The work presented in this dissertation focuses on ceramic anode materials for solid oxide fuel cells (SOFCs). The primary goal was to characterize the anode and relate the electrochemical behavior to the microstructure. The anode that was most extensively studied in this work was a composite of Gd0.10Ce0.90O1.95 (GDC) and...
Dimensionally constrained material systems are at the forefront of current materials research because of their novel and often enhanced physical, chemical and biological properties. The dimensionality effects are pervasive through different classes of materials including ceramics, metals and polymers. Often times dimensionality effects are manifested as internal structure variations in...
Structural dynamics in three polymer blend systems, differing largely with respect to morphology, have been investigated. The first system, composed of two immiscible homopolymers, exhibits a microstructure of micron-sized droplets dispersed in a matrix phase. We have examined small-angle x-ray scattering (SAXS) as a new approach for conducting in situ...
Oxide surface structures play a key role in many technological processes, including catalysis, thin film growth, and layered structures, and a thorough understanding of surface structures and surface structure dynamics is required in order to better engineer materials systems for these processes. This research works towards understanding these fundamental principles...
This dissertation examines the impact of product returns on effective supply chain management. Within this area of research, known as Closed-Loop Supply Chain Management, we consider both strategic and tactical level reverse logistics and inventory management problems from the perspective of a firm which must efficiently process returned items. More...
As technology moves into deep submicron and nanoscale era, undesirable trends such as increasing power density, leakage power, and temperature variation within chips have made thermal effects emerge as a major bottleneck in further technology scaling. Thermal effects are no longer considered as just a reliability issue, but it also...
Next generation of high performance nano-optoelectronic integrated circuits will require an integral combination of highly efficient all-optical nanophotonic devices and electrically-pumped nanophotonic devices, which will enable the chip to process optical information all optically with ultrafast speed and electro-optically to interface with the electronic control plane. The realizations of such...
In composite manufacturing, Vacuum Assisted Resin Transfer Molding (VARTM) is becoming increasingly important as a cost effective manufacturing method of structural composites. In this process the dry preform (reinforcement) is placed on a rigid tool and covered by a flexible film to form an airtight vacuum bag. Liquid resin is...
Autoxidation is a primary route by which lubricants in working conditions undergo degradation. Degraded lubricants, if not replaced periodically, contribute to increased wear and product failure. Experimental studies of lubricant degradation have yielded useful results but have left important questions unanswered. While many computational studies of degradation have been carried...
The purpose of the dissertation is to develop a framework for equilibration of activity-trip chain demand in an integrated system of activity scheduling and travel choices within a dynamic network equilibrium framework. Activity-based modeling systems generate detailed activity chain schedules for individuals, which have to be assigned to transportation networks....