemblies(aHNPs) have...
The Spectral Body: Theology and Economy in Dostoevsky and Melville’s Fiction This dissertation examines the intersections and tensions between religion and economy in Dostoevsky and Melville’s fiction. I argue that Christian theology of the body—as the site of both salvation and economic production—is at the center of their concern. These...
Prostate cancer (PCa) is the second most common cancer in American men and has led to approximately 29K deaths in 2018. The androgen signaling pathway plays a pivotal role in the pathogenesis of PCa, and androgen deprivation therapy (ADT) has been the main therapeutic approach for PCa. However, almost all...
Discrete molecules, linear and branched polymers, and disordered cross-linked networks are well studied objects of chemical synthesis. However, two-dimensional polymers (2DPs) have been long missing from this continuum of molecular architectures, both in chemical synthesis and in Nature. Recently, new polymerization strategies and characterization methods have enabled the unambiguous realization...
From visualizing thousands of social relationships, operationalizing measures that offer us insight into our theories, to characterizing cultural change over the span of centuries, computational methods appear to provide sociology a means to reveal patterns otherwise unknowable. While these methods are persistently critiqued for their inability to generate social theory,...
The BCR-ABL negative Myeloproliferative Neoplasms (MPNs) are clonal hematopoietic stem-cell disorders characterized by abnormal proliferation of differentiated myeloid lineages. MPNs include 3 clinically distinct disorders: Polycythemia Vera (PV), Essential Thrombocythemia (ET) and Primary Myelofibrosis (PMF). 95% of MPNs are characterized by driver mutations in Janus Kinase 2 (JAK2), Thrombopoietin receptor...
The dissertation’s topic is the creation of quotidian judgements and practices related to food, amid the enduring social and spatial stratification of everyday life. The sites are two large and diverse cities: Paris and Chicago. The method is ethnographic and contextual.Chapter 1 documents the dietary tastes and culinary practices of...
ABSTRACT In the past two decades, the number of African and Afro-Caribbean immigrants arriving in the U.S. has been increasing. Black immigrants (36% of whom migrated from Africa and 50% from the Caribbean since 2000) now account for nearly 10% of the Black population in the U.S. This growing demographic...
This dissertation explores black litigation strategies, black legal culture, and the effect of black litigation on civil law. Not only did African Americans sue white southerners and white-owned companies for white-on-black violence under Jim Crow, they shared their collective legal knowledge through a network of black newspapers and contributed to...
Does the Russian Federation in the Putin-Medvedev era follow a grand strategy, and if so, what does it look like, and how can we discern the making of Russian grand strategy? However, Russian grand strategy is neither formally codified nor readily accessible, and it remains opaque at best. In this...
Throughout history, the development of materials has relied heavily on the empirical judgment of scientists and engineers and on prolonged experiments proton to errors. Due to the complexity of material behavior, successful discovery of new candidates has been serendipitous, and down-selection of candidates remains a time-consuming process that requires repetitive...
This dissertation investigates how US Americans in the nineteenth century began to apply the category of religious fanaticism to individuals and communities deemed dangerous. Contributing to scholarship on secularism, racial governance, and American religious history, this dissertation argues that fanaticism is not a neutral category of description. It tracks how...